Methods of producing three-dimensional objects from materials having multiple mechanisms of hardening
US-9676963-B2 · Jun 13, 2017 · US
US12131102B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12131102-B2 |
| Application number | US-202117450575-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 12, 2021 |
| Priority date | Jun 27, 2018 |
| Publication date | Oct 29, 2024 |
| Grant date | Oct 29, 2024 |
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Various embodiments described herein provide a method of making an object from a three-dimensional geometry file and a light polymerizable resin on a light-transmissive window by projection of light through the window in a bottom-up stereolithography process. The method may comprise: slicing the file into a series of sequential images. Temperature fluctuations in the resin may be calculated for at least some of the sequential images upon light polymerization thereof based on sequential exposure of the resin to light, the light corresponding to the series of sequential images. During producing of the object, the production may be modified based on the calculated temperature fluctuations by: (i) reducing production speed during at least a portion of the production; (ii) activating a window cooler during at least a portion of the production; or (iii) increasing production speed during at least a portion of the production.
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What is claimed is: 1. A method of making an object from a three-dimensional geometry file and a light polymerizable resin on a light-transmissive window by projection of light through the window in a bottom-up stereolithography process, the method comprising the steps of: (a) slicing the file into a series of sequential images, each sequential image corresponding to a part geometry; (b) prior to beginning production of said object, calculating temperature fluctuations in the resin for at least a subset of said sequential images upon light polymerization thereof based on sequential exposure of the resin to light, the light corresponding to the series of sequential images, with the calculating carried out for each sequential image of said subset of said sequential images pixel-by-pixel based on resin properties and the corresponding part geometry; and (c) producing said object from said light polymerizable resin and said series of sequential images by bottom-up stereolithography, while (d) modifying said producing step based on said calculated temperature fluctuations by: (i) reducing production speed during at least a portion of the producing step that corresponds to at least one of the subset of said sequential images to avoid exceeding a predetermined temperature limit for said window; or (ii) activating a window cooler during at least a portion of said producing step that corresponds to at least one of the subset of said sequential images to cool said window and avoid exceeding the predetermined temperature limit for said window. 2. A method of making an object from a three-dimensional geometry file and a light polymerizable resin on a light-transmissive heated window by projection of light through the window in a bottom-up stereolithography process, said heated window comprising a composite of at least two layers of different materials joined with an adhesive layer, said method comprising the steps of: (a) slicing the file into a series of sequential images, each sequential image corresponding to a part geometry; (b) prior to beginning production of said object, calculating temperature fluctuations in the resin for at least a subset of said sequential images upon light polymerization thereof based on sequential exposure of the resin to light, the light corresponding to the series of sequential images, with the calculating carried out for each sequential image of said subset of said sequential images pixel-by-pixel based on resin properties and the corresponding part geometry and further based on window properties including a temperature profile for said heated window; and (c) producing said object from said light polymerizable resin and said series of sequential images by bottom-up stereolithography, while (d) modifying said producing step based on said calculated temperature fluctuations by: (i) reducing production speed during at least a portion of the producing step that corresponds to at least one of the subset of said sequential images to avoid exceeding a predetermined temperature limit for said; or (ii) activating a window cooler during at least a portion of said producing step that corresponds to at least one of the subset of said sequential images to cool said window and avoid exceeding the predetermined temperature limit for said window. 3. The method of claim 2 , wherein the subset of said sequential images includes images corresponding to portions of the object spaced apart from each other in a Z-direction in fixed increments. 4. The method of claim 2 , wherein said calculating step (b) is based on a solution of a partial differential equation. 5. The method of claim 2 , wherein said calculating step (b) is further based on planned or actual speed of said producing step (c). 6. The method of claim 2 , wherein said window cooler comprises a Peltier cooler. 7. The method of claim 2 , wherein said composite of said at least two layers of different materials comprises a first layer that is a polymer layer. 8. The method of claim 7 , wherein said polymer layer is a fluoropolymer layer. 9. The method of claim 7 , wherein said composite of said at least two layers of different materials comprises a second layer that is an inorganic supporting layer. 10. The method of claim 9 , wherein the inorganic supporting layer is one of a silicate glass, sapphire, or ALON (aluminum oxynitride) layer. 11. An additive manufacturing system comprising: an additive manufacturing apparatus configured to construct an object from a light polymerizable resin on a light-transmissive heated window by projection of light through the window in a bottom-up stereolithography process, said heated window comprising a composite of at least two different materials joined with an adhesive layer; a processor; and memory storing non-transitory computer readable instructions that, when executed by the processor, cause the processor to perform operations comprising: (a) slicing a three-dimensional geometry file into a series of sequential images, each sequential image corresponding to a part geometry; (b) prior to beginning production of said object, calculating temperature fluctuations in the resin for at least a subset of said sequential images upon light polymerization thereof based on sequential exposure of the resin to light, the light corresponding to the series of sequential images, with the calculating carried out for each sequential image of said subset of said sequential images pixel-by-pixel based on resin properties and the corresponding part geometry and further based on window properties including a temperature profile for said heated window; and (c) producing said object from said light polymerizable resin and said series of sequential images by bottom-up stereolithography, while (d) modifying said producing based on said calculated temperature fluctuations by: (i) reducing production speed during at least a portion of the producing step that corresponds to at least one of the subset of said sequential images to avoid exceeding a predetermined temperature limit for said window; or (ii) activating a window cooler during at least a portion of said producing step that corresponds to at least one of the subset of said sequential images to cool said window and avoid exceeding the predetermined temperature limit for said window. 12. The additive manufacturing system of claim 11 , wherein the subset of said sequential images includes images corresponding to portions of the object spaced apart from each other in a Z-direction in fixed increments. 13. The additive manufacturing system of claim 11 , wherein said instructions are configured to cause said calculating to be carried out before said producing or concurrently with said producing. 14. The additive manufacturing system of claim 11 , wherein said instructions are configured to cause said calculating to be based on planned or actual speed of said producing. 15. The additive manufacturing system of claim 11 , wherein said window cooler comprises a Peltier cooler. 16. The additive manufacturing system of claim 11 , wherein said composite of said at least two different materials comprises a first layer that is a polymer layer. 17. The additive manufacturing system of claim 16 , wherein said polymer layer is a fluoropolymer layer. 18. The additive manufacturing system of claim 16 , wherein said composite of said at least two different materials comprises a second layer that is an inorganic supporting layer. 19. The additive manufacturing system of claim 18 , wherein the inorganic support
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