Preparation method of fly ash-based ceramic membrane support

Patent metadata

Field	Value
Publication number	US-12071377-B2
Application number	US-202318398792-A
Country	US
Kind code	B2
Filing date	Dec 28, 2023
Priority date	Dec 30, 2022
Publication date	Aug 27, 2024
Grant date	Aug 27, 2024

Abstract

The present disclosure provides a preparation method of a fly ash-based ceramic membrane support, including the following steps: 1) subjecting fly ash to alkali washing and acid washing to obtain pretreated fly ash; 2) blending a raw material including the pretreated fly ash, and then conducting aging and extrusion molding to obtain a green body; and 3) spraying a surface water-retaining agent (including glycerol, tung oil, a diol, and polyethylene glycol) on a surface of the green body to allow static curing in a constant-temperature and constant-humidity environment, and then conducting drying and sintering after the curing is completed. The preparation method can effectively improve molding and sintering performances of the fly ash to obtain a fly ash-based ceramic membrane support with a qualified performance.

First claim

What is claimed is:

1. A preparation method of a fly ash-based ceramic membrane support, comprising the following steps:
1) subjecting fly ash to alkali washing and acid washing to obtain pretreated fly ash; wherein the alkali washing is conducted using an alkali washing solution selected from the group consisting of 2 wt % to 4 wt % of a sodium hydroxide solution and 15 wt % to 25 wt % of a sodium carbonate solution, and a solid-to-liquid ratio of the alkali washing solution is in a range of 1 kg: 1.5 L to 1 kg: 3 L; and the acid washing is conducted using an acid washing solution selected from the group consisting of 1 wt % to 3 wt % of a citric acid solution, 3 wt % to 7 wt % of a hydrochloric acid solution, 1 wt % to 5 wt % of a sulfuric acid solution, and 0.5 wt % to 3 wt % of a nitric acid solution, and a solid-to-liquid ratio of the acid washing solution is in a range of 1 kg: 0.5 L to 1 kg: 2.5 L;
2) blending a raw material, and then conducting aging and extrusion molding to obtain a green body; the raw material comprises the following components in parts by mass: 80 parts to 95 parts of the pretreated fly ash, 6 parts to 9 parts of a plastic clay, 5 parts to 8 parts of a pore-forming agent, 2 parts to 4 parts of a binder, 20 parts to 28 parts of water, 1 part to 2 parts of a lubricant, 2 parts to 4 parts of a water-retaining agent, 0.5 parts to 1 part of a water-reducing agent, and 0.1 parts to 0.3 parts of a release agent; and
3) spraying a surface water-retaining agent on a surface of the green body to allow static curing in a constant-temperature and constant-humidity environment, and then conducting drying and sintering after the curing is completed; wherein the surface water-retaining agent is prepared from glycerol, tung oil, a diol, and polyethylene glycol at a mass ratio of (1-2.5):(2-4):(0.3-0.7):(0.5-1).

2. The preparation method of a fly ash-based ceramic membrane support according to claim 1 , wherein the blending is performed in the following order: mixing the pretreated fly ash with the plastic clay, mixing with the water-reducing agent, mixing with the water-retaining agent and the lubricant, mixing with the pore-forming agent and the binder, and mixing with the release agent.

3. The preparation method of a fly ash-based ceramic membrane support according to claim 2 , wherein
the plastic clay is at least one selected from the group consisting of a Suzhou clay and a granite powder;
the pore-forming agent is at least one selected from the group consisting of corn starch and saw dust;
the binder comprises a cellulose;
the lubricant comprises a long-chain fatty acid methyl ester (FAME);
the water-reducing agent comprises a lignosulfonate; and
the release agent comprises an emulsified silicone oil.

4. The preparation method of a fly ash-based ceramic membrane support according to claim 1 , wherein the surface water-retaining agent is sprayed on the surface of the green body at (5-10) g/0.1 m 2 .

5. The preparation method of a fly ash-based ceramic membrane support according to claim 1 , wherein the static curing is conducted at 20° C. to 25° C. with a relative humidity of 25%±5% for 8 h to 12 h; and
the drying is microwave drying at 160° C. to 180° C. for 1 h to 3 h.

6. The preparation method of a fly ash-based ceramic membrane support according to claim 1 , wherein the sintering is conducted by burying sintering combined with low-temperature slow sintering; the burying sintering is conducted with a burying sintering sand comprising an alumina sand and/or a zirconia sand; and the low-temperature slow sintering comprises: heating from 25° C. to 180° C. at 0.5° C./min to 1.5° C./min, heating from 180° C. to 550° C. at 0.2° C./min to 0.8° C./min and holding the temperature of 550° C. for 30 min to 90 min, heating from 550° C. to 900° C. at 3° C./min to 4° C./min, and heating from 900° C. to 1,350° C. at 3° C./min to 5° C./min and holding the temperature of 1,350° C. for 1.5 h to 2.5 h.

Assignees

• Univ Central South

Inventors

• He Zhiguo
• Zhong Hui
• Xie Weiqi

Classifications

• C04B2235/5436

  micrometer sized, i.e. from 1 to 100 micron · CPC title

• C04B2235/661

  Multi-step sintering · CPC title

• C04B2235/6587

  Influencing the atmosphere by vaporising a solid material, e.g. by using a burying of sacrificial powder · CPC title

• C04B35/62685

  characterised by the order of addition of constituents or additives · CPC title

• C04B33/1305

  Organic additives · CPC title