Method of monitoring macrostickies in a recycling and paper or tissue making process involving recycled pulp

Patent metadata

Field	Value
Publication number	US-9562861-B2
Application number	US-201113079891-A
Country	US
Kind code	B2
Filing date	Apr 5, 2011
Priority date	Apr 5, 2011
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

A challenge in using recycled material in the papermaking process is the presence of hydrophobic organics with adhesive properties commonly known as “stickies.” Hydrophobic agglomerates can result in spots or defects in the final paper product or deposit on papermaking equipment resulting in poor runnability and downtime. Technologies for monitoring and controlling microstickies exist. However, a need exists for a technique to rapidly determine the size and content of macrostickies (diameter>100 microns) in recycled pulp process streams. The present invention is a device and method to perform real-time macrostickies and/or any visible hydrophobic particle analysis in an aqueous medium. Using the present invention, furnish quality can be monitored and treatment performance can be monitored and controlled. The technique is based on fluorescence image analysis to identify and count sticky particles as well as measure their size.

First claim

We claim:

1. A method for measuring the effectiveness of an additive added to an aqueous pulp slurry for decreasing macrostickie contaminants, the method comprising:
shining light into an aqueous pulp slurry comprising macrostickie and non-macrostickie contaminants flowing across a streamlined body;
adding a hydrophobic dye to the aqueous pulp slurry, such that the hydrophobic dye interacts with the macrostickie and non-macrostickie contaminants, the interaction causing a first modified fluorescent emission;
capturing a digital image of the first modified fluorescent emission, the digital image having a background;
correcting the background of the digital image;
filtering from the digital image the first modified fluorescent emission caused by the non-macrostickie contaminant to create a first filtered image;
adding an additive to the aqueous pulp slurry;
repeating the shining, adding, detecting, capturing, correcting, and filtering to create a second filtered image; and
comparing the first filtered image to the second filtered image to determine the effectiveness of the additive;
wherein the streamlined body narrows the flow of the aqueous pulp slurry in the measurement area.

2. The method of claim 1 , further comprising measuring a variable of the aqueous pulp slurry based on the altered digital image, wherein the variable is selected from a particle size distribution of macrostickies in the aqueous pulp slurry and a concentration of macrostickies in the aqueous pulp, and combinations thereof.

3. The method of claim 1 , wherein the hydrophobic dye is a solvatochromatic dye comprised of a chemical selected from the group consisting of a phenoxazone dye, a carbocyanine, a pyridinium betaine dye, a polysulfonated pyrene, a rhodamine, a fluorescein, and combinations thereof.

4. The method of claim 1 , wherein the hydrophobic dye is Nile Red.

5. The method of claim 1 , wherein the hydrophobic dye is dissolved in a solvent that is miscible in water.

6. The method of claim 1 , wherein the aqueous pulp slurry originates from a processing stage selected from the group consisting of a repulping stage, a deinking stage, a water loop stage, a wet-end stock preparation stage, a papermaking stage, and a tissuemaking stage.

7. The method of claim 1 , wherein capturing a digital image of the modified fluorescent emission further includes capturing a digital image of modified fluorescent emission due to the presence in the slurry of contaminant other than macrostickies, and altering the digital image comprising strengthening the captured modified fluorescent emission due to the presence of macrostickies, and weakening the captured modified fluorescent emission due to the presence of contaminant other than macrostickies.

8. The method of claim 7 , wherein altering the digital image further comprises filtering the digital image to remove weakened modified fluorescent emission and measuring the strengthened captured modified fluorescent emission.

9. The method of claim 7 , wherein at least the capturing, the altering, and the measuring are repeated.

10. The method of claim 1 , wherein the capturing is performed at a flow-through cell having an optical access window coated with a hydrophobic material.

11. A method of monitoring a variable, the method comprising;
shining light into an aqueous pulp slurry having visible contaminants flowing across a streamlined body;
adding a hydrophobic dye into the aqueous pulp slurry such that a modified fluorescent emission occurs and is capturable in the flow across the streamlined body;
capturing, via a digital camera, a digital image of the modified fluorescent emission in the aqueous pulp slurry flowing across the streamlined body;
altering the digital image to isolate the fluorescent emission caused by the interaction of the hydrophobic dye with at least one visible contaminant of the visible contaminants;
and measuring the variable of the aqueous pulp slurry based on the altered digital image;
wherein the streamlined body narrows the flow of the aqueous pulp slurry in the measurement area;
wherein the variable is selected from concentration of the visible contaminants, average particle size of the visible contaminants, effectiveness of an additive added to the aqueous pulp slurry, and combinations thereof.

12. The method of claim 11 , wherein the hydrophobic dye is a solvatochromatic dye comprised of a chemical selected from a phenoxazone dye, a carbocyanine, a pyridinium betaine dye, a polysulfonated pyrene, a rhodamine, a fluorescein, and combinations thereof.

13. The method of claim 11 , wherein the hydrophobic dye is Nile Red.

14. The method of claim 11 , wherein the altering comprises correcting the digital image, the correcting strengthening the captured modified fluorescent emission caused by the interaction of the hydrophobic dye and the visible contaminant, and weakening the captured modified fluorescent emission caused by the interaction of the hydrophobic dye and anything other than the visible contaminant.

15. The method of claim 1 , wherein one or more of the macrostickie contaminants have a particle size of 100 microns or more.

16. The method of claim 11 , wherein one or more of the macrostickie contaminants have a particle size of 100 microns or more.

17. The method of claim 11 , wherein the aqueous pulp slurry originates from a processing stage selected from the group consisting of a repulping stage, a deinking stage, a water loop stage, a wet-end stock preparation stage, a papermaking stage, and a tissuemaking stage.

18. The method of claim 11 , wherein at least the capturing, the altering, and the measuring are repeated.

19. The method of claim 11 , wherein the variable is the concentration of the visible contaminants.

20. The method of claim 1 , wherein the light is from a LED light source.

21. The method of claim 11 , wherein the light is from a LED light source.

Assignees

• Von Drasek William A
• Brotherson Brett
• Shevchenko Sergey M
• Murcia Michael J
• Nalco Co

Inventors

• Von Drasek William A
• Brotherson Brett
• Shevchenko Sergey M
• Murcia Michael J

Classifications

• G01N21/85

  Investigating moving fluids or granular solids · CPC title

• G01N21/643

  non-biological material · CPC title

• G01N21/6458

  Fluorescence microscopy (fluorescence microscopes per se G02B21/0076 and G02B21/16) · CPC title

• G01N33/343

  Paper pulp · CPC title

• G01N21/6486 Primary

  Measuring fluorescence of biological material, e.g. DNA, RNA, cells (G01N21/6428 takes precedence) · CPC title