Photosensitive resin structure for flexographic printing plate and method for producing flexographic printing plate

Patent metadata

Field	Value
Publication number	US-12019374-B2
Application number	US-202118037437-A
Country	US
Kind code	B2
Filing date	Dec 14, 2021
Priority date	Jan 20, 2021
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

A photosensitive resin structure for a flexographic printing plate, including: a support (a); a photosensitive resin composition layer (b) laminated on the support (a); and an infrared ray ablation layer (c) laminated on the photosensitive resin composition layer (b), wherein the infrared ray ablation layer (c) contains a resin having a predetermined constituent unit (c1).

First claim

The invention claimed is:

1. A photosensitive resin structure for a flexographic printing plate, comprising:
a support (a);
a photosensitive resin composition layer (b) laminated on the support (a); and
an infrared ray ablation layer (c) laminated on the photosensitive resin composition layer (b),
wherein the infrared ray ablation layer (c) comprises a resin having a constituent unit c1 represented by the following formula (1):

wherein R 1 and R 2 each independently represent a non-polar group, and R 3 and R 4 each independently represent a hydrogen atom or a non-polar group.

2. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein
a content of the constituent unit (c1) is 40% by mass or more and 100% by mass or less based on a total amount of the resin.

3. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein
R 3 and R 4 of the formula (1) are each independently a hydrogen atom, an alkyl group, an aryl group, a cycloalkyl group, a phenyl group, an alkenyl group, an aralkyl group, a cycloalkenyl group, an alkynyl group, a silyl group, or a siloxanyl group.

4. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein R 3 and R 4 of the formula (1) are a hydrogen atom.

5. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein
R 1 and R 2 of the formula (1) are each independently an alkyl group, an aryl group, a cycloalkyl group, a phenyl group, an alkenyl group, an aralkyl group, a cycloalkenyl group, an alkynyl group, a silyl group, or a siloxanyl group.

6. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein
R 1 and R 2 of the formula (1) are each independently an alkyl group or a phenyl group.

7. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein
R 1 and R 2 of the formula (1) are an alkyl group.

8. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein
the resin further has a constituent unit (c2) which is different from the constituent unit (c1) and has an aromatic group in a side chain.

9. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein
the constituent unit (c2) includes a constituent unit derived from a monovinyl-substituted aromatic hydrocarbon.

10. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein
the infrared ray ablation layer (c) comprises carbon black, and
pH of the carbon black is 2.0 or higher and 5.0 or lower.

11. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein
the infrared ray ablation layer (c) comprises a dispersant, and
a solubility parameter (SP value) of the dispersant is 9.5 or more and 12.5 or less.

12. The photosensitive resin structure for the flexographic printing plate according to claim 1 , wherein
a mixing ratio of the resin to the carbon black (resin/carbon black) in the infrared ray ablation layer (c) is in a range of 80/20 to 50/50.

13. A method for producing a flexographic printing plate, using the photosensitive resin structure for the flexographic printing plate according to claim 1 , and comprising:
first performing ultraviolet ray irradiation from a side of the support (a)
second drawing and processing a pattern on the infrared ray ablation layer (c) by infrared ray irradiation;
third irradiating the photosensitive resin composition layer (b) with an ultraviolet ray for pattern exposure using, as a mask, the infrared ray ablation layer (c) on which the pattern is drawn and processed; and
fourth removing the infrared ray ablation layer (c) and an unexposed portion of the photosensitive resin composition layer (b).

14. A flexographic printing method using the photosensitive resin structure for the flexographic printing plate according to claim 1 , and comprising:
first performing ultraviolet ray irradiation from a side of the support (a);
second drawing and processing a pattern on the infrared ray ablation layer (c) by infrared ray irradiation;
third irradiating the photosensitive resin composition layer (b) with an ultraviolet ray for pattern exposure using, as a mask, the infrared ray ablation layer (c) on which the pattern is drawn and processed;
fourth removing the infrared ray ablation layer (c) and an unexposed portion of the photosensitive resin composition layer (b) to produce a flexographic printing plate; and
fifth performing printing using the flexographic printing plate.

Assignees

• Asahi Chemical Ind

Inventors

• Akiyama Hiroki
• Miyamoto Shinji

Classifications

• C08F120/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08F10/10

  Isobutene · CPC title

• B41F5/24

  for flexographic printing · CPC title

• B41C1/10

  for lithographic printing; Master sheets for transferring a lithographic image to the forme {(chemical or electrical pretreatment B41N3/03)}(neutralising or similar differentiation treatments of lithographic printing formes B41N3/08) · CPC title

• G03F7/202

  Masking pattern being obtained by thermal means, e.g. laser ablation · CPC title