Polymer electrolyte membrane (PEM) fuel cells using zeolite-templated carbon (ZTC) as electrocatalyst

Patent metadata

Field	Value
Publication number	US-12100845-B2
Application number	US-202117497556-A
Country	US
Kind code	B2
Filing date	Oct 8, 2021
Priority date	Jul 14, 2021
Publication date	Sep 24, 2024
Grant date	Sep 24, 2024

Abstract

A polymer electrolyte membrane (PEM) fuel cell assembly, and a method for making the assembly, are provided. An exemplary method includes forming a functionalized zeolite templated carbon (ZTC), including forming a CaX zeolite, depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, treating the carbon/zeolite composite with a solution including hydrofluoric acid to form a ZTC, and treating the ZTC to add catalyst sites, forming the functionalized ZTC. The method further includes incorporating the functionalized ZTC into electrodes, forming a membrane electrode assembly (MEA), and forming the PEM fuel cell assembly.

First claim

What is claimed is:

1. A method for making a polymer electrolyte membrane (PEM) fuel cell assembly, comprising:
forming a functionalized zeolite templated carbon (ZTC), comprising:
forming a CaX zeolite, wherein the CaX zeolite is formed by ion exchanging a NaX zeolite with calcium ions;
depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, wherein the CVD wherein the CVD process comprises:
depositing carbon in a matrix of the CaX zeolite at a first temperature using a gas stream comprising acetylene,
switching the gas stream to a helium stream, and
increasing the first temperature to a second temperature, and repeating the CVD process by
cooling back to the first temperature,
switching the gas stream back to the gas stream comprising acetylene,
depositing carbon in the matrix of the CaX zeolite at the first temperature,
switching the gas stream to the helium stream, and
increasing the first temperature to the second temperature;

treating the carbon/zeolite composite with a solution comprising hydrofluoric acid to form a ZTC; and
treating the ZTC to add catalyst sites, forming the functionalized ZTC; and

incorporating the functionalized ZTC into electrodes;
forming a membrane electrode assembly (MEA); and
forming the PEM fuel cell assembly.

2. The method of claim 1 , wherein the acetylen is added as a 2 vol. % solution in helium.

3. The method of claim 1 , wherein the CVD process is performed at a temperature of between 823 K and 1123 K.

4. The method of claim 1 , wherein the first temperature is less than 875 K.

5. The method of claim 1 , wherein the first temperature is about 823 K.

6. The method of claim 1 , wherein the second temperature is greater than 1120 K.

7. The method of claim 1 , wherein the second temperature is about 1123 K.

8. The method of claim 1 , comprising forming the functionalized ZTC using an incipient wetness technique.

9. The method of claim 1 , comprising:
dissolving an active metal precursor to form an aqueous solution;
adding an amount of the aqueous solution to the ZTC corresponding to a pore volume of the ZTC forming a metal/ZTC composite;
drying the metal/ZTC composite; and
sintering the metal/ZTC composite to form the functionalized ZTC.

10. The method of claim 1 , comprising adhering the functionalized ZTC to a surface of an anode, a cathode, or both, using an ion conductive adhesive.

11. The method of claim 1 , comprising incorporating the functionalized ZTC into an anode, a cathode, or both by sputtering.

12. The method of claim 1 , comprising forming the MEA by pressing an anode, a PEM, and a cathode together in a hot press, wherein a surface of the anode facing the PEM, a surface of the cathode facing the PEM, or both, is coated with the functionalized ZTC.

13. The method of claim 1 , comprising forming the PEM fuel cell assembly by mounting the MEA in a housing with gas inlets for fuel and oxidizer.

14. A method for making a membrane electrode assembly (MEA), comprising:
forming a functionalized zeolite templated carbon (ZTC), comprising:
forming a CaX zeolite, wherein the CaX zeolite is formed by ion exchanging a NaX zeolite with calcium ions;
depositing carbon in the CaX zeolite using a chemical vapor deposition (CVD) process to form a carbon/zeolite composite, wherein the CVD wherein the CVD process comprises:
depositing carbon in a matrix of the CaX zeolite at a first temperature using a gas stream comprising acetylene,
switching the gas stream to a helium stream, and
increasing the first temperature to a second temperature, and repeating the CVD process by
cooling back to the first temperature,
switching the gas stream back to the gas stream comprising acetylene,
depositing carbon in the matrix of the CaX zeolite at the first temperature,
switching the gas stream to the helium stream, and
increasing the first temperature to the second temperature;

treating the carbon/zeolite composite with a solution comprising hydrofluoric acid to form a ZTC; and
treating the ZTC to add catalyst sites, forming the functionalized ZTC; and

incorporating the functionalized ZTC into electrodes; and
forming a membrane electrode assembly.

15. The method of claim 14 , wherein the first temperature is less than 875 K.

16. The method of claim 14 , wherein the first temperature is about 823 K.

17. The method of claim 14 , wherein the second temperature is greater than 1120 K.

18. The method of claim 14 , wherein the second temperature is about 1123 K.

19. The method of claim 14 , comprising:
dissolving an active metal precursor to form an aqueous solution;
adding an amount of the aqueous solution to the ZTC corresponding to a pore volume of the ZTC forming a metal/ZTC composite;
drying the metal/ZTC composite; and
sintering the metal/ZTC composite to form the functionalized ZTC.

20. The method of claim 14 , comprising adhering the functionalized ZTC to a surface of an anode, a cathode, or both, using an ion conductive adhesive.

21. The method of claim 14 , comprising incorporating the functionalized ZTC into an anode, a cathode, or both by sputtering.

22. The method of claim 14 , comprising forming the MEA by pressing an anode, a PEM, and a cathode together in a hot press, wherein a surface of the anode facing the PEM, a surface of the cathode facing the PEM, or both, is coated with the functionalized ZTC.

Assignees

• Saudi Arabian Oil Co

Inventors

• Hammad Ahmad D
• Amr Issam T
• Wang Yuguo
• Lithoxoos Georgios
• Othman Rashid M

Classifications

• H01M8/1004 Primary

  characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title

• H01M4/8882

  Heat treatment, e.g. drying, baking · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M4/96

  Carbon-based electrodes · CPC title

• H01M4/8605

  Porous electrodes · CPC title