Catalyst for hydrogenation reaction and preparation method for same

Patent metadata

Field	Value
Publication number	US-12172150-B2
Application number	US-202017623318-A
Country	US
Kind code	B2
Filing date	Jun 25, 2020
Priority date	Jun 28, 2019
Publication date	Dec 24, 2024
Grant date	Dec 24, 2024

Abstract

According to the present invention, when preparing a hydrogenation catalyst including nickel as an active ingredient, the reduction of nickel can be facilitated by using copper and sulfur as a promoter. In particular, the present invention can provide a catalyst which, while having a high nickel content, includes sulfur oxide and nickel oxide in a particular range, and thus exhibits even higher selective reduction degree for olefins while having high activity of the catalyst.

First claim

The invention claimed is:

1. A catalyst for a hydrogenation reaction, comprising:
0.5-3 parts by weight of at least one first promoter selected from copper and copper oxide, 3-15 parts by weight of at least one second promoter selected from sulfur and sulfur oxide, and 10-40 parts by weight of a silica carrier, based on 40-90 parts by weight of at least one active ingredient selected from nickel and nickel oxide.

2. The catalyst of claim 1 , wherein the catalyst comprises the active ingredient, the first promoter, and the second promoter, and
the second promoter is included in an amount of 3-15 parts by weight based on 100 parts by weight of all of the active ingredient, the first promoter, and the second promoter.

3. The catalyst of claim 1 , wherein the active ingredient is included in an amount of 50 parts by weight or more,
the catalyst comprises the second promoter and the active ingredient, and
the second promoter is included in an amount of 5-20 parts by weight based on 100 parts by weight of the active ingredient.

4. The catalyst of claim 1 , wherein the active ingredient has a crystallite size of 3-8 nm.

5. The catalyst of claim 1 , wherein the silica carrier is a porous carrier having a specific surface area of 200-400 m 2 /g and a pore size of 10-30 nm.

6. The catalyst of claim 1 , wherein the hydrogenation reaction has higher selectivity to olefins relative to aromatics.

7. The catalyst of claim 1 , wherein a reactant in the hydrogenation reaction is a hydrocarbon resin.

8. The catalyst of claim 7 , wherein the hydrocarbon resin comprises at least one selected from a hydrocarbon resin including dicyclopentadiene (DCPD), a hydrocarbon resin including C 5 fraction, and a hydrocarbon resin including C 9 fraction.

9. The catalyst of claim 1 , wherein the catalyst is in at least one form selected from a powder form, a particle form, and a granular form.

10. A method for preparing a catalyst for a hydrogenation reaction, the method comprising the steps of:
(a) preparing a first solution by dissolving 0.01-5 parts by weight of at least one promoter selected from copper and copper oxide and 10-40 parts by weight of a silica carrier in a solvent, based on 40-90 parts by weight of at least one active ingredient selected from nickel and nickel oxide;
(b) adding the first solution to a precipitation container and heating the first solution to a temperature of 60-100° C. while stirring;
(c) after the heating, preparing a second solution by adding a pH control agent and 3-15 parts by weight of at least one promoter selected from sulfur and sulfur oxide to a precipitation container, and adding the second solution dropwise to the first solution to prepare a precipitate;
(d) washing and filtering the precipitate and drying the precipitate to prepare a dried product; and
(e) reducing the dried product in a hydrogen atmosphere at a temperature of 200-500° C. to prepare a reduced product.

11. The method of claim 10 , further comprising, after the step (e), passivating the catalyst.

12. The method of claim 11 , wherein the passivating is performed with a nitrogen mixed gas including 0.1-20% oxygen.

13. The method of claim 11 , wherein the passivating is performed by deposition in a solution including an organic solvent.

14. The method of claim 10 , further comprising, after the step (d), calcining the prepared dried product in an air atmosphere of 200-500° C.

15. The method of claim 10 , wherein the preparing of the precipitate in the step (c) is performed at pH 7-9.

16. A hydrogenation method for hydrogenating a hydrocarbon resin, comprising contacting a hydrocarbon resin with hydrogen in the presence of the catalyst prepared by the method of claim 10 .

17. The hydrogenation method of claim 16 , wherein the hydrocarbon resin comprises at least one selected from a hydrocarbon resin including dicyclopentadiene (DCPD), a hydrocarbon resin including C 5 fraction, and a hydrocarbon resin including C 9 fraction.

18. The hydrogenation method of claim 16 , wherein the hydrocarbon resin has an aromatic/olefin hydrogenation ratio of 0.1-1.0 after a hydrogenation reaction.

19. The hydrogenation method of claim 16 , wherein the hydrocarbon resin has an APHA value of 30 or less after the hydrogenation reaction.

Assignees

• Hanwha Solutions Corp

Inventors

• Park Woo Jin
• Jeon Bong Sik
• Lee Yong Hee
• Jung Eui Geun

Classifications

• B01J37/18

  with gases containing free hydrogen · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J37/0236

  Drying, e.g. preparing a suspension, adding a soluble salt and drying · CPC title

• B01J37/20

  Sulfiding · CPC title