Method for producing plasticizer

Patent metadata

Field	Value
Publication number	US-12180332-B2
Application number	US-202117377531-A
Country	US
Kind code	B2
Filing date	Jul 16, 2021
Priority date	Aug 20, 2020
Publication date	Dec 31, 2024
Grant date	Dec 31, 2024

Abstract

A plasticizer and a method for producing the same are provided. The method for producing the plasticizer includes: reacting a reaction mixture at each of a plurality of temperature holding stages in a heating process to form a semi-finished product; and purifying the semi-finished product at each of a plurality of low pressure stages of a decompression process to obtain a plasticizer. A temperature range of the heating process is from 140° C. to 220° C., a pressure range of the decompression process is from 750 Torr to 20 Torr, and the reaction mixture contains dibasic acid (e.g., adipic acid), diol (e.g. 1,4-butanediol), monohydric alcohol (e.g., 2-ethylhexanol), and catalyst (e.g., titanium catalyst).

First claim

What is claimed is:

1. A method for producing a plasticizer, comprising:
mixing a dibasic acid, a diol, and a catalyst to form a reaction mixture;
adding a monohydric alcohol into the reaction mixture for a reaction and reacting the reaction mixture at each of a plurality of temperature holding stages in a heating process to form a semi-finished product; wherein a temperature range of the heating process ranges from 140° C. to 220° C.;
when an acid value of the semi-finished product ranging from 15 mg KOH/g to 20 mg KOH/g, terminating the heating process;
when an acid value of the semi-finished product ranging from 5 mg KOH/g to 10 mg KOH/g, purifying the semi-finished product at each of a plurality of low pressure stages of a decompression process to obtain the plasticizer, wherein a pressure range of the decompression process ranges from 750 Torr to 20 Torr; and
when the viscosity of the plasticizer ranging between 1500 cps to 3500 cps, terminating the reaction and the decompression process for unloading;
wherein a molecular weight distribution with Mw/Mn of the plasticizer is less than 1.35, and a weight average molecular weight of the plasticizer ranges from 2500 g/mol to 3800 g/mol.

2. The method for producing the plasticizer according to claim 1 , wherein the temperature holding stages are respectively a first temperature holding stage, a second temperature holding stage, a third temperature holding stage, and a fourth temperature holding stage, and wherein a temperature of the first temperature holding stage is from 140° C. to 155° C., a temperature of the second temperature holding stage is greater than 155° C. and up to 170° C., a temperature of the third temperature holding stage is greater than 170° C. and up to 190° C., and a temperature of the fourth holding stage is greater than 190° C. and up to 220° C.

3. The method for producing the plasticizer according to claim 2 , wherein a duration time of each of the first temperature holding stage, the second temperature holding stage, the third temperature holding stage, and the fourth temperature holding stage is from 0.5 hours to 4 hours.

4. The method for producing the plasticizer according to claim 2 , wherein the heating process of each of the temperature holding stages is completed at a temperature rising rate from 3° C./hour to 12° C./hour.

5. The method for producing the plasticizer according to claim 1 , wherein an overall average temperature rising rate of the heating process is from 4° C./hour to 8° C./hour.

6. The method for producing the plasticizer according to claim 1 , wherein the low pressure stages are respectively a first low pressure stage, a second low pressure stage, a third low pressure stage, and a fourth low pressure stage, and wherein a pressure of the first low pressure stage is from 750 Torr to 400 Torr, a pressure of the second low pressure stage is less than 400 Torr and as low as 300 Torr, a pressure of the third low pressure stage is less than 300 Torr and as low as 150 Torr, and a pressure of the fourth low pressure stage is less than 150 Torr and as low as 20 Torr.

7. The method for producing the plasticizer according to claim 6 , wherein a duration time of each of the first low pressure stage, the second low pressure stage, the third low pressure stage, and the fourth low pressure stage is from 0.5 hours to 3 hours.

8. The method for producing the plasticizer according to claim 6 , wherein the decompression process of each of the low pressure stages is completed at a decompression rate of from 75 Torr/hour to 175 Torr/hour.

9. The method for producing the plasticizer according to claim 1 , wherein an overall average decompression rate of the decompression process is from 75 Torr/hour to 125 Torr/hour.

10. The method for producing the plasticizer according to claim 1 , wherein in the reaction mixture, a molar ratio of the dibasic acid to the diol to the monohydric alcohol is 1:0.83-0.99:0.32-0.47.

Assignees

• Nan Ya Plastics Corp

Inventors

• Liao Te-Chao
• Chuang Jung-Jen
• Huang zhang-jian
• Hsu Che-Jung

Classifications

• C08G63/85

  Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof {(C08G63/823 takes precedence)} · CPC title

• C08G63/21

  in the presence of unsaturated monocarboxylic acids or unsaturated monohydric alcohols or reactive derivatives thereof · CPC title

• C08L67/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08G63/78

  Preparation processes · CPC title

• C08G63/20 Primary

  Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups · CPC title