High temperature fiber, method of making and high temperature fiber composites

Patent metadata

Field	Value
Publication number	US-12030820-B2
Application number	US-201916536725-A
Country	US
Kind code	B2
Filing date	Aug 9, 2019
Priority date	Aug 9, 2019
Publication date	Jul 9, 2024
Grant date	Jul 9, 2024

Abstract

Disclosed is a method of making high temperature fiber including chemically bonding high temperature material to a fiber template at a first temperature to form a precursor fiber and processing the precursor fiber at a second temperature to form the high temperature fiber. The first temperature does not equal the second temperature. Also disclosed are high temperature fibers made by the method.

First claim

What is claimed is:

1. A method of making a high temperature fiber comprising:
chemically bonding material to a fiber template at a first temperature to form a precursor fiber, the material bonded to the fiber template having a thickness greater than a radius of the fiber template; and
processing the precursor fiber at a second temperature to form the high temperature fiber;
wherein the first temperature does not equal the second temperature, and the first temperature is 250° C. to 500° C.;
wherein the high temperature fiber is a fiber which maintains shape and integrity at temperatures greater than or equal to 800° C.; and
wherein processing the precursor fiber to form the high temperature fiber further comprises additional chemical reactions, alterations to microstructure, alterations to crystalline phases, alterations to grain size, or combinations thereof;
wherein the fiber template comprises aluminum oxide, zirconium oxide, yttrium oxide, titanium dioxide, mullite, aluminosilicate, zirconium oxide, yttrium aluminum garnet, SiC, SiNC, SiOC, SiCNO, SiBCN, BN, Si 3 N 4 , SiAlCN, SiC/AlN, geopolymers, basalt, a carbide such as boron carbide, HfC, ZrC, S-glass, E-glass, A-glass, D-glass, silica, and combinations thereof.

2. The method of claim 1 , wherein the fiber template comprises aluminum oxide, zirconium oxide, yttrium oxide, titanium dioxide, mullite, aluminosilicate, zirconium oxide, yttrium aluminum garnet, BN, Si 3 N 4 , geopolymers, basalt, S-glass, E-glass, A-glass, D-glass, silica, and combinations thereof.

3. The method of claim 1 , wherein the fiber template comprises a hollow tube and chemically bonding the material to the fiber template occurs on the inside of the tube, the outside of the tube or both.

4. The method of claim 1 , wherein the material bonded to the fiber template comprises a nitride, carbide, boride, oxide, phosphide, selenide, silicide, precursors to the foregoing, or combination thereof.

5. The method of claim 1 , wherein processing comprises exposure to temperatures of 500 to 2300° C.; and
wherein the thickness of the material bonded to the fiber template after processing is greater than or equal to 30 nm; and
wherein the thickness of the material bonded to the fiber template after processing has a thickness greater than the radius of a central region of the fiber template.

6. The method of claim 1 , wherein chemically bonding occurs by atomic layer deposition; and
wherein the high temperature fiber comprises a first region and a second region, and the first region surrounds the second region and the average grain size of the first region is less than the average grain size of the second region.

7. The method of claim 1 , further comprising pretreating the fiber template before chemical bonding, wherein pretreating comprises thermal or radiation exposure.

8. The method of claim 1 , wherein the high temperature fiber comprises a central portion and the central portion comprises a doped composition.

9. The method of claim 8 , wherein the high temperature fiber consists of the central portion.

10. The method of claim 1 , wherein the high temperature fiber comprises a central portion and the central portion comprises more than one phase.

11. The method of claim 10 , wherein the high temperature fiber consists of the central portion.

Assignees

• Rtx Corp

Inventors

• Sheedy Paul
• Magdefrau Neal
• Schmidt Wayde R

Classifications

• C04B2111/00379

  the oriented elements being fibres · CPC title

• C04B41/89

  for obtaining at least two superposed coatings having different compositions · CPC title

• C04B35/62855

  Refractory metal oxides · CPC title

• C04B35/62849

  Silica or silicates · CPC title

• C04B35/58064

  based on refractory borides · CPC title