Compositions and foam compositions containing composite particles, articles, composite particles, and methods

Patent metadata

Field	Value
Publication number	US-12110375-B2
Application number	US-202318449942-A
Country	US
Kind code	B2
Filing date	Aug 15, 2023
Priority date	Jun 18, 2019
Publication date	Oct 8, 2024
Grant date	Oct 8, 2024

Abstract

Compositions are provided including an uncrosslinked thermoplastic nitrogen-containing matrix material and composite particles distributed in the matrix material. The composite particles each include a chemical blowing agent particle encapsulated within a shell including an uncrosslinked thermoplastic material. The uncrosslinked thermoplastic material exhibits at least a certain minimum complex viscosity at a decomposition temperature of the chemical blowing agent particle. Also described are foam compositions and articles including the foam compositions, such as a sheet or multilayer construction. Composite particles are further provided. Methods of making the foam compositions are additionally described herein. Also, polishing pads, polishing systems, and methods of polishing a substrate are provided.

First claim

What is claimed:

1. A composite particle comprising:
a chemical blowing agent particle encapsulated within a shell including an uncrosslinked thermoplastic material; and a co-encapsulated metal salt of the form MX or M (X) 2 ,
wherein M is zinc, calcium, cadmium, potassium, barium, strontium, magnesium, mercury, titanium, tin, lead, sodium, lithium, or cesium,
wherein X is an organic ligand or an inorganic ligand containing a nitrate, phosphate, phosphite, sulfate, carbonate, oxalic acid, halide, para-toluenesulfonate, tetrafluoroborate, perchlorate, hydroxide, cyanide moiety, or hydrates thereof,
wherein the uncrosslinked thermoplastic material exhibits a complex viscosity of 3,700 Pascal seconds (Pa·s) or greater at a decomposition temperature of the chemical blowing agent particle,
wherein the chemical blowing agent is selected from a diazocompound, a sulfonyl hydrazide, a tetrazole, a nitrosocompound, an acyl sulfonyl hydrazide, hydrazones, thiatriazoles, azides, sulfonyl azides, oxalates, thiatrizene dioxides, isatoic anhydride, or combinations thereof, and
wherein the composite particle is free of liquid hydrocarbon physical blowing agents.

2. The composite particle of claim 1 , wherein the metal salt comprises zinc nitrate, zinc sulfate, zinc phosphate, zinc chloride, zinc carbonate, zinc p-toluenesulfonate hydrate, zinc tetrafluoroborate hydrate, zinc perchlorate, zinc hydroxide, zinc cyanide, calcium nitrate, calcium sulfate, calcium phosphate, calcium carbonate, barium phosphate, barium nitrate, barium sulfate, cadmium phosphate, cadmium nitrate, cadmium sulfate, or combinations thereof.

3. The composite particle of claim 1 , wherein the metal salt comprises zinc nitrate, zinc sulfate, or zinc chloride.

4. The composite particle of claim 1 , wherein the shell surrounds a single core chemical blowing agent particle.

5. The composite particle of claim 1 , wherein the uncrosslinked thermoplastic material of the shell is selected from the group consisting of a starch, polyvinyl pyrollidone (PVP), a copolymer of vinylpyrrolidone and vinyl acetate, a polypropylene-based elastomer, a styrene-isoprene-styrene copolymer, a (C1-C3) alkyl cellulose, a hydroxyl (C1-C3) alkylcellulose, carboxy methylcellulose, sodium carboxymethyl cellulose, a polyoxazoline, a silicone-based thermoplastic polymer, an olefin-based thermoplastic polymer, a phenoxy resin, a polyamide, or combinations thereof.

6. The composite particle of claim 1 , wherein the chemical blowing agent is selected from 1,1-azodicarboxamide, p-toluenesulfonyl hydrazine, or 5H-phenyl tetrazole.

7. The composite particle of claim 1 , wherein the composite particle comprises a diameter of 1 to 60 micrometers, inclusive.

8. The composite particle of claim 1 , wherein the chemical blowing agent particle is present in an amount of at least 1 wt. % to 80 wt. %, based on the total weight of the composite particle.

9. The composite particle of claim 1 , wherein the shell is present in an amount of at least 20 wt. % to 99 wt. %, based on the total weight of the composite particle.

10. A composition comprising an uncrosslinked thermoplastic matrix material and a plurality of the composite particles of claim 1 distributed in the uncrosslinked thermoplastic matrix material.

11. The composition of claim 10 , wherein the uncrosslinked thermoplastic matrix material is selected from the group consisting of a polyorganosiloxane, a styrenic block copolymer, a styrenic polymer, a polystyrene, a polyolefin, a polyolefin copolymer, a polyvinyl chloride (PVC), an ethylene vinyl acetate, a polyamide, a polyurea, a polyurethane, a polyetherimine, a polyethyleneimine, a polyiminothioether, a polyaminoamide, a polyetherimide, a polyoxazoline, a polyimide, a polysulfonamide, a poly (amide imide), a poly (ester amide), a polyacrylate, a polymethacrylate, an acrylate copolymer, and an acrylic block copolymer.

12. The composition of claim 10 , wherein the uncrosslinked thermoplastic matrix material comprises a polylactic acid (PLA) and wherein the composition further comprises a polymer having a T g of 25 degrees Celsius or greater; a crosslinking agent; and a crosslink catalyst.

13. The composition of claim 10 , further comprising a crosslinking agent, a crosslink catalyst, or both.

14. A closed cell foam obtained from a composition comprising an uncrosslinked thermoplastic matrix material and a plurality of the composite particles of claim 1 distributed in the uncrosslinked thermoplastic matrix material.

15. The closed cell foam of claim 14 , wherein the uncrosslinked thermoplastic matrix material is selected from the group consisting of a polyorganosiloxane, a styrenic block copolymer, a polystyrene, a polyolefin, a polyolefin copolymer, a polyvinyl chloride (PVC), an ethylene vinyl acetate, a polyamide, a polyurea, a polyurethane, a polyetherimine, a polyethyleneimine, a polyiminothioether, a polyaminoamide, a polyetherimide, a polyoxazoline, a polyimide, a polysulfonamide, a poly (amide imide), a poly (ester amide), a polyacrylate, a polymethacrylate, an acrylate copolymer, and an acrylic block copolymer.

16. The closed cell foam of claim 14 , wherein the uncrosslinked thermoplastic matrix material includes a polylactic acid (PLA) and wherein the foam composition further comprises a polymer having a T g of 25 degrees Celsius or greater; a crosslinking agent; and a crosslink catalyst.

17. The closed cell foam of claim 14 , wherein the composition further comprises a crosslinking agent, a crosslink catalyst, or both.

Assignees

• 3M Innovative Properties Company

Inventors

• Fishman Joshua M
• Kalish Jeffrey P
• Meree Caitlin E
• Lin Qin
• Lee Nicholas K
• Yao Li
• Kalgutkar Rajdeep S
• Lehuu Duy K
• Amos David T

Classifications

• C08J2375/04

  Polyurethanes · CPC title

• C08J2439/06

  Homopolymers or copolymers of N-vinyl-pyrrolidones · CPC title

• C08J2403/08

  Ethers · CPC title

• C08J9/102

  Azo-compounds · CPC title

• C08J9/104

  Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof · CPC title