Three-dimensional printing with wetting agent

Patent metadata

Field	Value
Publication number	US-12179263-B2
Application number	US-201917626988-A
Country	US
Kind code	B2
Filing date	Sep 5, 2019
Priority date	Sep 5, 2019
Publication date	Dec 31, 2024
Grant date	Dec 31, 2024

Abstract

A multi-fluid kit for three-dimensional printing can include a wetting agent and a binding agent. The wetting agent can include from 0 wt % to about 49.8 wt % water, from about 0.5 wt % to about 30 wt % film-forming organic solvent that can have a boiling point from greater than about 100° C. to about 350° C., and from about 30 wt % to about 99.5 wt % amphiphilic solvent that can have a boiling point from about 45° C. to less than about 100° C. The amphiphilic solvent can be water-miscible and can be present in the wetting agent at a greater concentration than the water and at a greater concentration than the film-forming solvent. The binding agent can include from about 2 wt % to about 30 wt % of a polymer binder dispersed in an aqueous liquid vehicle.

First claim

What is claimed is:

1. A multi-fluid kit for three-dimensional printing comprising:
a wetting agent including:
from 0 wt % to about 49.8 wt % water,
from about 0.2 wt % to about 30 wt % film-forming organic solvent having a boiling point from greater than about 100° C. to about 350° C., and
from about 30 wt % to about 99.5 wt % amphiphilic solvent having a boiling point from about 45° C. to less than about 100° C., wherein the amphiphilic solvent is water-miscible and is present in the wetting agent at a greater concentration than the water and at a greater concentration than the film-forming solvent; and

a binding agent including from about 2 wt % to about 30 wt % of a polymer binder dispersed in an aqueous liquid vehicle.

2. The multi-fluid kit of claim 1 , wherein the film-forming solvent includes aliphatic alcohol, aromatic alcohol, alkyl diol, glycol, glycol ether, polyglycol ether, 2-pyrrolidinone, caprolactam, formamide, acetamide, 1,2-butanediol, C3 to C12 alcohol, or a mixture thereof.

3. The multi-fluid kit of claim 1 , wherein the amphiphilic solvent includes ethanol, methanol, 1-propanol, isopropanol, 1-butanol, acetone, methyl ethyl keytone, dimethylformamide, tetrahydrofuran, 1,4-dioxane, acetonitrile, or a mixture thereof.

4. The multi-fluid kit of claim 1 , wherein a surface tension of the amphiphilic solvent ranges from about 20 N/m to about 40 N/m when measured at 20° C.

5. The multi-fluid kit of claim 1 , wherein the amphiphilic solvent is ethanol and the film-forming solvent is 2-pyrrolidinone.

6. The multi-fluid kit of claim 1 , wherein the binding agent further includes a co-solvent and the co-solvent in the binding agent is the same as the film-forming solvent in the wetting agent.

7. The multi-fluid kit of claim 1 , wherein the wetting agent is a nonaqueous wetting agent.

8. A three-dimensional printing kit comprising:
a wetting agent including:
from 0 wt % to about 49.8 wt % water,
from about 0.2 wt % to about 60 wt % film-forming organic solvent having a boiling point from greater than about 100° C. to about 350° C., and
from about 30 wt % to about 99.5 wt % amphiphilic water-miscible solvent having a boiling point from about 45° C. to less than about 100° C.;

a binding agent including from about 2 wt % to about 30 wt % of a polymer binder dispersed in an aqueous liquid vehicle; and
a particulate build material including from about 80 wt % to 100 wt % metal particles, ceramic particles, or both metal particles and ceramic particles.

9. The three-dimensional printing kit of claim 8 , wherein the film-forming solvent is present in the wetting agent at from about 1 wt % to about 15 wt %.

10. The three-dimensional printing kit of claim 8 , wherein the film-forming solvent includes 1,2-butanediol or other diols or glycols and the amphiphilic solvent includes ethanol.

11. The three-dimensional printing kit of claim 8 , wherein the particulate build material includes from about 90 wt % to 100 wt % of the metal particles, and the metal particles have D50 particle size distribution value of from about 3 μm to about 100 μm.

12. The three-dimensional printing kit of claim 8 , wherein the amphiphilic solvent is present in the wetting agent at a greater concentration than the water and at a greater concentration than the film-forming solvent.

13. A method of three-dimensional printing comprising:
iteratively applying individual build material layers of a particulate build material onto a powder bed, the particulate build material from about 80 wt % to 100 wt % metal particles, ceramic particles, or both metal particles and ceramic particles;
based on a 3D object model, iteratively and selectively applying a wetting agent to individual build material layers, wherein the wetting agent includes from 0 wt % to about 49.8 wt % water, from about 0.2 wt % to about 60 wt % film-forming organic solvent having a boiling point from greater than about 100° C. to about 350° C., and from about 30 wt % to about 99.5 wt % amphiphilic water-miscible solvent having a boiling point from about 45° C. to less than about 100° C.; and
based on a 3D object model, iteratively and selectively applying a binding agent to individual build material layers to define individually patterned object layers that become adhered to one another to form a layered green body object, wherein the binding agent includes from about 2 wt % to about 30 wt % of a polymer binder dispersed in an aqueous liquid vehicle.

14. The method of claim 13 , further comprising sintering the layered green body object to form a heat-fused article.

15. The method of claim 14 , wherein the fused three-dimensional object has a porosity from about 0.1 vol % to about 60 vol %.

Assignees

• Hewlett Packard Development Co

Inventors

• Kasperchik Vladek
• Wu Jennifer
• Monroe Michael G

Classifications

• B22F1/10

  Metallic powder containing lubricating or binding agents; Metallic powder containing organic material · CPC title

• B22F12/55

  Two or more means for feeding material · CPC title

• B33Y70/10 Primary

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• C09D11/322

  Pigment inks · CPC title

• C09D11/107

  from unsaturated acids or derivatives thereof · CPC title