Polyacetal resin composition, extrusion-molded article, and injection-molded article

Patent metadata

Field	Value
Publication number	US-12037486-B2
Application number	US-202117801660-A
Country	US
Kind code	B2
Filing date	Mar 3, 2021
Priority date	Mar 12, 2020
Publication date	Jul 16, 2024
Grant date	Jul 16, 2024

Abstract

The present invention provides a polyacetal resin composition, which comprises a polyacetal resin, and which further comprises the following (A), (B) and (C), with respect to 100 parts by weight of the polyacetal resin: (A) 0.05 to 5.5 parts by weight of a low-density polyethylene having a melt flow rate of 1.0 to 50 g/10 minutes (190° C., 2.16 kg), (B) 0.05 to 2.0 parts by weight of a fatty acid compound (excluding calcium stearate), and (C) 0.001 to 1.0 part by weight of a layered double hydroxide represented by the following general formula (1): [(M 2+ ) x (M 3+ ) y (OH) 2(x+y) ](A n− ) x/n − (H 2 O) (1) (wherein, in the general formula (1), M 2+ represents a divalent metal ion, M 3+ represents a trivalent metal ion, A n− represents an n-valent anion, wherein one or more of the anions are contained in the layered double hydroxide, x represents a number in the range of 0<x≤ 6.0, n represents 1, 2, or 3, and y and z each represent a number of 0 or greater).

First claim

The invention claimed is:

1. A polyacetal resin composition consisting of a polyacetal resin and the following (A), (B), (C) and (D) with respect to 100 parts by weight of the polyacetal resin:
(A) 0.05 to 5.5 parts by weight of a low-density polyethylene having a melt flow rate of 1.0 to 50 g/10 minutes (190° C., 2.16 kg),
(B) 0.05 to 2.0 parts by weight of a fatty acid compound (excluding calcium stearate),
(C) 0.001 to 1.0 part by weight of hydrotalcite, and
(D) 0.01 to 5.0 parts by weight of a sterically hindered phenol and/or a nitrogen-containing compound; wherein
the polyacetal resin is prepared by a method that consists of copolymerizing a cyclic acetal comprising an oxymethylene group with a cyclic acetal comprising an oxyalkylene group containing 2 to 5 carbon atoms, and
the fatty acid compound is a fatty acid ester, a fatty acid amide, or a combination thereof.

2. The polyacetal resin composition according to claim 1 ,
wherein the cyclic acetal comprising an oxymethylene group is selected from the group consisting of trioxane and tetraoxane, and the cyclic acetal comprising an oxyalkylene group containing 2 to 5 carbon atoms is selected from the group consisting of ethylene oxide, 1,3-dioxolane, 1,3,6-trioxocane and 1,3-dioxepane.

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Sunaga Daisuke

Classifications

• C08L2207/066

  LDPE (radical process) · CPC title

• C08L23/06

  Polyethylene · CPC title

• C08K2003/267

  Magnesium carbonate · CPC title

• C08K5/20

  Carboxylic acid amides · CPC title

• C08K5/10

  Esters; Ether-esters · CPC title