Method for preparing nickel sulfate using low-nickel ferronickel

Patent metadata

Field	Value
Publication number	US-12017927-B2
Application number	US-202218555735-A
Country	US
Kind code	B2
Filing date	May 27, 2022
Priority date	Aug 3, 2021
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

The present invention relates to a method for preparing nickel sulfate using low-nickel ferronickel is disclosed. The method comprises the following steps: (1) grinding ferronickel to obtain ferronickel powder, and then sintering the ferronickel powder with an oxidant to prepare ferronickel oxide powder; (2) adding sulfuric acid to the ferronickel oxide powder prepared in step (1), mixing, heating, and washing with water to prepare a sulfate salt water washing solution; (3) adding a base to the sulfate salt water washing solution prepared in step (2) to adjust the pH value, then adding a fluoride salt to form a precipitate, filtering to remove the precipitate, and drying the filtrate to obtain nickel sulfate. The method provided in the present invention can improve the efficiency of preparing nickel sulfate, reduce the loss of nickel, and prepare nickel sulfate with high purity, the content of Ni potentially reaching 19.73%-21.34%.

First claim

The invention claimed is:

1. A method for preparing nickel sulfate using ferronickel, comprising the following steps:
(1) grinding ferronickel to obtain ferronickel powder, and then sintering the ferronickel powder in the presence of an oxidant to prepare ferronickel oxide powder;
(2) adding sulfuric acid to the ferronickel oxide powder prepared in step (1), mixing, heating, and washing with water to prepare a sulfate water wash liquid;
(3) adding alkali to the sulfate water wash liquid prepared in step (2) to adjust the pH value, then adding fluoride salt to form a precipitate, performing filtration to remove the precipitate, and drying the filtrate to obtain nickel sulfate;
wherein in step (3), before drying the filtrate, an extractant is added to perform extraction to obtain a raffinate phase and a nickel-loaded organic phase, and then the nickel-loaded organic phase is back-extracted by sulfuric acid to obtain nickel sulfate;
the extractant comprises sodium dodecyl sulfate, bis(2,4,4-trimethylpentyl) dithiophosphonic acid, tributyl phosphate, and sulfonated kerosene;
a volume ratio of sodium dodecyl sulfate, bis(2,4,4-trimethylpentyl) dithiophosphonic acid, tributyl phosphate, and sulfonated kerosene is (1-10):(5-20):(1-10):(60-90).

2. The method according to claim 1 , wherein step (1) further comprises adding ammonium sulfate during the grinding.

3. The method according to claim 2 , wherein a mass of the ammonium sulfate is 0.3%-2% of the mass of the ferronickel.

4. The method according to claim 1 , wherein in step (1), a temperature of the sintering is 700-1100° C., and a time of the sintering is 60-200 min; the oxidant is selected from one of air, O 2 and H 2 O 2 .

5. The method according to claim 1 , wherein the process of step (2) comprises: adding sulfuric acid to part of the ferronickel oxide powder prepared in step (1) and mixing them to obtain slurry A; then performing a first heating to the slurry A, adding part of the ferronickel oxide powder prepared in step (1) to the slurry A to obtain slurry B, performing a second heating and washing with water to obtain a sulfate water wash liquid.

6. The method according to claim 5 , wherein in the slurry A, a ratio of mass of the ferronickel oxide powder to volume of the sulfuric acid is 1 kg:(4-15) L; and in the slurry B, a ratio of mass of the ferronickel oxide powder to volume of the sulfuric acid is 1 kg:(1-3) L.

7. The method according to claim 5 , wherein a temperature of the first heating is 300-500° C., and a time of the first heating is 10-60 min; a temperature of the second heating is 600-800° C., and a time of the second heating is 10-60 min.

Assignees

• Guangdong Brunp Recycling Technology Co Ltd
• Hunan Brunp Recycling Tech Co Ltd
• Hunan Brunp Ev Recycling Co Ltd

Inventors

• Yu Haijun
• Zhong Yingsheng
• Xie Yinghao
• Li Aixia
• Zhang Xuemei
• Li Changdong

Classifications

• C01G53/10 Primary

  Sulfates · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• C22B23/043

  Sulfurated acids or salts thereof · CPC title

• C01P2006/80

  Compositional purity · CPC title

• C01P2004/03

  obtained by SEM · CPC title