Ionic conductor containing high-temperature phase of LiCB9H10, method for manufacturing same, and solid electrolyte for all-solid-state battery containing said ion conductor

US12043551B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-12043551-B2
Application numberUS-201917267185-A
CountryUS
Kind codeB2
Filing dateAug 16, 2019
Priority dateAug 23, 2018
Publication dateJul 23, 2024
Grant dateJul 23, 2024

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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Abstract

Official abstract text for this publication.

A method for manufacturing an ion conductor including LiCB9H10 and LiCB11H12 is provided. The method includes mixing LiCB9H10 and LiCB11H12 in a molar ratio of LiCB9H10/LiCB11H12=1.1 to 20. An ion conductor including lithium (Li), carbon (C), boron (B) and hydrogen (H) is also provided. The ion conductor has X-ray diffraction peaks at at least 2θ=14.9±0.3 deg, 16.4±0.3 deg and 17.1±0.5 deg in X ray diffraction measurement at 25° C., and has an intensity ratio (B/A) of 1.0 to 20 as calculated from A=(X-ray diffraction intensity at 16.4±0.3 deg)−(X-ray diffraction intensity at 20 deg) and B=(X-ray diffraction intensity at 17.1±0.5 deg)−(X-ray diffraction intensity at 20 deg).

First claim

Opening claim text (preview).

The invention claimed is: 1. A method for manufacturing an ion conductor comprising LiCB 9 H 10 and LiCB 11 H 12 , comprising: mixing LiCB 9 H 10 and LiCB 11 H 12 in a molar ratio of LiCB 9 H 10 /LiCB 11 H 12 =1.1 to 20. 2. The method for manufacturing an ion conductor according to claim 1 , wherein the mixing is conducted by mechanical milling treatment. 3. The method for manufacturing an ion conductor according to claim 2 , wherein a period of time for conducting the mechanical milling treatment is 1 to 48 hours. 4. The method for manufacturing an ion conductor according to claim 1 , wherein the obtained ion conductor has X-ray diffraction peaks at at least 2θ=14.9±0.3 deg, 16.4±0.3 deg and 17.1±0.5 deg in X ray diffraction measurement at 25° C., and has an intensity ratio (B/A) of 1.0 to 20 as calculated from A=(X-ray diffraction intensity at 16.4±0.3 deg)−(X-ray diffraction intensity at 20 deg) and B−(X-ray diffraction intensity at 17.1±0.5 deg)−(X-ray diffraction intensity at 20 deg). 5. An ion conductor comprising lithium (Li), carbon (C), boron (B) and hydrogen (H), wherein the ion conductor comprises LiCB 9 H 10 and LiCB 11 H 12 in a molar ratio of LiCB 9 H 10 /LiCB 11 H 12 =1.1 to 20, wherein the ion conductor has X-ray diffraction peaks at at least 2θ=14.9±0.3 deg, 16.4±0.3 deg and 17.1±0.5 deg in X ray diffraction measurement at 25° C., and has an intensity ratio (B/A) of 1.0 to 20 as calculated from A=(X-ray diffraction intensity at 16.4±0.3 deg)−(X-ray diffraction intensity at 20 deg) and B=(X-ray diffraction intensity at 17.1±0.5 deg)−(X-ray diffraction intensity at 20 deg). 6. The ion conductor according to claim 5 , wherein the ion conductor has peaks at 749 cm −1 (+5 cm −1 ) and 763 cm −1 (+5 cm −1 ) respectively in Raman spectroscopy. 7. The ion conductor according to claim 5 , wherein the ion conductor has an ion conductivity of 1.0 to 10 mScm −1 at 25° C. 8. A solid electrolyte for an all-solid battery comprising the ion conductor according to claim 5 . 9. An electrode formed by contacting the solid electrolyte according to claim 8 with metallic lithium. 10. An all-solid battery comprising the electrode according to claim 9 .

Assignees

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Classifications

  • Solid electrolytes · CPC title

  • Physical characteristics, e.g. porosity, surface area · CPC title

  • Methods for charging or discharging (circuits for charging H02J7/00) · CPC title

  • Solid materials · CPC title

  • Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

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What does patent US12043551B2 cover?
A method for manufacturing an ion conductor including LiCB9H10 and LiCB11H12 is provided. The method includes mixing LiCB9H10 and LiCB11H12 in a molar ratio of LiCB9H10/LiCB11H12=1.1 to 20. An ion conductor including lithium (Li), carbon (C), boron (B) and hydrogen (H) is also provided. The ion conductor has X-ray diffraction peaks at at least 2θ=14.9±0.3 deg, 16.4±0.3 deg and 17.1±0.5 deg in X…
Who is the assignee on this patent?
Mitsubishi Gas Chemical Co, Tohoku Techno Arch Co Ltd
What technology area does this patent fall under?
Primary CPC classification H01M10/0562. Mapped technology areas include Electricity.
When was this patent published?
Publication date Tue Jul 23 2024 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 5 related publications on this page (citations in our corpus or others sharing the same primary CPC).