Continuous and modular process for producing water-redispersible polymer powder compositions

Patent metadata

Field	Value
Publication number	US-12060444-B2
Application number	US-201616471554-A
Country	US
Kind code	B2
Filing date	Dec 21, 2016
Priority date	Dec 21, 2016
Publication date	Aug 13, 2024
Grant date	Aug 13, 2024

Abstract

The invention relates to a method for producing polymer powder compositions which are redispersible in water and which are based on polymerisates of one or more ethylenically unsaturated monomers. In a first step, an aqueous polymerisate dispersion is produced by means of a radically initiated polymerization of one or more ethylenically unsaturated monomers in an aqueous medium, said polymerisate dispersion being convened into the polymer powder composition which is redispersible in water by means of a diving process. The invention is characterized in that the polymerization and the drying process are each carried out in a continuous manner, and the polymerization and the diving process are carried out in separate interconnected modules.

First claim

The invention claimed is:

1. A modular, continuous process for producing a water redispersible polymer powder composition, comprising:
providing a polymerization module and, in a first step, continuously producing an aqueous polymer dispersion by free radical initiated polymerization of one or more ethylenically unsaturated monomers selected from the group consisting of vinyl esters of carboxylic acids having 1 to 15 carbon atoms, methacrylic esters of branched or unbranched alcohols having 1 to 15 carbon atoms, acrylic esters of branched or unbranched alcohols having 1 to 15 carbon atoms, olefins, dienes, vinyl aromatics, ethylenically unsaturated mono- and dicarboxylic acids, ethylenically unsaturated carboxamides, ethylenically unsaturated sulfonic acids and salts thereof, multiply ethylenically unsaturated comonomers, N-methylol acrylamide, epoxide-functional comonomers and silicon-functional comonomers, in an aqueous medium in the polymerization module and before, during, or after the polymerization, adding at least one protective colloid;
providing a separate drying module, and in a second step, continuously directing the aqueous polymer dispersion produced in the first step into the drying module without intermediate storage, and
recovering a water redispersible polymer powder from said second step, wherein the polymerization polymer dispersion flows from the polymerization module into the drying module via a pipeline.

2. The process of claim 1 , wherein the polymerization module and the drying module comprise separately transportable modules, each module individually optionally comprising one or more submodules.

3. The process of claim 2 , wherein at least one module is contained within a casing to facilitate transport.

4. The process of claim 1 , wherein the free radical initiated polymerization takes place in the presence of a protective colloid, and an emulsifier.

5. The process of claim 4 , wherein the protective colloid is present in such an amount that no further protective colloid is added to the aqueous polymer dispersion produced in the first step, prior to drying in the second step.

6. The process of claim 1 , wherein the protective colloid(s) is/are selected from the group consisting of polyvinyl alcohols.

Assignees

• Wacker Chemie Ag

Inventors

• Eckl Bernhard
• Kalchauer Michael
• Seidel Jessica
• Weitzel Hans-Peter

Classifications

• C08J3/122

  Pulverisation by spraying · CPC title

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• B29B2009/163

  Coating, i.e. applying a layer of liquid or solid material on the granule · CPC title

• B29B9/10

  by moulding the material, i.e. treating it in the molten state · CPC title

• C08F2/22 Primary

  Emulsion polymerisation · CPC title