Acrylic fiber for artificial hair, method for producing same, and head decoration article containing same
US-10869514-B2 · Dec 22, 2020 · US
US12102151B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12102151-B2 |
| Application number | US-201816050584-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 31, 2018 |
| Priority date | Jun 6, 2013 |
| Publication date | Oct 1, 2024 |
| Grant date | Oct 1, 2024 |
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The present invention relates to a fiber for artificial hair having a hollow in a center of a fiber cross section. A ratio of an area of the hollow to an entire area of the fiber cross section is 5% to 50%. The fiber cross section has a flat multilobed shape, and the hollow has a first side and a second side that are inclined 70 to 110 degrees relative to a major axis of the fiber cross section. The present invention also relates to hair ornament products including the above fiber for artificial hair. Thus, the present invention provides a fiber for artificial hair having a favorable curl setting property when curling with a hair iron and a favorable combing property after curling with a hair iron, and hair ornament products including the same.
Opening claim text (preview).
The invention claimed is: 1. An artificial hair comprising a thermoplastic fiber having a cross section comprising an outer circumference and a hollow center, wherein the outer circumference has a shape comprising two overlapping circles or two overlapping ellipses directly connected by recessed portions, wherein the recessed portions have a form of arcs, or each recessed portion has a bottom point formed by the two overlapping circles or ellipses forming acute angles in the recessed portions, the hollow center is non-circular or non-elliptical and has a shape of a quadrangle, a hexagon, a combination of a quadrangle and an arc or a combination of a hexagon and an arc, the hollow center is located in the center of the cross section and a ratio of an area of the hollow center to an area of the cross section is from 10% to 40%, an average value of a maximum straight line distance and a minimum straight line distance between a first side and a second side of the hollow center is from 50% to 150% relative to an average value of a maximum straight line distance and a minimum straight line distance between a first minor axis and a second minor axis in the cross section, the thermoplastic fiber comprises a polyester-based resin composition comprising 100 parts by weight of a polyester resin and from 5 to 40 parts by weight of a brominated epoxy-based flame retardant, and the polyester resin is at least one selected from the group consisting of polyalkylene terephthalate and a copolymerized polyester comprising polyalkylene terephthalate. 2. The artificial hair of claim 1 , wherein the first side and the second side of the hollow center are inclined 70 to 110 degrees relative to a major axis of the cross section, and the first side and the second side of the hollow center have a length of from 5 μm to 50 μm. 3. The artificial hair of claim 1 , wherein a ratio of a length of a major axis to a length of the first minor axis in the cross section is from 1.2 to 3.0. 4. The artificial hair of claim 1 , wherein the thermoplastic fiber further comprises at least one resin composition selected from the group consisting of a polyamide-based resin composition, a vinyl chloride-based resin composition, a modacrylic-based resin composition, a polycarbonate-based resin composition, and a polyphenylene sulfide-based resin composition. 5. The artificial hair of claim 1 , wherein the thermoplastic fiber is curved by gear crimping. 6. A hair ornament product, comprising: a thermoplastic fiber having a cross section comprising an outer circumference and a hollow center, wherein the outer circumference has a shape comprising two overlapping circles or two overlapping ellipses directly connected by recessed portions, wherein the recessed portions have a form of arcs, or each recessed portion has a bottom point formed by the two overlapping circles or ellipses forming acute angles in the recessed portions, the hollow center is non-circular or non-elliptical and has a shape of a quadrangle, a hexagon, a combination of a quadrangle and an arc, or a combination of a hexagon and an arc, the hollow center is located in the center of the cross section and a ratio of an area of the hollow center to an area of the cross section is from 10% to 40%, an average value of a maximum straight line distance and a minimum straight line distance between a first side and a second side of the hollow center is from 50% to 150% relative to an average value of a maximum straight line distance and a minimum straight line distance between a first minor axis and a second minor axis in the cross section, the thermoplastic fiber comprises a polyester-based resin composition comprising 100 parts by weight of a polyester resin and from 5 to 40 parts by weight of a brominated epoxy-based flame retardant, and the polyester resin is at least one selected from the group consisting of polyalkylene terephthalate and a copolymerized polyester comprising polyalkylene terephthalate. 7. The hair ornament product of claim 6 , wherein the hair ornament product is at least one selected from the group consisting of a hair wig, a hairpiece, weaving hair, a hair extension, braided hair, a hair accessory, and doll hair. 8. The hair ornament product of claim 6 , wherein the hair ornament product is heat-treated at a temperature of from 120° C. to 240° C. with a hair iron. 9. The hair ornament product of claim 6 , wherein a ratio of a length of a major axis to a length of the first minor axis in the cross section is from 1.2 to 3.0. 10. The hair ornament product of claim 6 , wherein the first side and the second side of the hollow center are inclined 70 to 110 degrees relative to a major axis of the cross section, and the first side and the second side of the hollow center have a length of from 5 μm to 50 μm. 11. The hair ornament product of claim 6 , wherein the thermoplastic fiber further comprises at least one resin composition selected from the group consisting of a polyamide-based resin composition, a vinyl chloride-based resin composition, a modacrylic-based resin composition, a polycarbonate-based resin composition, and a polyphenylene sulfide-based resin composition. 12. The hair ornament product of claim 6 , wherein the thermoplastic fiber is curved by gear crimping. 13. A method for forming a thermoplastic fiber for artificial hair, wherein the thermoplastic fiber has a cross section comprising an outer circumference and a hollow center, the outer circumference has a shape comprising two overlapping circles or two overlapping ellipses directly connected by recessed portions, wherein the recessed portions have a form of arcs, or each recessed portion has a bottom point formed by the two overlapping circles or ellipses forming acute angles in the recessed portions, the hollow center is non-circular or non-elliptical and has a shape of a quadrangle, a hexagon, a combination of a quadrangle and an arc, or a combination of a hexagon and an arc, the hollow center is located in the center of the cross section and a ratio of an area of the hollow center to an area of the cross section is from 10% to 40%, an average value of a maximum straight line distance and a minimum straight line distance between a first side and a second side of the hollow center is from 50% to 150% relative to an average value of a maximum straight line distance and a minimum straight line distance between a first minor axis and a second minor axis in the cross section, the thermoplastic fiber comprises a polyester-based resin composition comprising 100 parts by weight of a polyester resin and from 5 to 40 parts by weight of a brominated epoxy-based flame retardant, and the polyester resin is at least one selected from the group consisting of polyalkylene terephthalate and a copolymerized polyester comprising polyalkylene terephthalate; the method comprising: dry blending a resin composition to form a polymer mixture; extruding the mixture to form polymer pellets; drying the polymer pellets; melting the dried polymer pellets in a melt spinning machine; and extruding the melted polymer pellets through a spinneret to obtain the thermoplastic fibers, wherein the spinneret comprises a cocoon-shaped or spectacle-shaped nozzle and a quadrangle-shaped nozzle hole. 14. The artificial hair of claim 1 , wherein the recessed portions have a form of arcs. 15. The artificial hair of claim 1 , wherein each recessed portion has a bottom point formed by the two overlapping circles or ellipses forming acute angles in the recessed portions. 16. The artificial hair of claim 15 , wherein
Wearing apparel · CPC title
polyesters, e.g. polyethylene terephthalate [PET] · CPC title
from copolycondensation products · CPC title
with a non-circular cross section; Spinnerette packs therefor (D01D5/38 takes precedence) · CPC title
with a hollow structure; Spinnerette packs therefor (D01D5/38 takes precedence; producing tubes of plastic material B29D; addition of agents forming hollow filaments D01F1/08) · CPC title
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