Methods of forming alloys by reducing metal oxides

Patent metadata

Field	Value
Publication number	US-12116684-B2
Application number	US-201916388272-A
Country	US
Kind code	B2
Filing date	Apr 18, 2019
Priority date	Apr 24, 2018
Publication date	Oct 15, 2024
Grant date	Oct 15, 2024

Abstract

A method of forming an alloy includes disposing a first metal oxide and a second metal oxide in a molten salt. The molten salt is in contact with a working electrode and a counter electrode. An electrical potential is applied between the counter electrode and the working electrode to co-reduce the first metal oxide and the second metal oxide to form a first metal and a second metal, respectively.

First claim

What is claimed is:

1. A method of forming an alloy, the method comprising:
disposing a first metal oxide comprising cobalt oxide and a second metal oxide comprising nickel oxide in a molten salt, the molten salt in contact with a working electrode comprising nickel and a counter electrode; and
applying an electrical potential between the counter electrode and the working electrode to co-reduce the first metal oxide and the second metal oxide to form a cobalt-nickel alloy.

2. The method of claim 1 , further comprising selecting the counter electrode to comprise ruthenium, lithium iridate, lithium ruthenate, a lithium rhodate, a lithium tin oxygen, a lithium manganese oxygen compound, calcium ruthenate, strontium ruthenium ternary compounds, calcium iridium oxide, strontium iridate, calcium platinate, strontium platinate, magnesium ruthenate, magnesium iridate, sodium ruthenate, sodium iridate, potassium iridate, or potassium ruthenate.

3. The method of claim 2 , further comprising selecting the counter electrode to comprise the ruthenium, lithium iridate, lithium ruthenate, a lithium rhodate, a lithium tin oxygen, a lithium manganese oxygen compound, calcium ruthenate, strontium ruthenium ternary compounds, calcium iridium oxide, strontium iridate, calcium platinate, strontium platinate, magnesium ruthenate, magnesium iridate, sodium ruthenate, sodium iridate, potassium iridate, or potassium ruthenate over a base material.

4. The method of claim 1 , further comprising maintaining the molten salt at a temperature of at least 750° C.

5. The method of claim 1 , wherein applying the electrical potential between the counter electrode and the working electrode comprises maintaining the molten salt under an inert atmosphere.

6. The method of claim 5 , wherein maintaining the molten salt under the inert atmosphere comprises maintaining the molten salt under an atmosphere consisting essentially of argon.

7. The method of claim 1 , further comprising disposing a reference electrode in contact with the molten salt.

8. The method of claim 1 , further comprising selecting the molten salt to comprise one of potassium chloride, potassium bromide, cesium bromide, calcium bromide, or strontium bromide.

9. A method of forming an alloy, the method comprising:
disposing a first metal oxide and a second metal oxide in a molten salt, the molten salt in contact with a working electrode and a counter electrode, the working electrode comprising a metal selected from the group consisting of iron, nickel, cobalt, and combinations thereof; and
applying an electrical potential between the counter electrode and the working electrode to co-reduce the first metal oxide and the second metal oxide to form a nickel-rich alloy of the first metal and the second metal.

10. The method of claim 9 , wherein applying an electrical potential between the counter electrode and the working electrode comprises transferring a metal from the working electrode to the alloy, the working electrode consisting essentially of the metal.

11. A method of reducing metal oxides, the method comprising:
providing an electrochemical cell comprising a working electrode, a counter electrode comprising a platinum-group metal, and a molten salt in contact with the working electrode and the counter electrode;
disposing a material comprising at least two metal oxides in contact with the molten salt and the working electrode, one of the at least two metal oxides comprising nickel oxide; and
providing an electric current between the counter electrode and the working electrode to reduce the at least two metal oxides to form an alloy comprising at least two metals formed by reduction, the alloy comprising a nickel-cobalt alloy, a samarium-cobalt alloy, or an iron-cobalt-nickel alloy.

12. The method of claim 11 , further comprising selecting the counter electrode to comprise a metal selected from the group consisting of iridium, ruthenium, and platinum.

13. The method of claim 11 , further comprising selecting the counter electrode to comprise a substrate material selected from the group consisting of high-density graphite, molybdenum, tantalum, titanium, nickel, chromium, tungsten, and combinations thereof, wherein the substrate material is coated with the platinum-group metal.

14. The method of claim 11 , further comprising selecting the counter electrode to comprise a substrate material coated with a coating material comprising the platinum-group metal and having a thickness between about 3.0 mm and about 5.0 mm.

15. The method of claim 11 , further comprising selecting the working electrode to consist essentially of nickel.

16. The method of claim 1 , wherein the working electrode consists essentially of nickel, and wherein applying an electrical potential between the counter electrode and the working electrode to co-reduce the first metal oxide and the second metal oxide to form a cobalt-nickel alloy further comprises alloying nickel from the working electrode to form the cobalt-nickel alloy.

17. The method of claim 1 , wherein applying an electrical potential between the counter electrode and the working electrode to form a cobalt-nickel alloy comprises forming the cobalt-nickel alloy comprising a molar ratio of cobalt to nickel that is substantially the same as a molar ratio of the cobalt oxide to nickel oxide.

18. The method of claim 9 , wherein applying an electrical potential between the counter electrode and the working electrode to co-reduce the first metal oxide and the second metal oxide to form a nickel-rich alloy of the first metal and the second metal comprises forming a nickel-rich cobalt-nickel alloy.

19. The method of claim 11 , further comprising:
selecting the working electrode to consist essentially of a metal; and
alloying the metal of the working electrode with the alloy comprising the at least two metals formed by reduction.

20. The method of claim 11 , wherein providing an electrochemical cell comprising a working electrode, a counter electrode comprising a platinum-group metal, and a molten salt comprises selecting the working electrode to consist essentially of cobalt.

Assignees

• Battelle Energy Alliance Llc

Inventors

• Tripathy Prabhat K

Classifications

• C25C7/025

  used in cells for the electrolysis of melts · CPC title

• C25C3/36

  Alloys obtained by cathodic reduction of all their ions · CPC title

• C25C5/04 Primary

  from melts · CPC title