Dispersion powder compositions comprising gemini surfactants

Patent metadata

Field	Value
Publication number	US-9334388-B2
Application number	US-92373107-A
Country	US
Kind code	B2
Filing date	Oct 25, 2007
Priority date	Oct 25, 2006
Publication date	May 10, 2016
Grant date	May 10, 2016

Abstract

The invention relates to water-redispersible dispersion powder compositions based on polymers of one or more ethylenically unsaturated monomers, wherein one or more gemini surfactants are present.

First claim

What is claimed is:

1. A water-redispersible polymer powder, comprising polymer particles prepared by emulsion polymerizing unsaturated monomers in an aqueous medium and spray drying a resulting polymer particle-containing aqueous medium containing from 3-30 weight percent based on polymer solids of protective colloid, and containing at least one gemini surfactant selected from the group consisting of alkynediols and alkynediol derivatives, the water-redispersible polymer powder further optionally comprising one or more antiblocking agents selected from the group consisting of calcium carbonate, magnesium carbonate, talc, gypsum, silica, kaolin, metakaolin, calcined kaolin, silicates, and mixtures thereof, wherein the polymer particles consist of polymerized residues of the unsaturated monomers, wherein the water-redispersible polymer powders redisperse in water to form dispersions containing polymer particles having particle sizes of from 0.1 μm to 5 μm, and wherein the water-redispersible polymer powder is suitable for adding to chemical building products containing hydraulically settable inorganic binders.

2. The water-redispersible polymer powder of claim 1 which is suitable for increasing hardness and/or decreasing voids in a self-leveling hydraulically settable flooring composition when added to the composition in amounts of less than or equal to 10% by weight based on the solids content of the composition.

3. The water-redispersible polymer powder of claim 1 , wherein the water-redispersible powders, when used at a 3 weight percent concentration in a self-leveling flooring composition of 20 weight percent Portland cement, 4 weight percent EFA filler, 50 weight percent silica sand, 22.7 weight percent calcium carbonate filler, and 0.3 weight percent casein, produces a higher quality surface than an otherwise similar composition not containing any of said gemini surfactant or containing said gemini surfactant added separately from the water-redispersible polymer powder.

4. The water-redispersible polymer powder of claim 1 , wherein the polymer particles consist of residues of monomers selected from the group consisting of vinyl esters of unbranched or branched alkylcarboxylic acids having from 1 to 15 carbon atoms, esters of (meth)acrylic acid with unbranched or branched alcohols having from 1 to 15 carbon atoms, vinylaromatics, olefins, dienes and vinyl halides, and optionally one or more auxiliary monomers in a total amount of from 0.05 to 50 weight percent.

5. The water-redispersible polymer powder of claim 1 , wherein the polymer particles consist of residues of monomers selected from the group consisting of vinyl acetate; vinyl acetate together with ethylene; vinyl acetate together with vinyl esters of α-branched monocarboxylic acids having from 5 to 13 carbon atoms; vinyl acetate together with vinyl esters of α-branched C 9 carboxylic acids and optionally ethylene; vinyl acetate together with vinyl esters of α-branched C 10 carboxylic acids and optionally ethylene; vinyl acetate together with vinyl laurate and optionally ethylene; and ethylene together with vinyl esters of α-branched monocarboxylic acids having from 5 to 13 carbon atoms.

6. The water-redispersible polymer powder of claim 1 , wherein at least one monomer residue is a residue of a monomer selected from the group consisting of ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl, isobutyl or t-butyl methacrylate, methyl acrylate, methyl methacrylate, n-butyl, isobutyl or t-butyl acrylate, 2-ethylhexyl acrylate and norbornyl acrylate.

7. The water-redispersible polymer powder of claim 1 , wherein the polymer consists of a vinyl acetate/ethylene copolymer.

8. The water-redispersible polymer powder of claim 1 , wherein a gemini surfactant derived from an alkynediol is an alkynediol derivative in which one or both of the alcohol groups of the alkynediol are substituted by polyethylene glycol radicals.

9. The water-redispersible polymer powder of claim 1 , wherein the gemini surfactant is a reaction product of an epoxide with an alkynediol.

10. The water-redispersible polymer powder of claim 1 , wherein the gemini surfactant includes at least one alkynediol of the formula (1)
RR 1 (R 2 O)C—C≡C—C(OR 2 )R 1 R  (1),

where
R and R 1 are each a linear or branched, substituted or unsubstituted alkyl, aryl or alkoxyalkyl radical having from 1 to 10 carbon atoms and
R 2 is a hydrogen atom or a polyethylene glycol chain of the formula (—CH 2 —CH 2 —O) n —CH 2 —CH 2 —OH where n=0.5 to 50, with the individual radicals R, R 1 and R 2 each have their meanings independently of one another.

11. The water-redispersible polymer powder of claim 1 , wherein an alkynediol of the formula (2)

or the reaction product of two equivalents [[(2-ethylhexyl)oxy]methyloxirane] with polyethylene glycol ether with one equivalent of alkynediol derivative of the formula (2), is used as a gemini surfactant.

12. A process for the preparation of the water-redispersible polymer powder of claim 1 , comprising polymerizing one or more ethylenically unsaturated monomers by aqueous emulsion polymerization to form an aqueous dispersion of polymer particles consisting of polymerized residues of said ethylenically unsaturated monomers, and spray drying said aqueous dispersion in the presence of at least one alkynediol or alkynediol derivative gemini surfactant and from 3 to 30% of at least one protective colloid to form a dry water-redispersible polymer powder.

13. The process of claim 12 , wherein no antiblocking agent is added.

14. The process of claim 12 , wherein an antiblocking agent is added to the dry water-redispersible polymer powder, in an amount of up to 30 weight percent based on the weight of the polymer particles.

15. The process of claim 12 , wherein the gemini surfactants are added after completion of the aqueous emulsion polymerization of the ethylenically unsaturated monomers.

16. The process of claim 12 , wherein the gemini surfactant is added to polymer dispersion following completion of polymerization and prior to spray drying.

17. The process of claim 12 , wherein the gemini surfactants are added during spray drying.

18. A building chemical product comprising at least one hydraulically settable inorganic binder, and a water-redispersible polymer powder of claim 1 .

19. The building chemical product of claim 18 which is a self-leveling flooring composition.

20. A building chemical product comprising:
a) from 5 to 10% by weight of the water-redispersible polymer powder of claim 1 ;
b) from 5 to 80% by weight of inorganic, hydraulically setting binders;
c) from 5 to 80% by weight of inorganic fillers, and
d) optionally, flow-promoting additives,

wherein the percents by weight are relative to the total weight of the building chemical product.

21. The building chemical product of claim 18 , wherein the polymer of the water-redispersible polymer powder is formed by polymerizing monomer(s) selected from the group consisting of ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl, isobutyl or t-butyl methacrylate, methyl acrylate, methyl methacrylate, n-butyl, isobutyl or t-butyl acrylate, 2-ethylhexyl acrylate and norbornyl acrylate.

22. The building chemical product of claim 18 , wherein the water-redispersible polymer powder consists of a vinyl aceta

Assignees

• Killat Marion
• Wacker Chemie Ag

Inventors

• Killat Marion

Classifications

• C04B2111/00672

  Pointing or jointing materials · CPC title

• C04B2103/406

  non-ionic · CPC title

• C04B2111/62

  Self-levelling compositions · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L2666/02

  Organic macromolecular compounds, natural resins, waxes or and bituminous materials · CPC title