Compositions and foam compositions containing composite particles, articles, composite particles, and methods

Patent metadata

Field	Value
Publication number	US-11767406-B2
Application number	US-202017607144-A
Country	US
Kind code	B2
Filing date	Jun 9, 2020
Priority date	Jun 18, 2019
Publication date	Sep 26, 2023
Grant date	Sep 26, 2023

Abstract

Compositions are provided including an uncrosslinked thermoplastic nitrogen-containing matrix material and composite particles distributed in the matrix material. The composite particles each include a chemical blowing agent particle encapsulated within a shell including an uncrosslinked thermoplastic material. The uncrosslinked thermoplastic material exhibits at least a certain minimum complex viscosity at a decomposition temperature of the chemical blowing agent particle. Also described are foam compositions and particles including the foam compositions, such as a sheet or multilayer construction. Composite particles are further provided. Methods of making the foam compositions are additionally described herein. Also, polishing pads, polishing systems, and methods of polishing a substrate are provided.

First claim

What is claimed:

1. A composition comprising:
an uncrosslinked thermoplastic nitrogen-containing matrix material, and
a plurality of composite particles distributed in the uncrosslinked thermoplastic nitrogen-containing matrix material,
wherein the composition exhibits an elastic modulus of 0.5 megaPascals (MPa) or greater,
wherein the uncrosslinked thermoplastic nitrogen-containing matrix material comprises a polyamide, a polyurethane, a polyetherimine, a polyethyleneimine, a polyimide, a polyurea, a polyoxazoline, a polyiminothioether, a polyaminoamide, a polysulfonamide, a polyetherimide, a poly(amide imide), a poly(ester amide), or combinations thereof,
wherein the plurality of composite particles is present in an amount of 0.1 to 20 wt. %, inclusive, of the total weight of the composition, and
wherein the plurality of composite particles each comprises:
a core-shell particle comprising a core which is free of liquid hydrocarbon physical blowing agents, the core comprising at least one solid chemical blowing agent particle, the core encapsulated within a shell comprising an uncrosslinked thermoplastic material,
wherein the uncrosslinked thermoplastic material exhibits a complex viscosity of 3,700 Pa·s or greater at a decomposition temperature of the chemical blowing agent particle, and
wherein the chemical blowing agent is selected from a diazocompound, a sulfonyl hydrazide, a tetrazole, a nitrosocompound, an acyl sulfonyl hydrazide, hydrazones, thiatriazoles, azides, sulfonyl azides, oxalates, thiatrizene dioxides, isatoic anhydride, or combinations thereof.

2. The composition of claim 1 , wherein the uncrosslinked thermoplastic nitrogen-containing matrix material comprises a polyurethane.

3. The composition of claim 1 , wherein the uncrosslinked thermoplastic nitrogen-containing matrix material comprises an acid-terminated polyamide or an amine-terminated polyamide.

4. The composition of claim 1 , further comprising a crosslinking agent, a crosslink catalyst, or both.

5. The composition of claim 1 , wherein the plurality of composite particles is present in an amount of 0.5 to 15 wt. %, 0.5 to 10 wt. %, 1 to 8 wt. %, or 10 to 17 wt. %, inclusive, of the total weight of the composition.

6. The composition of claim 1 , wherein the chemical blowing agent is 1,1-azodicarboxamide, 5H-phenyltetrazole, isatoic anhydride, p-toluenesulfonyl semicarbazide, or p-toluenesulfonylhydrazine.

7. A foam composition comprising:
a closed cell foam material obtained from a composition comprising an uncrosslinked thermoplastic nitrogen-containing matrix material, and a plurality of composite particles distributed in the uncrosslinked thermoplastic nitrogen-containing matrix material,
wherein the uncrosslinked thermoplastic nitrogen-containing matrix material comprises a polyamide, a polyurethane, a polyetherimine, a polyethyleneimine, a polyimide, a polyurea, a polyoxazoline, a polyiminothioether, a polyaminoamide, a polysulfonamide, a polyetherimide, a poly(amide imide), a poly(ester amide), or combinations thereof,
wherein the plurality of composite particles is present in an amount of 0.1 to 20 wt. %, inclusive, of the total weight of the composition,
wherein the plurality of composite particles each comprises:
a core-shell particle comprising a core which is free of liquid hydrocarbon physical blowing agents, the core comprising at least one solid chemical blowing agent particle, the core encapsulated within a shell comprising an uncrosslinked thermoplastic material,
wherein the uncrosslinked thermoplastic material exhibits a complex viscosity of 3,700 Pa·s or greater at a decomposition temperature of the chemical blowing agent particle, and
wherein the chemical blowing agent is selected from a diazocompound, a sulfonyl hydrazide, a tetrazole, a nitrosocompound, an acyl sulfonyl hydrazide, hydrazones, thiatriazoles, azides, sulfonyl azides, oxalates, thiatrizene dioxides, isatoic anhydride, or combinations thereof.

8. The foam composition of claim 7 , wherein the foam composition comprises a smooth major surface and an opposing major surface comprising replicated features.

9. The foam composition of claim 7 , having an average cell size of 250 micrometers or less, 150 micrometers or less, 120 micrometers or less, 100 micrometers or less, 80 micrometers or less, or 60 micrometers or less.

10. The foam composition of claim 7 , wherein the uncrosslinked thermoplastic nitrogen-containing matrix material comprises a polyamide, a polyurethane, a polyimide, a polyurea, a polyetherimide, a poly(amide imide), or combinations thereof.

11. The foam composition of claim 7 , wherein the foam composition has a cell density of 1 to 1,000 cells per square millimeter (cells/mm 2 ) or 4 to 500 cells/mm 2 .

12. An article comprising the foam composition of claim 7 attached to a substrate.

13. The article of claim 12 , wherein the article is a multilayer article and the foam composition is a layer of foam disposed in between a layer of a second material and a layer of a third material.

14. A polishing pad comprising a foam composition of claim 7 .

15. A polishing system comprising the polishing pad of claim 14 and a polishing solution.

16. A method of making a foam composition of claim 7 , the method comprising:
a) compressing a mixture comprising: an uncrosslinked thermoplastic nitrogen-containing matrix material and a plurality of composite particles distributed in the uncrosslinked thermoplastic nitrogen-containing matrix material to form a composition, wherein the composition exhibits an elastic modulus of 0.5 megaPascals (MPa) or greater,
wherein the uncrosslinked thermoplastic nitrogen-containing matrix material comprises a polyamide, a polyurethane, a polyetherimine, a polyethyleneimine, a polyimide, a polyurea, a polyoxazoline, a polyiminothioether, a polyaminoamide, a polysulfonamide, a polyetherimide, a poly(amide imide), a poly(ester amide), or combinations thereof,
wherein the plurality of composite particles is present in an amount of 0.1 to 20 wt. %, inclusive, of the total weight of the composition, and wherein the plurality of composite particles each comprises:
a core-shell particle comprising a core which is free of liquid hydrocarbon physical blowing agents, the core comprising at least one solid chemical blowing agent particle, the core encapsulated within a shell comprising an uncrosslinked thermoplastic material,
wherein the uncrosslinked thermoplastic material exhibits a complex viscosity of 3,700 Pa·s or greater at a decomposition temperature of the chemical blowing agent particle, and
wherein the chemical blowing agent is selected from a diazocompound, a sulfonyl hydrazide, a tetrazole, a nitrosocompound, an acyl sulfonyl hydrazide, hydrazones, thiatriazoles, azides, sulfonyl azides, oxalates, thiatrizene dioxides, isatoic anhydride, or combinations thereof; and

b) heating the compressed mixture, thereby forming the foam composition.

17. The method of claim 16 , wherein the mixture is compressed, heated, or both in a multilayer extruder.

18. The method of claim 16 , further comprising casting the mixture into a replication mold while the heated mixture is forming the foam composition, thereby imparting a plurality of replicated features on a major surface of the foam composition.

Assignees

• 3M Innovative Properties Company

Inventors

• Fishman Joshua M
• Kalish Jeffrey P
• Meree Caitlin E
• Lin Qin
• Lee Nicholas K
• Yao Li
• Kalgutkar Rajdeep S
• Lehuu Duy K
• Amos David T

Classifications

• C08J2375/04

  Polyurethanes · CPC title

• C08J2439/06

  Homopolymers or copolymers of N-vinyl-pyrrolidones · CPC title

• C08J2403/08

  Ethers · CPC title

• C08J9/102

  Azo-compounds · CPC title

• C08J9/104

  Hydrazines; Hydrazides; Semicarbazides; Semicarbazones; Hydrazones; Derivatives thereof · CPC title