Method for the production of superabsorbents

Patent metadata

Field	Value
Publication number	US-12239947-B2
Application number	US-201917264093-A
Country	US
Kind code	B2
Filing date	Aug 9, 2019
Priority date	Aug 20, 2018
Publication date	Mar 4, 2025
Grant date	Mar 4, 2025

Abstract

A process for producing superabsorbent particles by polymerizing a monomer solution, comprising the steps of continuously polymerizing the monomer solution on the continuous belt of a belt reactor, comminuting the polymer gel obtained, rinsing the polymer gel obtained on the underside of the belt reactor into a separation unit with water, separating the polymer gel from the water in the separation unit and recycling the polymer gel into the comminution, wherein the polymer gel has a swelling capacity in water of at least 100 g/g, the dwell time of the polymer gel in the rinse water is less than 40 minutes, and the separation unit has openings with a clear width of at least 1 mm.

First claim

The invention claimed is:

1. A process for producing superabsorbent particles by polymerizing a monomer solution comprising
a) at least one ethylenically unsaturated monomer which bears an acid group and has been neutralized to an extent of 50 to 85 mol %,
b) at least one crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomers mentioned under a) and
e) optionally one or more water-soluble polymer,
comprising
i) continuously polymerizing the monomer solution on a continuous belt of a belt reactor,
ii) comminuting a polymer gel obtained in step i),
iii) rinsing the polymer gel obtained on the underside of the belt reactor into a separation unit with water,
iv) separating the polymer gel from the water in the separation unit and
v) recycling the polymer gel separated off in step iv) into step ii),
wherein the polymer gel has a swelling capacity in water of at least 100 g/g, a dwell time between step iii) and step iv) is less than 20 minutes, and the separation unit in step iv) has openings with a clear width of at least 1 mm.

2. The process according to claim 1 , wherein the dwell time between step iii) and step iv) is less than 15 minutes.

3. The process according to claim 1 , wherein the dwell time between step iii) and step iv) is less than 10 minutes.

4. The process according to claim 3 , wherein the dwell time between step iii) and step iv) is less than 5 minutes.

5. The process according to claim 1 , wherein the polymer gel obtained on the underside of the belt reactor is collected in a tank.

6. The process according to claim 1 , wherein the separation unit in step iv) has openings having a clear width of at least 1.5 mm.

7. The process according to claim 6 , wherein the separation unit in step iv) has openings having a clear width of at least 2 mm.

8. The process according to claim 7 , wherein the separation unit in step iv) has openings having a clear width of at least 3 mm.

9. The process according to claim 1 , wherein the openings in the separation unit in step iv) consist of the meshes of a screen.

10. The process according to claim 1 , wherein the openings in the separation unit in step iv) take the form of slots.

11. The process according to claim 1 , wherein the separation unit is a horizontal rotating drum, and the drum is inclined from the inlet to the outlet.

12. The process according to claim 11 , wherein the drum is inclined by at least 10° relative to the horizontal.

13. The process according to claim 12 , wherein the drum is inclined by at least 20° relative to the horizontal.

14. The process according to claim 13 , wherein the drum is inclined by at least 30° relative to the horizontal.

15. The process according to claim 1 , wherein water obtained in step v) is recycled into the process in step iii).

16. A hygiene article comprising superabsorbents produced by a process of claim 1 .

Assignees

• Basf Se

Inventors

• Pfeiffer Thomas
• Funk Ruediger
• Krueger Marco
• Possemiers Karl
• Schroeder Juergen
• Weismantel Matthias

Classifications

• C08F2/16

  Aqueous medium · CPC title

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• B01J13/0065 Primary

  containing an organic phase · CPC title

• A61L15/60

  Liquid-swellable gel-forming materials, e.g. super-absorbents · CPC title

• B01J13/0069 Primary

  Post treatment · CPC title