Method for decomposing phenol-based by-product

Patent metadata

Field	Value
Publication number	US-12084408-B2
Application number	US-202117619211-A
Country	US
Kind code	B2
Filing date	May 31, 2021
Priority date	Jul 10, 2020
Publication date	Sep 10, 2024
Grant date	Sep 10, 2024

Abstract

Provided is a method of decomposing phenol-based by-product, and more particularly, a method of decomposing phenol-based by-product including: introducing a phenol-based by-product stream, a first stream of a side discharge stream from a decomposition device, and a process water stream to a mixing device and mixing the streams; introducing a discharge stream from the mixing device to a layer separation device to phase-separate the discharge stream into an oil phase and an aqueous phase; passing an oil stream discharged from the layer separation device through any one or more of a first heat exchanger and a second heat exchanger and introducing the oil stream to the decomposition device to carry out decomposition; and supplying the first stream of the side discharge stream from the decomposition device to the mixing device, forming a mixed stream of a second stream of the side discharge stream with a lower discharge stream and discharging the mixed stream, and recovering effective components from an upper discharge stream.

First claim

The invention claimed is:

1. A method of decomposing phenol-based by-product, the method comprising:
introducing a phenol-based by-product stream, a first stream of a side discharge stream from a decomposition device, and a process water stream to a mixing device and mixing the streams;
introducing a discharge stream from the mixing device to a layer separation device to phase-separate the discharge stream into an oil phase and an aqueous phase;
passing an oil stream discharged from the layer separation device through any one or more of a first heat exchanger and a second heat exchanger and introducing the oil stream to the decomposition device to carry out decomposition; and
supplying the first stream of the side discharge stream from the decomposition device to the mixing device, forming a mixed stream of a second stream of the side discharge stream from the decomposition device with a lower discharge stream from the decomposition device and discharging the mixed stream, and recovering effective components from an upper discharge stream from the decomposition device.

2. The method of decomposing phenol-based by-product of claim 1 , wherein the phenol-based by-product includes any one or more of phenol-based by-product produced in a phenol preparation process and phenol-based by-product produced in a bisphenol A preparation process.

3. The method of decomposing phenol-based by-product of claim 1 , wherein the phenol-based by-product includes one or more selected from the group consisting of bisphenol A, phenol, α-methylstyrene, acetophenone, cumylphenol, and an α-methylstyrene dimer.

4. The method of decomposing phenol-based by-product of claim 1 , wherein the side discharge stream from the decomposition device includes one or more selected from the group consisting of phenol, acetophenone, α-methylstyrene, and cumene.

5. The method of decomposing phenol-based by-product of claim 1 , wherein the side discharge stream from the decomposition device includes 40 wt % or more of acetophenone.

6. The method of decomposing phenol-based by-product of claim 1 , wherein an operation pressure of the decomposition device is 0.1 KG to 3 KG.

7. The method of decomposing phenol-based by-product of claim 1 , wherein a temperature of the side discharge stream from the decomposition device is 150° C. to 400° C.

8. The method of decomposing phenol-based by-product of claim 1 , wherein the phenol-based by-product stream is supplied to the mixing device after heat exchange with the oil stream discharged from the layer separation device in the first heat exchanger.

9. The method of decomposing phenol-based by-product of claim 8 , wherein the mixed stream is heat-exchanged with the oil stream, which has been passed through the first heat exchanger, in the second heat exchanger and then is discharged.

10. The method of decomposing phenol-based by-product of claim 1 , wherein the effective components include one or more selected from the group consisting of phenol, α-methylstyrene, and cumene.

11. The method of decomposing phenol-based by-product of claim 1 , wherein the phenol-based by-product stream is passed through a cooler before being introduced to the layer separation device.

Assignees

• Lg Chemical Ltd

Inventors

• Kang Min Suk
• Lee Sang Beom
• Jang Chi Hyun

Classifications

• C07C45/82

  by distillation · CPC title

• C07C37/72

  by liquid-liquid treatment · CPC title

• C07C37/56

  by replacing a carboxyl or aldehyde group by a hydroxy group · CPC title

• C07C37/52

  by splitting polyaromatic compounds, e.g. polyphenolalkanes · CPC title

• C07C7/04

  by distillation · CPC title