Method and apparatus for decomposing phenolic by-product

Patent metadata

Field	Value
Publication number	US-11247958-B2
Application number	US-201916975331-A
Country	US
Kind code	B2
Filing date	Oct 15, 2019
Priority date	Dec 20, 2018
Publication date	Feb 15, 2022
Grant date	Feb 15, 2022

Abstract

The present disclosure relates to a method and an apparatus for decomposing a phenolic by-product generated in a bisphenol A preparation process, the method including: a step (S10) of feeding the phenolic by-product to a multistage reactive distillation column; a step (S20) of separating the phenolic by-product into an upper discharge stream containing an active component, a side discharge stream containing acetophenone, and a bottom discharge stream containing tar by the multistage reactive distillation column; and a step (S30) of mixing the side discharge stream discharged from the multistage reactive distillation column and the bottom discharge stream discharged from the multistage reactive distillation column to form a mixed discharge stream.

First claim

The invention claimed is:

1. A method for decomposing a phenolic by-product generated in a bisphenol A preparation process, the method comprising:
a step of feeding the phenolic by-product to a multistage reactive distillation column;
a step of separating the phenolic by-product into an upper discharge stream containing an active component, a side discharge stream containing acetophenone, and a bottom discharge stream containing tar by the multistage reactive distillation column; and
a step of mixing the side discharge stream discharged from the multistage reactive distillation column and the bottom discharge stream discharged from the multistage reactive distillation column to form a mixed discharge stream.

2. The method of claim 1 , wherein the phenolic by-product is subjected to a heat exchange with the mixed discharge stream by a heat exchanger and fed to the multistage reactive distillation column.

3. The method of claim 1 , wherein the side discharge stream contains 99 wt % or more of acetophenone contained in the phenolic by-product.

4. The method of claim 1 , wherein the side discharge stream is discharged through a side outlet provided at a stage within the top 50% to 90% of a total number of stages of the multistage reactive distillation column.

5. The method of claim 1 , wherein a viscosity of the mixed discharge stream is lower than that of the bottom discharge stream.

6. The method of claim 1 , wherein an operation pressure of the multistage reactive distillation column is 0.1 bar (10 kPa) to 3.0 bar (300 kPa).

7. An apparatus for decomposing a phenolic by-product generated in a bisphenol A preparation process, the apparatus comprising:
a multistage reactive distillation column separating the phenolic by-product into an upper discharge stream containing an active component, a side discharge stream containing acetophenone, and a bottom discharge stream containing tar; and
a moving line system including a side discharge stream moving line through which the side discharge stream is discharged and moved, and a bottom discharge stream moving line through which the bottom discharge stream is discharged and moved,
wherein the side discharge stream moving line and the bottom discharge stream moving line are connected to each other so that the side discharge stream and the bottom discharge stream are joined with each other to form a mixed discharge stream.

8. The apparatus of claim 7 , wherein a side outlet through which the side discharge stream is discharged is provided at a stage within the top 50% to 90% of a total number of stages of the multistage reactive distillation column.

9. The apparatus of claim 7 , wherein an upper outlet through which the upper discharge stream is discharged is provided at an upper portion of the multistage reactive distillation column.

10. The apparatus of claim 7 , further comprising a heat exchanger performing a heat exchange between the phenolic by-product and the mixed discharge stream.

11. The apparatus of claim 7 , wherein an operation pressure of the multistage reactive distillation column is 0.1 bar (10 kPa) to 3.0 bar (300 kPa).

12. The method of claim 1 , wherein the upper discharge stream comprises a light component.

13. The apparatus of claim 7 , wherein the upper discharge stream comprises a light component.

Assignees

• Lg Chemical Ltd

Inventors

• Kang Min Suk
• Lee Sang Beom
• Shin Joon Ho

Classifications

• C07C37/52

  by splitting polyaromatic compounds, e.g. polyphenolalkanes · CPC title

• C07C7/04

  by distillation · CPC title

• C07C37/74 Primary

  by distillation · CPC title

• C07C45/82

  by distillation · CPC title

• C07C15/085

  Isopropylbenzene · CPC title