US12159995B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12159995-B2 |
| Application number | US-201916982959-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 26, 2019 |
| Priority date | Apr 5, 2018 |
| Publication date | Dec 3, 2024 |
| Grant date | Dec 3, 2024 |
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A negative electrode active material with high capacity and excellent cycle performance and rate performance is provided. In addition, a secondary battery including the negative electrode active material, and an electronic device including the secondary battery are provided. Nanosilicon is mixed with a solid electrolyte containing lithium, titanium, phosphorus, and oxygen, and graphene oxide is further added thereto. Then, graphene oxide contained in the mixture is reduced with ethanol in which ascorbic acid and lithium hydroxide hydrate are dissolved, so that the negative electrode active material is manufactured.
Opening claim text (preview).
The invention claimed is: 1. A negative electrode active material comprising: a secondary particle comprising: an active material being silicon; and a solid electrolyte; and a graphene compound coating the secondary particle, wherein the solid electrolyte contains lithium, titanium, phosphorus and oxygen. 2. The negative electrode active material according to claim 1 , wherein the solid electrolyte contains aluminum. 3. The negative electrode active material according to claim 1 , wherein the active material has a primary-particle size greater than or equal to 10 nm and less than or equal to 100 nm. 4. The negative electrode active material according to claim 1 , wherein the graphene compound contains graphene oxide. 5. The negative electrode active material according to claim 1 , wherein the graphene compound contains reduced graphene oxide. 6. A secondary battery comprising the negative electrode active material according to claim 1 . 7. An electronic device comprising the secondary battery according to claim 6 .
Oxides · CPC title
Negative electrodes · CPC title
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Electrodes based on metals, Si or alloys · CPC title
Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title
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