Monitoring and controlling hydrophobic components in a pulp process

Patent metadata

Field	Value
Publication number	US-12044607-B2
Application number	US-201917418510-A
Country	US
Kind code	B2
Filing date	Dec 20, 2019
Priority date	Dec 28, 2018
Publication date	Jul 23, 2024
Grant date	Jul 23, 2024

Abstract

A sample of an aqueous stream is conducted to an optical measurement device. A hydrophobic dye is added. The sample is fractionated into fractions according to particle size or mass. Fluorescence intensity values and light scattering intensity values for the fractions are measured. Fluorescence intensity values of the fractions are added together thus obtaining a sum of the fluorescence intensity values. Light scattering intensity values of the fractions are added together, thus obtaining a sum of the light scattering intensity values. A hydro-phobicity density of the particles in the sample, is calculated by dividing the sum of the fluorescence intensity values with the sum of the light scattering intensity values. A concentration of hydrophobic contaminants in the aqueous stream is monitored and controlled based on the calculated hydrophobicity density of the particles in the sample.

First claim

The invention claimed is:

1. A method for monitoring and controlling hydrophobic contaminants in an aqueous stream of a pulp or papermaking process, the method comprising:
conducting a sample of the aqueous stream to an optical measurement device, the sample containing solid particles;
adding hydrophobic dye to the sample;
fractionating the sample into two or more fractions according to particle size and/or particle mass; and
measuring fluorescence intensity values and light scattering intensity values for each of the two or more fractions; the method further comprising:
adding together the fluorescence intensity values of the fractions thus obtaining a sum of the fluorescence intensity values;
adding together the light scattering intensity values of the fractions thus obtaining a sum of the light scattering intensity values;
calculating a hydrophobicity density of the particles in the sample by dividing the sum of the fluorescence intensity values with the sum of the light scattering intensity values, and
monitoring and controlling a concentration of hydrophobic contaminants in the aqueous stream based on the calculated hydrophobicity density of the particles in the sample,

or
adding together the fluorescence intensity values of a fraction thus obtaining a sum of the fluorescence intensity values in the fraction,
adding together the light scattering intensity values of the fraction thus obtaining a sum of the light scattering intensity values in the fraction,
calculating a hydrophobicity density of the particles in the fraction by dividing the sum of fluorescence intensity values of the fractions with the sum of light scattering intensity values of the fraction; and
monitoring and controlling the concentration of hydrophobic contaminants in the aqueous stream based on the calculated hydrophobicity density of the particles in the fraction.

2. A method as claimed in claim 1 , wherein the method further comprises:
controlling the concentration of hydrophobic contaminants in the aqueous stream by
manually and/or automatically adjusting a dosing of at least one chemical into the aqueous stream; and/or
manually and/or automatically adjusting a dosing of pulp washing water into the aqueous stream.

3. A method as claimed in claim 2 , further comprising:
controlling the dosing of pulp washing water into the aqueous stream based on the calculated hydrophobicity density of the particles in the sample and/or based on the calculated hydrophobicity density of the particles in the fractions.

4. A method as claimed in claim 1 , the method further comprising:
utilizing the calculated hydrophobicity density of the particles to deduce a concentration of wood pitch in the aqueous stream based on a predefined correlation between the concentration of the pitch particles and the hydrophobicity density.

5. A method as claimed in claim 1 , comprising, performing continuously as a function of time:
conducting the sample of the aqueous stream to the optical measurement device, the sample containing solid particles;
adding hydrophobic dye to the sample;
fractionating the sample into the two or more fractions according to particle size and/or particle mass;
measuring the fluorescence intensity values and the light scattering intensity values for each of the two or more fractions;
adding together the fluorescence intensity values measured continuously as a function of time, thus obtaining the cumulative sum of the fluorescence intensity values;
adding together the light scattering intensity values measured continuously as a function of time, thus obtaining the cumulative sum of the light scattering intensity value;
calculating the hydrophobicity density of the particles in the sample by dividing the cumulative sum of the fluorescence intensity values with the cumulative sum of the light scattering intensity values; and/or
calculating the hydrophobicity density of the particles in the fraction by dividing the fluorescence intensity values with the light scattering intensity values.

6. A method as claimed in claim 1 , wherein the fractionating comprises:
fractionating the sample into one or more of a colloid fraction, fines fraction, agglomerates fraction, and fiber fraction.

7. A method as claimed in claim 1 , wherein the hydrophobic contaminants are:
microstickies in a form of colloidal particles and/or particles adsorbed onto fine particles; and/or macrostickies.

8. A method as claimed in claim 1 , wherein the hydrophobic contaminants are pitch particles in a form of: colloidal particles, agglomerates and/or particles adsorbed onto fibers.

9. A method as claimed in claim 1 , comprising:
based on the calculated hydrophobicity density, controlling an amount and/or type of at least one chemical added to the aqueous stream, to control the concentration of hydrophobic contaminants.

10. A method as claimed in claim 1 , comprising:
based on the calculated hydrophobicity density, controlling a dosing into the aqueous stream of one or more of a dispersant, fixative, detackifier, retention aid, and surfactant.

11. A method as claimed in claim 1 , comprising:
taking the sample of the aqueous stream from filtrate water, dilute mass, or wire water.

12. A method as claimed in claim 1 , comprising:
adding chemicals and/or pulp washing water to the aqueous stream at a position that is located at a sample taking position, upstream of the sample taking position and/or downstream of the sample taking position.

13. An apparatus for monitoring and controlling hydrophobic contaminants in an aqueous stream of a pulp or papermaking process, the apparatus comprising:
a sampler configured to conduct a sample of the aqueous stream, the sample containing solid particles;
a dyer configured to add hydrophobic dye to the sample;
a fractionator configured to fractionate the sample into two or more fractions according to particle size and/or particle mass;
an optical measurement device configured to measure fluorescence intensity values and light scattering intensity values for each of the two or more fractions; and
a computer configured to:
add together the fluorescence intensity values of the fractions thus obtaining a sum of the fluorescence intensity values, and to add together the light scattering intensity values of the fractions thus obtaining a sum of the light scattering intensity values; and
calculate a hydrophobicity density of the particles in the sample by dividing the sum of the fluorescence intensity values with the sum of the light scattering intensity values;

or
add together the fluorescence intensity values of a fraction thus obtaining a sum of the fluorescence intensity values in the fraction, and to add together the light scattering intensity values of the fraction thus obtaining a sum of the light scattering intensity values in the fraction, and
calculate a hydrophobicity density of the particles in the fraction by dividing the sum of the fluorescence intensity values of the fraction with the sum of the light scattering intensity values of the fraction,

the apparatus including a controller configured to monitor and control a concentration of hydrophobic contaminants in the aqueous stream based on either:
the calculated hydrophobicity density of the particles fraction, or
the calculated hydrophobicity density of the particles in the sample.

14. An apparatus as claimed in claim 13 , wherein the controller is configured to:
control the concentration of hydrophobic contaminants in the aqueous stream by:
automatically adjusting the dosing of at least one chemical into the aqueous stream; and/

Assignees

• Kemira Oyj

Inventors

• Joensuu Iiris
• Piironen Marjatta
• Bergeron Andy
• Bjerketvedt Travis

Classifications

• G01N15/075

  by optical means · CPC title

• G01N33/343

  Paper pulp · CPC title

• G01N15/06 Primary

  Investigating concentration of particle suspensions (by weighing G01N5/00; investigating sedimentation of particle suspensions G01N15/04; investigating individual particles G01N15/10) · CPC title

• G01N30/0005

  Field flow fractionation · CPC title

• G01N15/0205

  by optical means · CPC title