Methods of selectively recovering palladium from a palladium-containing material

Patent metadata

Field	Value
Publication number	US-12012642-B2
Application number	US-201916541930-A
Country	US
Kind code	B2
Filing date	Aug 15, 2019
Priority date	Aug 15, 2019
Publication date	Jun 18, 2024
Grant date	Jun 18, 2024

Abstract

A method of selectively recovering palladium from a palladium-containing material comprises providing a leaching solution comprising hydrochloric acid, hydrogen peroxide, and an iron salt comprising one or both of ferric chloride or ferrous chloride and contacting a palladium-containing material with the leaching solution to dissolve palladium from the palladium-containing material. Related methods of selectively recovering palladium from a palladium-containing material are also disclosed.

First claim

What is claimed is:

1. A method of selectively recovering palladium from a palladium-containing material, the method comprising:
providing a leaching solution comprising hydrochloric acid, hydrogen peroxide, and an iron salt comprising one or both of ferric chloride or ferrous chloride;
contacting a palladium-containing material with the leaching solution to dissolve palladium from the palladium-containing material; and
contacting the dissolved palladium with one or more of zinc, aluminum, or tin to precipitate palladium from the leaching solution.

2. The method of claim 1 , wherein providing a leaching solution comprises providing a leaching solution having a ratio of iron ions to hydrogen peroxide within a range from about 1.0:50.0 to about 1.0:250.

3. The method of claim 1 , wherein providing a leaching solution comprises providing a leaching solution comprising the iron salt within a range from about 1.0 mM to about 20.0 mM.

4. The method of claim 1 , wherein providing a leaching solution comprises providing a leaching solution comprising:
between about 0.01 M and about 10.0 M hydrochloric acid;
between about 0.1 weight percent to about 30.0 weight percent hydrogen peroxide; and
between about 1.0 mM and about 20.0 mM of the iron salt.

5. The method of claim 1 , wherein contacting a palladium-containing material with the leaching solution comprises contacting a catalytic converter with the leaching solution.

6. The method of claim 1 , wherein providing a leaching solution comprises providing a leaching solution comprising about 1.0 part ferric ions for between about 100 and about 200 parts hydrochloric acid.

7. The method of claim 1 , wherein providing a leaching solution comprises providing a leaching solution comprising ferric ions within a range of from about 5.0 mM to about 50 mM for every about 1.0 M of hydrochloric acid.

8. The method of claim 1 , wherein providing a leaching solution comprises providing a leaching solution comprising from about 50.0 to about 250 parts by weight hydrogen peroxide for every about 1.0 part by weight of ferric ions.

9. The method of claim 1 , wherein providing a leaching solution comprises providing a leaching solution at a temperature within a range from about 15° C. to about 80° C.

10. The method of claim 1 , wherein providing a leaching solution comprises providing a leaching solution at a temperature within a range from about 18° C. to about 25° C.

11. A method of selectively recovering palladium from a palladium-containing material, the method comprising:
contacting, at a temperature less than about 25° C., a palladium-containing material with a leaching solution to form a solution comprising dissolved palladium, the leaching solution comprising:
from about 1.0 M to about 2.0 M hydrochloric acid;
from about 1.0 weight percent to about 10.0 weight percent hydrogen peroxide; and
from about 5 mM ferrous chloride to about 10 mM ferrous chloride; and

removing the dissolved palladium from the solution comprising dissolved palladium.

12. The method of claim 1 , wherein contacting a palladium-containing material with the leaching solution to dissolve palladium from the palladium-containing material comprises dissolving palladium from the palladium-containing material without dissolving platinum from the palladium-containing material.

13. The method of claim 1 , wherein providing a leaching solution comprising hydrochloric acid, hydrogen peroxide, and an iron salt comprising one or both of ferric chloride or ferrous chloride comprises providing the leaching solution to a leaching vessel, and further comprising:
contacting the dissolved palladium with one or more of zinc, aluminum, or tin to precipitate palladium from the leaching solution and form a palladium-free solution; and
recycling at least a portion of the palladium-free solution to the leaching vessel.

14. A method of selectively recovering palladium from a palladium-containing material, the method comprising:
providing a leaching solution comprising hydrochloric acid, hydrogen peroxide, and an iron salt comprising one or both of ferric chloride or ferrous chloride, the leaching solution comprising less ferric ions by weight than the hydrogen peroxide by weight; and
contacting a palladium-containing material with the leaching solution to dissolve palladium from the palladium-containing material.

15. The method of claim 1 , wherein providing a leaching solution comprising hydrochloric acid, hydrogen peroxide, and an iron salt comprising one or both of ferric chloride or ferrous chloride comprises providing a leaching solution comprising between about 80 parts and about 90 parts by weight of hydrogen peroxide for every about 1.0 part by weight of one or both of ferric ions or ferrous ions.

Assignees

• Battelle Energy Alliance Llc

Inventors

• Lister Tedd E
• Diaz Aldana Luis A

Classifications

• C22B3/10

  Hydrochloric acid {, other halogenated acids or salts thereof} · CPC title

• Y02P10/20

  Recycling · CPC title

• C22B3/46

  by substitution, e.g. by cementation · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title

• C22B11/048

  from spent catalysts · CPC title