Multiproduct low biuret urea production

Patent metadata

Field	Value
Publication number	US-12240800-B2
Application number	US-202318692124-A
Country	US
Kind code	B2
Filing date	Nov 22, 2023
Priority date	Nov 22, 2022
Publication date	Mar 4, 2025
Grant date	Mar 4, 2025

Abstract

Embodiments pertain to a urea plant and to the operation of a urea plant in a reduced load mode. In embodiments, two evaporators in parallel are used, connected to a finishing section respectively to a melamine plant.

First claim

The invention claimed is:

1. A method of operating a urea plant in a reduced load mode, the method comprising:
operating a high pressure urea synthesis section of a urea plant in a reduced load mode;
subjecting a urea solution stream from the urea synthesis section to purification in a recovery section to give purified urea solution;
subjecting the purified urea solution to evaporation of water in a first vacuum evaporation stage, to give a first concentrated urea solution;
subjecting a first part of the first concentrated urea solution to evaporation of water in a first evaporator of a second vacuum evaporation stage to form a first urea melt;
subjecting a second part of the first concentrated urea solution to evaporation of water in a second evaporator of the second vacuum evaporation stage to form second urea melt;

wherein the first evaporator is operated at a first operating capacity ratio, as percentage of a design capacity of the first evaporator, and wherein the second evaporator is operated at a second operating capacity ratio, as percentage of a design capacity of the second evaporator, wherein the second operating capacity ratio is lower than the first operating capacity ratio, and wherein the second evaporator has an outlet for the second urea melt connected with an inlet of a melamine plant.

2. The method according to claim 1 , wherein the first evaporator is operated at 90-100% of the design capacity of the first operator, and the second evaporator is operated at 20-80% of the design capacity of the second evaporator.

3. The method according to claim 1 , wherein the first evaporator is connected to a urea finishing section to form a solid urea product.

4. The method according to claim 3 , wherein the urea finishing section is a prilling tower.

5. The method according to claim 3 , wherein the urea supply of the finishing section originates for at least 90 wt. % from the first evaporator.

6. The method according to claim 1 , comprising supplying a part of the first urea melt to the melamine plant.

7. The method according to claim 1 , comprising supplying a part or all of the second urea melt to the melamine plant.

8. A plant for the production of urea, comprising:
a urea production section comprising a synthesis section and a recovery section,
a first vacuum evaporation stage receiving urea solution from the urea production section,
a second vacuum evaporation stage receiving concentrated urea solution from the first vacuum evaporation stage, comprising a first evaporator and a second evaporator arranged in parallel, both receiving concentrated urea solution from the first vacuum evaporation stage, wherein the first evaporator has an outlet for a first urea melt connected to a finishing section and to a melamine plant, and wherein the second evaporator has an outlet for a second urea melt connected to said melamine plant.

9. The plant according to claim 8 wherein the finishing section is a prilling tower.

10. The plant according to claim 9 , wherein the finishing section is connected for receiving urea melt exclusively from the first evaporator.

11. A plant according to claim 8 suitable for the production of urea and melamine, comprising said melamine plant and a liquid flow line for the second urea melt from said outlet of the second evaporator to the melamine plant.

12. A method of switching a urea plant according to claim 8 from a first mode to a second mode wherein the urea production rate is higher in the first mode than in the second mode, the method comprising:
decreasing a flow rate of concentrated urea solution to the second evaporator;
and keeping a flow rate of concentrated urea solution to the first evaporator constant, or increasing a flow rate of concentrated urea solution to the first evaporator, or decreasing a flow rate of concentrated urea solution to the first evaporator in such an amount that the decrease, relative to the flow rate of the first evaporator in the first mode, is smaller than the decrease of the flow rate of concentrated urea solution to the second evaporator relative to the flow rate of the second evaporator in the first mode.

13. The method according to claim 12 , wherein in the second mode, a part or all of the second urea melt from the second evaporator is supplied to the melamine plant in the second mode, and a part or all of the first urea melt from the first evaporator is supplied to the finishing section.

14. The method according to claim 13 , wherein in the second mode, a first part of the first urea melt is supplied to the finishing section and a second part of the first urea melt is supplied to the melamine plant.

15. The method according to claim 14 , wherein the urea melt flow rate to the melamine plant in the second mode is at least 80% of the urea melt flow rate to the melamine plant in the first mode.

Assignees

• Stamicarbon

Inventors

• Manic Branislav
• Patil Rahul

Classifications

• C07D251/60

  from urea or from carbon dioxide and ammonia · CPC title

• C07C273/16

  Separation; Purification · CPC title

• B01D1/0088

  Cascade evaporators · CPC title

• C07C273/12 Primary

  combined with the synthesis of melamine · CPC title

• C07C273/04 Primary

  from carbon dioxide and ammonia · CPC title