Heat-curable resin composition

Patent metadata

Field	Value
Publication number	US-12110356-B2
Application number	US-202217869197-A
Country	US
Kind code	B2
Filing date	Jul 20, 2022
Priority date	Aug 2, 2021
Publication date	Oct 8, 2024
Grant date	Oct 8, 2024

Abstract

Provided is a heat-curable resin composition capable of being turned into a cured product having a low relative permittivity, a low dielectric tangent, an excellent adhesiveness and a high resistance. The heat-curable resin composition contains:(A) a citraconimide compound;(B) an epoxy resin;(C) an epoxy resin curing agent; and(D) a curing accelerator.

First claim

What is claimed is:

1. A heat-curable resin composition comprising:
one or more of each of
(A) a citraconimide compound;
(B) an epoxy resin;
(C) an epoxy resin curing agent; and
(D) a curing accelerator,
wherein the epoxy resin curing agent (C) is at least one selected from an amine compound, a phenolic compound, an acid anhydride compound and an active ester compound.

2. The heat-curable resin composition according to claim 1 , wherein the citraconimide compound (A) is a biscitraconimide compound represented by the following formula (1):

wherein A represents a divalent organic group.

3. The heat-curable resin composition according to claim 2 , wherein A in the formula (1) is selected from the groups of the following structures and dimer acid skeleton-derived hydrocarbon groups:

wherein * represents a bond to a nitrogen atom in the citraconimide group; n is 1 to 20.

4. The heat-curable resin composition according to claim 1 , wherein the curing accelerator (D) contains at least one of an imidazole-based curing accelerator, an organic phosphorus-based curing accelerator and a tertiary amine-based curing accelerator.

5. The heat-curable resin composition according to claim 1 , wherein the epoxy resin (B) has at least two epoxy groups per each molecule.

6. The heat-curable resin composition according to claim 1 , wherein
the component (B) is contained in an amount of 1 to 900 parts by mass per 100 parts by mass of the component (A),
a molar equivalent ratio of functional groups in the curing agent as the component (C) that are reactive with epoxy groups to 1 molar equivalent of epoxy groups in the epoxy resin (B) is 0.1 to 4.0, and
the component (D) is contained in an amount of 0.01 to 20 parts by mass per 100 parts by mass of the component (A).

7. The heat-curable resin composition according to claim 1 , wherein the citraconimide compound (A) has a number average molecular weight of 200 to 10,000.

8. An adhesive agent comprising the heat-curable resin composition according to claim 1 .

9. A semiconductor encapsulation material comprising the heat-curable resin composition according to claim 1 .

10. A heat-curable resin composition consisting essentially of:
one or more of each of
(A) a citraconimide compound;
(B) an epoxy resin;
(C) an epoxy resin curing agent;
(D) a curing accelerator; and
optionally, one or more of an inorganic filler, a flame retardant, an ion trapping agent, an antioxidant, an adhesiveness imparting agent, a low stress agent and a colorant,
wherein the epoxy resin curing agent (C) is at least one selected from an amine compound, a phenolic compound, an acid anhydride compound and an active ester compound.

11. The heat-curable resin composition according to claim 1 , which consists of one or more of each of said components (A), (B), (C) and (D) and optionally one or more of an inorganic filler, a flame retardant, an ion trapping agent, an antioxidant, an adhesiveness imparting agent, a low stress agent and a colorant.

12. The heat-curable resin composition according to claim 11 , which consists of one or more of each of said components (A), (B), (C) and (D).

13. The heat-curable resin composition according to claim 1 , which comprises
one or more of each of
(A);
(B) in an amount of 3 to 200 parts by mass, per 100 parts by mass of the component (A),
(C) in an amount at which a molar equivalent ratio of the functional groups in the epoxy resin curing agent to 1 molar equivalent of the epoxy groups in the component (B) is 0.2 to 2.0; particularly preferably 0.4 to 1.0; and
(D) in an amount of preferably 0.5 to 10 parts by mass, per 100 parts by mass of the component (A).

14. The heat-curable resin composition according to claim 11 , which consists of
one or more of each of
(A);
(B) in an amount of 3 to 200 parts by mass, per 100 parts by mass of the component (A);
(C) in an amount at which a molar equivalent ratio of the functional groups in the epoxy resin curing agent to 1 molar equivalent of the epoxy groups in the component (B) is 0.2 to 2.0, particularly preferably 0.4 to 1.0; and
(D) in an amount of preferably 0.5 to 10 parts by mass, per 100 parts by mass of the component (A); and

optionally, one or more of said optional components.

15. The heat-curable resin composition according to claim 11 , which consists of
one or more of each of
(A);
(B) in an amount of 3 to 200 parts by mass, per 100 parts by mass of the component (A);
(C) in an amount at which a molar equivalent ratio of the functional groups in the epoxy resin curing agent to 1 molar equivalent of the epoxy groups in the component (B) is 0.2 to 2.0, particularly preferably 0.4 to 1.0; and
(D) in an amount of preferably 0.5 to 10 parts by mass, per 100 parts by mass of the component (A).

Assignees

• Shinetsu Chemical Co

Inventors

• Kushihara Naoyuki
• Sasahara Rina

Classifications

• C09J151/08

  grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C09D151/08

  grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C08F283/10 Primary

  on to polymers containing more than one epoxy radical per molecule {(C08F283/004 takes precedence)} · CPC title