Method for manufacturing electrode, and electrode

Patent metadata

Field	Value
Publication number	US-12234563-B2
Application number	US-202218569324-A
Country	US
Kind code	B2
Filing date	Jul 1, 2022
Priority date	Jul 12, 2021
Publication date	Feb 25, 2025
Grant date	Feb 25, 2025

Abstract

The present invention provides a simple method for producing an electrode having improved oxygen evolution reaction (OER) activity without a need for catalyst coating and an electrode produced by this production method. The method is a method for producing an electrode including a step of subjecting an electrically conductive substrate comprising a nickel alloy comprising 30 to 70% by mass of Ni and 30 to 70% by mass of Fe, provided that Ni+Fi=100% by mass, to a thermal treatment, and a step of etching the thermally treated electrically conductive substrate with an etchant comprising at least any acid of an organic acid and a weak inorganic acid. The electrode is an electrode that is produced by this production method and that is useful as an oxygen evolution anode or the like.

First claim

The invention claimed is:

1. A method for producing an oxygen generation anode for water electrolysis, comprising:
thermally treating an electrically conductive substrate comprising a nickel alloy comprising Ni in a range from 30 to 70% by mass, and Fe in a range from 30 to 70% by mass, relative to a total of Ni and Fe as 100% by mass, at a temperature in a range from 500 to 600° C., thereby a surface layer comprising Fe as a main component being formed; and
etching the thermally treated electrically conductive substrate with an etchant comprising an organic acid and a weak inorganic acid so that the surface layer is at least partially removed, thereby the anode having an at least partially porous surface comprising Ni as a main component being obtained in an area of the surface layer where the surface layer has been partially removed by the etching with the etchant.

2. The method for producing an oxygen generation anode for water electrolysis according to claim 1 , wherein
the organic acid is acetic acid, and
the weak inorganic acid is boric acid.

3. The method for producing an oxygen generation anode for water electrolysis according to claim 1 , further comprising blasting a surface of the electrically conductive substrate before the thermal treating.

4. The method for producing an oxygen generation anode for water electrolysis according to claim 1 , wherein the nickel alloy comprises Ni in a range from 40 to 60% by mass, and Fe in a range from 40 to 60% by mass relative to the total of Ni and Fe as 100% by mass.

5. The method for producing an oxygen generation anode for water electrolysis according to claim 1 , further comprising providing a catalyst layer on the at least partially porous surface of the etched electrically conductive substrate.

6. The method for producing an oxygen generation anode for water electrolysis according to claim 5 , further comprising providing an intermediate layer between the at least partially porous surface of the etched electrically conductive substrate and the catalyst layer.

7. The method for producing an oxygen generation anode for water electrolysis according to claim 1 ,
wherein in the etching, the surface layer of the thermally treated electrically conductive substrate is partially removed, thereby anode having a partially porous surface comprising Ni as a main component is obtained.

Assignees

• De Nora Permelec Ltd

Inventors

• Zaenal Awaludin
• Kato Akihiro
• Nakai Takaaki
• Arimoto Osamu
• Madono Akihiro
• Fukuda Sayaka

Classifications

• C25B1/04

  by electrolysis of water · CPC title

• C23F17/00

  Multi-step processes for surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by subclass C21D or C22F or class C25 (coating for obtaining at least two superposed coatings either by methods not provided for in a single one of main groups C23C2/00 - C23C26/00, or by combinations of methods providedfor in subclasses C23C and C25D, C23C28/00) · CPC title

• C23F1/16

  Acidic compositions (C23F1/42 takes precedence) · CPC title

• C22F1/10

  of nickel or cobalt or alloys based thereon · CPC title

• C21D6/001

  containing Ni (C21D6/004 takes precedence) · CPC title