Polyamic acid and method for producing same, polyamic acid solution, polyimide, polyimide film, laminate and method for producing same, and flexible device and method for producing same

Patent metadata

Field	Value
Publication number	US-12104017-B2
Application number	US-202017037012-A
Country	US
Kind code	B2
Filing date	Sep 29, 2020
Priority date	Mar 30, 2018
Publication date	Oct 1, 2024
Grant date	Oct 1, 2024

Abstract

A polyamic acid according to one or more embodiments of the present invention contains a structural unit represented by general formula (1) and a structural unit represented by general formula (2). In general formula (1), the plurality of R1s are each independently a hydrogen atom, a monovalent aliphatic group or an aromatic group. In general formula (2), the plurality of R2s are each independently an alkyl group having 1-3 carbon atoms or an aryl group having 6-10 carbon atoms. In general formulas (1) and (2), X is a tetravalent organic group. In general formula (2), the plurality of Ys are each independently an alkylene group having 1-3 carbon atoms or an arylene group having 6-10 carbon atoms, and m is an integer of 51-199.

First claim

What is claimed is:

1. A polyamic acid, comprising:
a structural unit represented by general formula (1);
and a structural unit represented by general formula (2),

wherein:
a plurality of R 1 s are each independently a hydrogen atom, an alkyl group, or an aryl group,
a plurality of R 2 s are each independently an alkyl group having 1 to 3 carbon,
X is a tetravalent organic group,
a plurality of Ys are each independently an alkylene group having 1 to 3 carbon atoms, or an arylene group,
m is an integer of 51 to 199,
in the general formulas (1) and (2), X comprises:
at least one selected from the group consisting of a tetravalent organic group represented by formula (A) and a tetravalent organic group resented by formula (B); and
a tetravalent organic group represented by formula (C), and

the tetravalent organic group represented by formula (C) is comprised in an amount of 30 mol % or more with respect to a total amount of X

2. The polyamic acid according to claim 1 ,
wherein in the general formula (2), each of the plurality of R 2 s is a methyl group and each of the plurality of Ys is a propylene group.

3. The polyamic acid according to claim 1 ,
wherein the polyamic acid is a block copolymer comprising a first segment and a second segment, wherein the first segment contains the structural unit represented by the general formula (1) and does not contain the structural unit represented by the general formula (2), and
wherein the second segment contains the structural unit represented by the general formula (2).

4. The polyamic acid according to claim 3 ,
wherein the polyamic acid is an ABA type triblock copolymer in which the second segment is bonded to both ends of the first segment.

5. A method for producing the polyamic acid according to claim 1 , comprising:
reacting a tetracarboxylic dianhydride and a diamine in an organic solvent.

6. The method for producing the polyamic acid according to claim 5 , comprising:
reacting the tetracarboxylic dianhydride and a first diamine in the organic solvent to form a polyamic acid segment; and
adding a second diamine,
wherein, the first diamine includes 2,2′-bis(trifluoromethyl)benzidine, and the second diamine is a silicone diamine represented by a general formula (3):

wherein R 2 , Y and m in the general formula (3) are identical, respectively, to R 2 , Y and m in the general formula (2).

7. The method for producing the polyamic acid according to claim 6 ,
wherein a total number of moles of the tetracarboxylic dianhydride is equal to or more than 1.01 times and less than 1.10 times a total number of moles of the first diamine.

8. A polyamic acid solution, comprising:
the polyamic acid according to claim 1 ; and
an organic solvent.

9. A polyimide, comprising:
a cyclodehydration product of the polyamic acid according to claim 1 .

Assignees

• Kaneka Corp

Inventors

• Nakayama Hirofumi
• Uno Mari

Classifications

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• C08G77/455

  containing polyamide, polyesteramide or polyimide sequences · CPC title

• C08G73/1082

  wholly aromatic in the tetracarboxylic moiety · CPC title

• C08G73/1067

  Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound · CPC title

• C08G73/106

  containing silicon · CPC title