Alkaline cleaning compositions comprising a hydroxyphosphono carboxylic acid and methods of reducing metal corrosion

Patent metadata

Field	Value
Publication number	US-12187985-B2
Application number	US-202017008169-A
Country	US
Kind code	B2
Filing date	Aug 31, 2020
Priority date	Feb 28, 2017
Publication date	Jan 7, 2025
Grant date	Jan 7, 2025

Abstract

The invention relates to compositions, methods of manufacture, and methods for reducing metal corrosion during alkaline cleaning. In particular, the method employs a hydroxyphosphono carboxylic acid in alkaline cleaning of hard surfaces.

First claim

What is claimed is:

1. A hard surface cleaning system comprising:
a multi-part cleaning system consisting essentially of:
a composition consisting essentially of an alkali metal hydroxide alkalinity source,
a composition consisting essentially of a hydroxyphosphono carboxylic acid and optionally a surfactant, and
a composition consisting essentially of a peroxycarboxylic acid oxidizer and optionally a peroxide oxidizer;
wherein the hydroxyphosphono carboxylic acid is in a separate composition from the alkali metal hydroxide alkalinity source until preparation of a use solution;
wherein the peroxycarboxylic acid oxidizer is in a separate composition from the hydroxyphosphono carboxylic acid and the alkali metal hydroxide alkalinity source until preparation of a use solution;
wherein the multi-part cleaning system is a concentrated multi-part cleaning system and the alkalinity source is at a concentration of between about 10 wt. % and about 50 wt. % (active);
wherein the cleaning system provides a pH of at least about 9 upon dilution; and

a hard surface, wherein the hard surface is a food processing stainless steel clean-in-place surface, clean-out-of-place surface, or heat processing surface.

2. The hard surface cleaning system of claim 1 , wherein the concentration of the alkalinity source is between about 35 wt. % and about 50 wt. % (active) in the multi-part cleaning system.

3. The hard surface cleaning system of claim 2 , wherein the hydroxyphosphono carboxylic acid is at a concentration of between about 0.01 wt. % and about 40 wt. % in the multi-part concentrated cleaning system.

4. The hard surface cleaning system of claim 3 , wherein the surfactant is at a concentration of between about 0.01 wt. % and about 40 wt. % in the multi-part cleaning system; wherein the surfactant is selected from the group consisting of nonionic surfactants, cationic surfactants, amphoteric surfactants, zwitterionic surfactants, anionic surfactants, and combinations thereof.

5. The hard surface cleaning system of claim 2 , wherein the concentrated multi-part cleaning system is a liquid system and has between about 20 wt. % and about 90 wt. % water.

6. The hard surface cleaning system of claim 2 , wherein the composition consisting essentially of the an alkali metal hydroxide alkalinity source is a solid or a liquid, and wherein the composition consisting essentially of the hydroxyphosphono carboxylic acid is a solid or a liquid.

7. The hard surface cleaning system of claim 1 , wherein the multi-part system is a three-part system.

8. The hard surface cleaning system of claim 1 , wherein the multi-part cleaning system in a use solution has between about 0.001 wt. % and about 12 wt. % (active) of the alkalinity source.

9. The hard surface cleaning system of claim 8 , wherein the use solution has between about 0.001 wt. % and about 4 wt. % of the hydroxyphosphono carboxylic acid.

10. The hard surface cleaning system of claim 9 , wherein the use solution has a surfactant in an amount greater than 0 ppm and up to about 1000 ppm; wherein the surfactant is selected from the group consisting of nonionic surfactants, cationic surfactants, amphoteric surfactants, zwitterionic surfactants, anionic surfactants, and combinations thereof.

11. The hard surface cleaning system of claim 10 , wherein the multi-part composition is a three-part composition.

12. The hard surface cleaning system of claim 1 , wherein the hard surface is a clean-in-place surface.

13. The hard surface cleaning system of claim 1 , wherein the hard surface is a clean-out-of place surface.

14. The hard surface cleaning system of claim 1 , wherein the hard surface is a heat processing surface.

Assignees

• Ecolab Usa Inc

Inventors

• Stokes Jennifer
• Silvernail Carter M
• Schacht Paul Frazer
• Erickson Anthony W
• Reed Peter E

Classifications

• C11D2111/44

  Multi-step processes · CPC title

• C11D2111/16

  Metals · CPC title

• C11D2111/14

  Hard surfaces · CPC title

• C11D3/365

  containing carboxyl groups · CPC title

• C11D1/38

  Cationic compounds {(C11D1/002, C11D1/004, C11D1/008 take precedence)} · CPC title