Method for improving corrosion resistance of neodymium-iron-boron materials by low-temperature oxidation and/or nitridation treatment

Patent metadata

Field	Value
Publication number	US-12112884-B2
Application number	US-202217711551-A
Country	US
Kind code	B2
Filing date	Apr 1, 2022
Priority date	Mar 2, 2022
Publication date	Oct 8, 2024
Grant date	Oct 8, 2024

Abstract

A method for improving the corrosion resistance of NdFeB materials is provided. The method includes in-situ growing a layer of oxide, nitride, or oxynitride on the surface of NdFeB magnet correspondingly by performing at least one of an oxidation treatment and a nitridation treatment at low temperature in a range of 200˜400° C., thereby significantly improving the corrosion resistance of the magnet. The method is simple to operate, low-cost, green, safe, and efficient. Depending on the parameters of the low-temperature oxidation and/or nitridation treatment, the thickness of the oxide, nitride, or oxynitride layer is adjustable from 10 nm to 100 μm, which can improve the corrosion resistance of the magnet while maintaining excellent magnetic properties. Moreover, the thin surface layer is in-situ grown on the NdFeB substrate, which is strong and stable over a long service period and can be applied for mass production.

First claim

What is claimed is:

1. A method for improving corrosion resistance of neodymium-iron-boron (NdFeB) materials, consisting of:
in-situ growing at least one selected from a group consisting of an oxide layer, a nitride layer and an oxynitride layer on a surface of a NdFeB magnet by correspondingly performing at least one of oxidation treatment and nitridation treatment of the NdFeB magnet;
wherein the “performing at least one of the oxidation treatment and the nitridation treatment” consists of:
providing the NdFeB magnet in a tube furnace or an atmosphere furnace;
vacuumizing to 10 −2 -10 −4 pascals (Pa) in the tube furnace or the atmosphere furnace;
introducing at least one selected a group consisting of oxygen (O 2 ), nitrogen (N 2 ), ammonia gas (NH 3 ) and water vapor with a flow rate in a range of 200-5000 milliliters per minute (mL/min) into the tube furnace or the atmosphere furnace; and
controlling a temperature of the at least one of the oxidation treatment and the nitridation treatment in a range of 300-350 degrees Celsius (° C.) for 0.5-24 hours;
wherein the oxide layer consists of an oxide of one or more elements from the NdFeB magnet; the nitride layer consists of a nitride of one or more elements from the NdFeB magnet; and the oxynitride layer consists of an oxynitride of one or more elements from the NdFeB magnet.

2. The method according to claim 1 , wherein a thickness of the at least one selected from the group consisting of the oxide, the nitride and the oxynitride layer is adjustable in a range from 10 nanometers (nm) to 100 micrometers (μm).

3. The method according to claim 1 , wherein components of the NdFeB magnet, in atomic percent, are (RE a RE′ 1-a ) x (Fe b M 1-b ) 100-x-y-z M′ y B z ,
where RE is neodymium (Nd) or a mixture of neodymium (Nd) and at least one of lanthanide elements except lanthanum (La), cerium (Ce) and yttrium (Y); RE′ is at least one selected from a group consisting of La, Ce and Y; Fe is iron; M is one or two of cobalt (Co) and nickel (Ni); M′ is at least one selected from a group consisting of niobium (Nb), zirconium (Zr), tantalum (Ta), vanadium (V), aluminum (Al), copper (Cu), gallium (Ga), titanium (Ti), chromium (Cr), molybdenum (Mo), manganese (Mn), silver (Ag), gold (Au), lead (Pb) and silicon (Si); B is boron; and a, b, x, y, and z respectively satisfy conditions comprising: 0.55≤a≤1, 0.8≤b≤1, 12≤x≤18, 0≤y≤2, and 5.5≤z≤6.5.

Assignees

• Univ Zhejiang

Inventors

• Yan Mi
• Jin Jiaying
• Chen Wang
• Wu Chen

Classifications

• H01F1/057

  and IIIa elements, e.g. Nd2Fe14B · CPC title

• C21D8/1255 Primary

  with diffusion of elements, e.g. decarburising, nitriding · CPC title

• H01F1/0577

  sintered · CPC title

• H01F41/026 Primary

  protecting methods against environmental influences, e.g. oxygen, by surface treatment (magnetic particles with skin H01F1/061, H01F1/09, H01F1/24, H01F1/33 and G11B5/706) · CPC title

• Y02E10/72

  Wind turbines with rotation axis in wind direction · CPC title