Cement slurry compositions comprising pozzolanic cement additives and methods for improving development of compressive strengths in the cement slurry compositions

Patent metadata

Field	Value
Publication number	US-12077709-B2
Application number	US-202218073650-A
Country	US
Kind code	B2
Filing date	Dec 2, 2022
Priority date	Dec 2, 2022
Publication date	Sep 3, 2024
Grant date	Sep 3, 2024

Abstract

Pumpable slurry compositions comprising at least one aluminosilicate additive and optional pozzolanic cement additives and methods for improving development of compressive strengths in the pumpable cement slurry compositions are disclosed herein. The methods utilize one or more pumpable cement slurry compositions comprising at least one cement component, water, at least one first aluminosilicate additive, at least one optional second aluminosilicate additive, and one or more optional pozzolanic additives, wherein the at least one first aluminosilicate additive has an amorphous phase of greater than about 50% and a weight ratio of silica oxide to aluminum oxide of about 1.0 to about 2.5, and the at least one optional second aluminosilicate additive has a weight ratio of silica oxide to aluminum oxide of about 1.7 to about 3.3.

First claim

What is claimed is:

1. A pumpable cement slurry composition comprising:
at least one cement component comprising cement particles;
water;
an aluminosilicate additive component consisting of:
a first aluminosilicate additive comprising metakaolin and having an amorphous phase of greater than 50%; and
a second aluminosilicate additive comprising rice husk ash,

wherein the first and second aluminosilicate additives are each present at a concentration of about 10% to about 15% by weight of the at least one cement component and comprise a weight ratio of silica to aluminum oxide (Si/Al weight ratio) of about 1.0 to about 2.5, and
wherein the pumpable cement slurry composition comprises a density of about 10 ppg to about 11.5 ppg and a solid volume fraction of less than about 40%.

2. The pumpable cement slurry composition of claim 1 , wherein the amorphous phase of the first aluminosilicate additive is greater than or equal to about 90% and the weight ratio of silica to aluminum oxide of the first aluminosilicate additive is about 1.1 to about 2.3.

3. The pumpable cement slurry composition of claim 1 , wherein the at least one cement component is Portland cement or ordinary Portland cement, construction cement, or a combination thereof.

4. The pumpable cement slurry composition of claim 1 , wherein particle sizes of the first aluminosilicate additive and the second aluminosilicate additive are each less than particle sizes of the cement particles.

5. The pumpable cement slurry composition of claim 1 , wherein a viscosity of the pumpable cement slurry composition is less than about 400 cP.

6. The pumpable cement slurry composition of claim 1 , wherein the density of the pumpable cement slurry composition is about 10 ppg to about 11 ppg.

7. The pumpable cement slurry composition of claim 5 , wherein the viscosity of the pumpable cement slurry composition is less than about 350 cP.

8. The pumpable cement slurry composition of claim 5 , wherein the viscosity of the pumpable cement slurry composition is less than about 300 cP.

9. The pumpable cement slurry composition of claim 1 , wherein the solid volume fraction of the pumpable cement slurry composition is less than about 35%.

10. The pumpable cement slurry composition of claim 9 , wherein the solid volume fraction of the pumpable cement slurry composition is less than about 25%.

11. The pumpable cement slurry composition of claim 9 , wherein the at least one cement component is Portland cement.

12. The pumpable cement slurry composition of claim 9 , wherein the at least one cement component is ordinary Portland cement.

13. A method for cementing a subterranean well comprising of a borehole, the method comprising:
preparing a pumpable cement slurry composition comprising:
at least one cement component comprising cement particles;
water present at a concentration of at least about 200% by weight of the cement component;
an aluminosilicate additive component consisting of:
a first aluminosilicate additive comprising metakaolin and having an amorphous phase of greater than about 50% and a silica to aluminum ratio (Si/Al ratio) of about 1.0 to about 2.5;
a second aluminosilicate additive comprising rice husk ash; and

at least one cement additive selected from one or more dispersants, at least one antifoam, one or more retarders, one or more accelerators, silica, or at least one combination thereof;
wherein the first and second aluminosilicate additives are each present at a concentration of about 10% to about 15% by weight of the at least one cement component and comprise a weight ratio of silica to aluminum oxide (Si/Al weight ratio) of about 1.0 to about 2.5, and
wherein the pumpable cement slurry composition comprises a density of about 10 ppg to about 11.5 ppg and a solid volume fraction of less than about 40%;

pumping the pumpable cement slurry composition into the subterranean well such that the pumpable cement slurry composition is disposed at or in a zone of the subterranean well; and
allowing the pumpable cement slurry composition to set and form a solid mass in the zone.

14. The method of claim 13 , wherein the second aluminosilicate additive has a weight ratio of silica to aluminum oxide of about 1.7 to about 2.5.

15. The method of claim 14 , wherein a viscosity of the pumpable cement slurry composition is less than about 400 cP.

Assignees

• Schlumberger Technology Corp

Inventors

• Engelke Bernardo
• Foster Lynn
• Lafitte Valerie

Classifications

• C09K8/473

  Density reducing additives, e.g. for obtaining foamed cement compositions · CPC title

• C04B2111/00146

  Sprayable or pumpable mixtures · CPC title

• C04B28/04

  Portland cements · CPC title

• C04B14/047

  Zeolites · CPC title

• C04B2201/20

  for the density · CPC title