Oil Crystallization Promoter, Preparation Method Therefor and Use Thereof
US-2024407384-A1 · Dec 12, 2024 · US
US12201116B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12201116-B2 |
| Application number | US-201916977400-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 1, 2019 |
| Priority date | Mar 1, 2018 |
| Publication date | Jan 21, 2025 |
| Grant date | Jan 21, 2025 |
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A high stearic oilseed stearin fat including: from 19% to 95% of disaturated triglycerides in which the (w/w) ratio of disaturated triglycerides with one oleic acid to disaturated triglycerides with one linoleic acid (SOS/SLS) is higher than 1; and at least 1% of trisaturated triglycerides; in which the Ssn-2/Stotal×100 value is of from 11 to 98; and a process for preparing the same.
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The invention claimed is: 1. Stearic oilseed stearin fat having a content of stearic acid higher than 11% (w/w), comprising: from 19% to 95% of disaturated triglycerides in which the (w/w) ratio of disaturated triglycerides with one oleic acid to disaturated triglycerides with one linoleic acid (SOS/SLS) is higher than 2.3; and at least 1% of trisaturated triglycerides; in which the S sn-2 /S total ×100 value is of from 11 to 98. 2. Stearic oilseed stearin fat according to claim 1 , wherein it is obtained from seed oils selected from sunflower, brassica, cotton, maize, peanut, soybean or safflower oilseeds or mixed thereof; the oils containing more oleic acid than linoleic acid; more than 11% of stearic acid; and up to 24% of linoleic acid. 3. Stearic oilseed stearin fat according to claim 1 , wherein it comprises from 19% to 89% of disaturated triglycerides. 4. Stearic oilseed stearin fat according to claim 1 , wherein the total amount of trisaturated triglycerides is higher than 1.3%. 5. Stearic oilseed stearin fat according to claim 1 , wherein the S sn-2 /S total ×100 value is of from 13.5 to 95.6. 6. Stearic oilseed stearin fat according to claim 1 , wherein the total amount of triunsaturated triglycerides is higher than 2.2%. 7. Stearic oilseed stearin fat according to claim 1 , wherein the stearic oilseed stearin fat contains at least 625 ppm of waxes. 8. A process for preparing the stearic oilseed stearin fat according to claim 1 , the process comprising the following steps: a) interesterification of HSHO seed oils by using any commercial lipase resulting in partial random rearrangement of saturated fatty acid into the triglycerides molecules; and b) at least one fractionation of the partial random interesterified HSHO seed oils or their stearins. 9. A process according to claim 8 , wherein the interesterification is carried out by using between 0.1% to 10.0% of any commercial lipase at a temperature of from 50° C. to 80° C., for a period of time of from 20 minutes to 30 hours. 10. A process according to claim 8 , wherein the fractionation step is a dry fractionation comprising the steps of crystallisation by: cooling of completely melted oil to a temperature in the range of from 5° C. to 25° C. during a period of time of from 20 minutes to 15 hours, and then cooling to a final temperature in the range of from −10° to 22° C. for a period of time of from 10 minutes to 48 hours; and separation the solid stearin and liquid olein by pressure filtration, vacuum filtration or centrifugation. 11. A process according to claim 8 , wherein the fractionation step is a solvent fractionation conducted by using organic solvent or a blend of solvents with a ratio oil to solvent (v/v) of from 1/0.2 to 1/11 at temperature of from 25° C. to −20° C. 12. A process for preparing the stearic oilseed stearin fat according to claim 1 , the process comprising at least one fractionation of a mixture of interesterified high stearic seed oil, fat or stearin and no interesterified no hydrogenated high stearic oil, fat or stearin, in which the mixture consists of 10% to 90% interesterified high stearic seed oil, fat or stearin. 13. Shortening, margarine, spread, blended spread, bakery fat, frying fat, filling fat, coating compound, confectionary fat or ice-cream fat containing the stearic oilseed stearin fat according to claim 1 . 14. A method comprising preparing shortening, margarine, spread, blended spread, bakery fat, frying fat, filling fat, coating compound, confectionary fat or ice-cream fat from the stearic oilseed stearin fat according to claim 1 .
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