Light-emitting device including light-emitting layer and electron-transport layer

Patent metadata

Field	Value
Publication number	US-12101997-B2
Application number	US-201917416754-A
Country	US
Kind code	B2
Filing date	Dec 17, 2019
Priority date	Dec 28, 2018
Publication date	Sep 24, 2024
Grant date	Sep 24, 2024

Abstract

A novel light-emitting device, a light-emitting device with high emission efficiency, a light-emitting device with a long lifetime, or a light-emitting device with low driving voltage is provided. An EL layer includes a first layer, a second layer, a third layer, a light-emitting layer, and a fourth layer in this order from the anode side. The first layer contains a first organic compound and a second organic compound. The fourth layer contains a seventh organic compound. The first organic compound exhibits an electron-accepting property with respect to the second organic compound. A HOMO level of the second organic compound is higher than or equal to −5.7 eV and lower than or equal to −5.4 eV. The fourth layer includes a region where the amount of seventh organic compound is large and a region where the amount of seventh organic compound is small in the thickness direction.

First claim

The invention claimed is:

1. A light-emitting device comprising:
an anode;
a cathode; and
an EL layer between the anode and the cathode,
wherein the EL layer comprises a light-emitting layer and an electron-transport layer,
wherein the electron-transport layer comprises a first substance and a second substance,
wherein the first substance is any of an alkali metal, an alkaline earth metal, an organic complex of an alkali metal or an alkaline earth metal, and a compound of an alkali metal or an alkaline earth metal,
wherein the second substance is an organic compound with an electron-transport property,
wherein the electron-transport layer comprises a first region and a second region in a thickness direction,
wherein an amount of the first substance in the first region is larger than an amount of the first substance in the second region,
wherein the first region is closer to the anode than the second region is in the electron-transport layer,
wherein a decay curve showing a change in luminance of light emission obtained when a constant current is supplied to the light-emitting device has a maximum value, and
wherein the decay curve comprises a portion where the change in luminance exceeds 100%.

2. An electronic device comprising:
the light-emitting device according to claim 1 ; and
at least one of a sensor, an operation button, a speaker, and a microphone.

3. A light-emitting device comprising:
an anode;
a cathode; and
an EL layer between the anode and the cathode,
wherein the EL layer comprises a light-emitting layer and an electron-transport layer,
wherein the electron-transport layer comprises a first substance and a second substance,
wherein the first substance is any of an alkali metal, an alkaline earth metal, an organic complex of an alkali metal or an alkaline earth metal, and a compound of an alkali metal or an alkaline earth metal,
wherein the second substance is an organic compound with an electron-transport property,
wherein the electron-transport layer comprises a first region and a second region in a thickness direction,
wherein an amount of the second substance in the first region is smaller than an amount of the second substance in the second region,
wherein the first region is closer to the anode than the second region is in the electron-transport layer,
wherein a decay curve showing a change in luminance of light emission obtained when a constant current is supplied to the light-emitting device has a maximum value, and
wherein the decay curve comprises a portion where the change in luminance exceeds 100.

4. An electronic device comprising:
the light-emitting device according to claim 3 , and
at least one of a sensor, an operation button, a speaker, and a mic.

5. A light-emitting device comprising:
an anode;
a cathode; and
an EL layer between the anode and the cathode,
wherein the EL layer comprises a first layer, a second layer, a third layer, a light-emitting layer, and a fourth layer in this order from the anode side,
wherein the first layer is in contact with the anode,
wherein the first layer comprises a first organic compound and a second organic compound,
wherein the second layer comprises a third organic compound,
wherein the third layer comprises a fourth organic compound,
wherein the light-emitting layer comprises a fifth organic compound and a sixth organic compound,
wherein the fourth layer comprises a seventh organic compound and a first substance, wherein the first organic compound exhibits an electron-accepting property with respect to the second organic compound,
wherein the fifth organic compound is an emission center substance,
wherein the first substance is any of an alkali metal, an alkaline earth metal, an organic complex of an alkali metal or an alkaline earth metal, and a compound of an alkali metal or an alkaline earth metal,
wherein a HOMO level of the second organic compound is higher than or equal to −5.7 eV and lower than or equal to −5.4 eV,
wherein electron mobility of the seventh organic compound is higher than or equal to 1×10 −7 cm 2 /Vs and lower than or equal to 5×10 −5 cm 2 /Vs when a square root of electric field strength [V/cm] is 600,
wherein the fourth layer comprises a first region and a second region in a thickness direction,
wherein an amount of the seventh organic compound in the first region is smaller than an amount of the seventh organic compound in the second region, and
wherein the first region is closer to the anode than the second region is in the fourth layer.

6. The light-emitting device according to claim 5 ,
wherein the fourth layer is in contact with the light-emitting layer, and
wherein a HOMO level of the seventh organic compound is higher than or equal to −6.0 eV.

7. The light-emitting device according to claim 5 ,
wherein a difference between a HOMO level of the third organic compound and the HOMO level of the second organic compound is less than or equal to 0.2 eV, and
wherein the HOMO level of the third organic compound is deeper than or equal to the HOMO level of the second organic compound.

8. The light-emitting device according to claim 5 ,
wherein the second organic compound comprises a first hole-transport skeleton,
wherein the third organic compound comprises a second hole-transport skeleton,
wherein the fourth organic compound comprises a third hole-transport skeleton, and
wherein the first hole-transport skeleton, the second hole-transport skeleton, and the third hole-transport skeleton are independently any one of a carbazole skeleton, a dibenzofuran skeleton, a dibenzothiophene skeleton, and an anthracene skeleton.

9. The light-emitting device according to claim 5 ,
wherein the seventh organic compound comprises an anthracene skeleton.

10. The light-emitting device according to claim 5 ,
wherein the seventh organic compound comprises an anthracene skeleton and a heterocyclic skeleton.

11. The light-emitting device according to claim 5 ,
wherein the electron mobility of the seventh organic compound is lower than electron mobility of the sixth organic compound.

12. The light-emitting device according to claim 5 ,
wherein a difference between a HOMO level of the fourth organic compound and a HOMO level of the third organic compound is less than or equal to 0.2 eV.

13. The light-emitting device according to claim 12 ,
wherein the HOMO level of the fourth organic compound is deeper than the HOMO level of the third organic compound.

14. The light-emitting device according to claim 5 ,
wherein the second organic compound comprises a dibenzofuran skeleton.

15. The light-emitting device according to claim 5 ,
wherein the second organic compound and the third organic compound are the same substance.

16. The light-emitting device according to claim 5 ,
wherein the fifth organic compound is a blue fluorescent material.

17. The light-emitting device according to claim 5 ,
wherein a decay curve showing a change in luminance of light emission obtained when a constant current is supplied to the light-emitting device has a maximum value, and
wherein the decay curve comprises a portion where the change in luminance exceeds 100.

18. An electronic device comprising:
the light-emitting device according to claim 5 ; and
at least one of a sensor, an operation button, a speaker, and a microphone.

Assignees

• Semiconductor Energy Lab

Inventors

• Hashimoto Naoaki
• Seo Satoshi
• Suzuki Tsunenori
• Takita Yusuke
• Okuyama Takumu
• Ohsawa Nobuharu
• Yamazaki Shunpei
• Sasaki Toshiki

Classifications

• H10K85/636 Primary

  comprising heteroaromatic hydrocarbons as substituents on the nitrogen atom · CPC title

• H10K85/6576 Primary

  comprising only sulfur in the heteroaromatic polycondensed ring system, e.g. benzothiophene · CPC title

• H10K2101/30

  Highest occupied molecular orbital [HOMO], lowest unoccupied molecular orbital [LUMO] or Fermi energy values · CPC title

• H10K85/6574

  comprising only oxygen in the heteroaromatic polycondensed ring system, e.g. cumarine dyes · CPC title

• H10K50/16

  Electron transporting layers · CPC title