Urea production with multiple evaporators

Patent metadata

Field	Value
Publication number	US-11332437-B2
Application number	US-202017424958-A
Country	US
Kind code	B2
Filing date	Dec 30, 2020
Priority date	Dec 30, 2019
Publication date	May 17, 2022
Grant date	May 17, 2022

Abstract

A urea production process which includes and a synthesis section, a recovery section and evaporation section and a finishing section wherein the evaporation section includes a first evaporator and downstream thereof a second evaporator for urea solution. The second evaporator operates a lower pressure than the first evaporator to provide a urea melt and second vapor, solidifying the urea melt in a finishing section to provide a solid urea produce and off gas, scrubbing the off gas followed by condensing to produce a first condensate and second condensate; supplying the first condensate to a wastewater treatment section and supply the second condensate to the scrubber wherein the second condensate is used as a scrub liquid in the scrubber.

First claim

The invention claimed is:

1. A urea production process comprising:
a) concentrating urea solution in a first evaporator of an evaporation section, to give concentrated urea solution and a first vapor,
b) further concentrating said concentrated urea solution from said first evaporator in a second evaporator of said evaporation section, to give a urea melt and second vapor,
c) solidifying said urea melt in a finishing section giving solid urea product and off-gas,
d) scrubbing said off-gas in a scrubber,
e) condensing said first vapor in a first condenser to give a first condensate,
f) condensing said second vapor in a second condenser to give a second condensate,
g) supplying said first condensate to a wastewater treatment section, and
h) separately supplying said second condensate to said scrubber, wherein said second condensate is used as scrub liquid in said scrubber, wherein said scrubber additionally uses an acid scrub liquid.

2. A urea production process according to claim 1 , wherein said acid scrub liquid comprises nitric acid or sulphuric acid.

3. A urea production process according to claim 1 , wherein said wastewater treatment section comprising a hydrolyser and a desorber.

4. A urea production process according to claim 1 , wherein said finishing section is a prilling tower.

5. A urea production process according to claim 1 , wherein said finishing section is a granulator.

6. A urea production process according to claim 1 , wherein the urea melt from the second evaporator comprises less than 0.1 wt. % moisture.

7. A urea production process according to claim 1 , wherein said scrubbing gives cleaned off-gas and utilized scrub liquid comprising urea, wherein the process further comprises supplying the utilized scrub liquid to the second evaporator.

8. A urea production process according to claim 1 , wherein the utilized scrub liquid is added to the concentrated urea solution downstream of the first evaporator.

9. A urea production process according to claim 1 , wherein the second evaporator operates at 130-140° C. and at a pressure of less than 15 kPa, and wherein the first evaporator gives a concentrated urea solution with at least 90 wt. % urea including biuret at the outlet and operates with a temperature of at least 120° C.

10. A urea production process according to claim 1 , wherein a liquid stream comprising water and one or more additives is supplied to the evaporation section downstream for urea solution of the first evaporator.

11. A urea production process according to claim 10 , wherein the liquid stream comprising one or more additives is mixed with the concentrated urea solution in the transport line between the first and second evaporator, or is supplied to an inlet of the second evaporator, and the solid urea product comprises the one or more additives in amount of at least 0.10 wt. % based on total weight of additives and total weight of solid urea product.

12. The urea production process of claim 10 , wherein the one or more additives is an aqueous solution.

13. A urea production system comprising an evaporation section, a finishing section, a wastewater treatment section, and a scrubber, wherein the evaporation section comprises a first evaporator and downstream thereof a second evaporator, and a first condenser and a second condenser, wherein
a) said first evaporator comprises an inlet for urea solution, an outlet for concentrated urea solution and an outlet for a first vapor,
b) said second evaporator comprises an inlet for said concentrated urea solution, an outlet for urea melt and an outlet for second vapor,
c) said finishing section comprises an inlet for said urea melt, an outlet for solid urea product and an outlet for off-gas and is configured for solidifying said urea melt into said solid urea product,
d) said scrubber comprises an inlet for said off-gas and is configured for scrubbing said off-gas using scrub liquid,
e) said first condenser comprises an inlet for said first vapor and an outlet for a first condensate,
f) said second condenser comprises an inlet for said second vapor and an outlet for a second condensate,
g) said wastewater treatment section comprises an inlet for said first condensate, and
h) the plant comprises a connection for said second condensate from said outlet of said second condenser directly to an inlet of said scrubber.

14. A urea production system according to claim 13 , wherein said wastewater treatment section comprising a hydrolyser and a desorber.

Assignees

• Stamicarbon

Inventors

• Patil Rahul
• Simons Petrus Anna Maria Robertus
• Manic Branislav

Classifications

• B01D53/73

  After-treatment of removed components · CPC title

• B01D1/0029

  Use of radiation · CPC title

• B01D5/0003 Primary

  by using heat-exchange surfaces for indirect contact between gases or vapours and the cooling medium · CPC title

• B01D5/009

  Collecting, removing and/or treatment of the condensate · CPC title

• B01D5/006

  with evaporation or distillation · CPC title