Methods of treating fluids using thermal gradient osmosis

Patent metadata

Field	Value
Publication number	US-12128358-B2
Application number	US-202017009360-A
Country	US
Kind code	B2
Filing date	Sep 1, 2020
Priority date	Sep 4, 2019
Publication date	Oct 29, 2024
Grant date	Oct 29, 2024

Abstract

A method of treating a fluid comprises introducing a feed fluid stream comprising multiple materials to first side of a semi-permeable membrane. A draw fluid stream having a higher temperature than the feed fluid stream is introduced to second, opposing side of the semi-permeable membrane to form a thermal gradient across the semi-permeable membrane. One or more of the multiple materials of the feed fluid stream is drawn through the semi-permeable membrane and into the draw fluid stream via thermal gradient osmosis. A fluid treatment system and a thermal gradient osmosis apparatus are also described.

First claim

What is claimed is:

1. A method of treating a fluid, comprising:
introducing a feed fluid stream comprising multiple materials to a first side of a semi-permeable membrane;
introducing a draw fluid stream having a higher temperature than a temperature of the feed fluid stream to a second, opposing side of the semi-permeable membrane to form a thermal gradient across the semi-permeable membrane;
increasing a temperature of one or more portions of the semi-permeable membrane proximate the second, opposing side of the semi-permeable membrane relative to one or more other portions of the semi-permeable membrane proximate the first side of the semi-permeable membrane by physically contacting the semi-permeable membrane with at least a portion of a membrane heating device; and
drawing one or more of the multiple materials of the feed fluid stream through the semi-permeable membrane and into the draw fluid stream via thermal gradient osmosis.

2. A method of treating a fluid, comprising:
introducing a feed fluid stream comprising multiple materials to a first side of a semi-permeable membrane, a second, opposing side of the semi-permeable membrane coated with a porous, thermally reflective material comprising discrete, thermally reflective particles and a binder material;
introducing a draw fluid stream having a higher temperature than a temperature of the feed fluid stream to the second, opposing side of the semi-permeable membrane to form a thermal gradient across the semi-permeable membrane; and
drawing one or more of the multiple materials of the feed fluid stream through the semi-permeable membrane and into the draw fluid stream via thermal gradient osmosis.

3. The method of claim 2 , further comprising:
selecting the feed fluid stream to comprise an organic solution; and
selecting the semi-permeable membrane to comprise a hydrophobic material.

4. The method of claim 2 , further comprising:
selecting the feed fluid stream to comprise a solution including a solvent and at least one solute; and
selecting the semi-permeable membrane to comprise at least one material exhibiting an affinity to the at least one solute.

5. The method of claim 2 , further comprising:
selecting the feed fluid stream to comprise a gaseous material comprising two or more gases; and
selecting the semi-permeable membrane to comprise at least one material exhibiting an affinity to one of the two or more gases.

6. The method of claim 2 , further comprising selecting the semi-permeable membrane to promote selective migration of the one or more of the multiple materials of the feed fluid stream through the semi-permeable membrane and into the draw fluid stream via one or more of physical interactions, electrostatic interactions, magnetic interactions, pressure, and chemical activity.

7. The method of claim 2 , wherein introducing the feed fluid stream comprising multiple materials to the first side of the semi-permeable membrane comprises attaching at least one of a hydrophilic functional group, a hydrophobic functional group, an amphiphilic functional group, an organophilic functional group, an oxophilic functional group, a lipophilic functional group, or an oleophilic functional group to the semi-permeable membrane.

8. The method of claim 2 , wherein introducing the feed fluid stream comprising multiple materials to the first side of the semi-permeable membrane comprises forming the semi-permeable membrane including at least one of a hydrophilic material, a hydrophobic material, an amphiphilic material, an organophilic material, an oxophilic material, a lipophilic material, or an oleophilic material.

9. The method of claim 2 , wherein introducing the feed fluid stream comprising multiple materials to the first side of the semi-permeable membrane comprises forming the semi-permeable membrane from at least two different materials.

10. The method of claim 2 , wherein introducing the feed fluid stream comprising multiple materials to the first side of the semi-permeable membrane comprises forming the semi-permeable membrane including a multi-layer structure.

11. The method of claim 10 , wherein forming the semi-permeable membrane including the multi-layer structure comprises forming the semi-permeable membrane including the multi-layer structure comprising a hydrophilic support layer and a hydrophilic, two dimensional material.

12. A method of treating a fluid, comprising:
introducing a feed fluid stream comprising multiple materials to a first side of a semi-permeable membrane;
selecting the feed fluid stream to comprise an aqueous solution;
selecting the semi-permeable membrane to comprise a hydrophilic support layer and a hydrophilic selective layer on the hydrophilic support layer;
introducing a draw fluid stream having a higher temperature than a temperature of the feed fluid stream to a second, opposing side of the semi-permeable membrane to form a thermal gradient across the semi-permeable membrane;
positioning a thermally reflective assembly in communication with the draw fluid stream; and
drawing one or more of the multiple materials of the feed fluid stream through the semi-permeable membrane and into the draw fluid stream via thermal gradient osmosis.

13. The method of claim 12 , further comprising heating an initial draw fluid stream using a heating apparatus upstream of the semi-permeable membrane to form the draw fluid stream.

14. The method of claim 13 , further comprising employing one or more of solar thermal energy, wind energy, hydropower energy, geothermal energy, nuclear energy, fuel cell energy, combustion-based energy, waste heat, and recycled heat using the heating apparatus.

15. The method of claim 12 , wherein drawing one or more of the multiple materials of the feed fluid stream through the semi-permeable membrane and into the draw fluid stream via thermal gradient osmosis comprises drawing dissolved solids of the feed fluid stream through the semi-permeable membrane and into the draw fluid stream via thermal gradient osmosis.

16. The method of claim 12 , wherein positioning the thermally reflective assembly in communication with the draw fluid stream comprises positioning the thermally reflective assembly including at least one porous, thermally reflective structure in communication with the draw fluid stream.

17. The method of claim 12 , wherein positioning the thermally reflective assembly in communication with the draw fluid stream comprises positioning the thermally reflective assembly including at least one thermally isolated structure in communication with the draw fluid stream.

18. The method of claim 17 , wherein positioning the thermally reflective assembly including the at least one thermally isolated structure in communication with the draw fluid stream comprises positioning the thermally reflective assembly including the at least one thermally isolated structure in communication with the draw fluid stream to reflect thermal energy off of the thermally isolated structure back into the draw fluid stream.

19. The method of claim 12 , further comprising forming the semi-permeable membrane of a two dimensional material having three or fewer monolayers bonded together through intramolecular forces.

Assignees

• Battelle Energy Alliance Llc

Inventors

• Wilson Aaron D
• Orme Christopher J
• Klaehn John R
• Adhikari Birendra
• Stewart Frederick F
• Snyder Seth W

Classifications

• B01D2313/221

  Heat exchangers · CPC title

• B01D2313/903

  Integrated control or detection device · CPC title

• B01D69/1216

  Three or more layers · CPC title

• B01D69/107

  Organic support material · CPC title

• B01D61/002

  Forward osmosis or direct osmosis · CPC title