Sustainable laundry sour compositions with iron control

Patent metadata

Field	Value
Publication number	US-12234429-B2
Application number	US-202217664094-A
Country	US
Kind code	B2
Filing date	May 19, 2022
Priority date	Nov 3, 2011
Publication date	Feb 25, 2025
Grant date	Feb 25, 2025

Abstract

Linen treatment compositions and linen processes are disclosed which help to prevent iron deposition from wash water, and/or redeposition after iron containing stain (such as blood) removal by alkaline detergents. The linen treatment composition is a combination of a hydroxycarboxylic acid and an acid source, which may be organic or inorganic. The invention provides for effective iron control in a phosphorus-free formula that is also free of toxic or hazardous chemicals and includes sustainable, environmentally friendly ingredients, while still providing effective iron control.

First claim

What is claimed is:

1. A method for treating linen, to reduce or eliminate iron deposition/redeposition comprising:
washing the linen with a detergent at an alkaline pH in a washing machine;
rinsing said linen;
obtaining a liquid linen treatment composition consisting of: about 15 wt. % to about 45 wt. % of a hydroxycarboxylic acid which is selected from one or more of: glycolic acid, malic acid, lactic acid, tartaric acid, citric acid, hydroxybutyric acid, glyceric acid, tartronic acid, salicylic acid, m-hydroxybenzoic acid, p-hydroxybenzoic acid, gallic acid, mandelic acid and gluconic acid; about 1 wt. 1% about 10 wt. % of a carboxylate polymer which is a polyacrylic acid salt, a polymaleic acid salt, or a combination thereof; water in the amount of between about 15 wt. % and about 45 wt. %; about 12 wt. % to about 21 wt. % of sulfuric acid form urea sulfate; and optionally one or more additives selected from a chelating agent, a dye, a perfume, an additional acid source, a surfactant and/or a defoamer;
applying the linen treatment composition or a use solution of said linen treatment composition to said linen; wherein the use solution of the linen treatment composition has a pH of between about 3 and about 10; and
reducing or eliminating iron deposition or redeposition on said linen,
wherein the linen treatment composition is free of a peroxycarboxylic acid and is applied prior to washing said linen, after washing said linen, during washing of said linen, or multiple times throughout the method.

2. The method of claim 1 , wherein said hydroxycarboxylic acid is selected from one or more of: glycolic acid, malic acid, lactic acid, tartaric acid, citric acid, glyceric acid, tartronic acid, salicylic acid, and gluconic acid.

3. The method of claim 1 , wherein said sulfuric acid is present in an amount between about 12 wt. % and about 18 wt. %.

4. The method of claim 1 , wherein said sulfuric acid and urea are in a molar ratio of about 1:1.

5. The method of claim 1 , wherein said additional acid source is selected from one or more of formic acid, acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, itaconic acid, trichloroacetic acid, urea hydrochloride, benzoic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, maleic acid, fumaric acid, adipic acid, terephthalic acid, sulfamic acid, methylsulfamic acid, hydrochloric acid, hydrobromic acid, hydrofluoric acid, and nitric acid.

6. The method of claim 1 , wherein the use solution of the linen treatment composition has a pH of between about 3 and about 6.

7. The method of claim 1 , wherein the use solution of the linen treatment composition has a pH of between about 7 and about 10.

8. The method of claim 1 , wherein said carboxylate polymer is the polyacrylic acid salt.

9. The method of claim 2 , wherein said hydroxycarboxylic acid is citric acid.

10. The method of claim 1 , wherein said chelating agent is present in an amount up to about 8 wt. %.

11. The method of claim 10 , wherein the chelating agent is selected from diethylene triamine pentaacetate, diethylene triamine penta(methyl phosphonic acid), ethylene diamine-N′N′-disuccinic acid, ethylene diamine tetraacetate, ethylene diamine tetra(methylene phosphonic acid), hydroxyethane di(methylene phosphonic acid), glutamic acid, methylglycinediacetic acid, L-aspartic acid N,N-diacetic acid tetrasodium salt, sodium diethanolglycine/2-hydroxyethyliminodiacetic acid disodium salt, iminodisuccinic acid and salts, ethylenediaminedisuccinic acid and salts, or combinations thereof.

12. The method of claim 1 , wherein said use solution is formed by diluting the linen treatment composition with a dilution ratio between about 1:10 and about 1:10,000.

13. The method of claim 1 , wherein the carboxylate polymer is in a concentration of between about 5 wt. % to about 10 wt. %.

Assignees

• Ecolab Usa Inc

Inventors

• Soontravanich Sukhwan
• Hubig Stephan
• Miralles Altony J

Classifications

• C11D3/2086

  Hydroxy carboxylic acids-salts thereof · CPC title

• C11D2111/14

  Hard surfaces · CPC title

• C11D2111/12

  Soft surfaces, e.g. textile · CPC title

• C11D7/265

  Carboxylic acids or salts thereof · CPC title

• C11D7/08

  Acids · CPC title