Two-component curable composition for manufacturing thermoplastic polyurethane resin, thermoplastic polyurethane resin, and fiber-reinforced resin
US-11891511-B2 · Feb 6, 2024 · US
US12012479B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12012479-B2 |
| Application number | US-201917284922-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 13, 2019 |
| Priority date | Dec 3, 2018 |
| Publication date | Jun 18, 2024 |
| Grant date | Jun 18, 2024 |
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Disclosed herein is a polyurethane resin containing, as copolymerization components, a polycarbonate polyol (A), an organic diisocyanate (B) and a chain extender (C), wherein the polycarbonate polyol (A) contains a specific structure in an amount of 60 mol % or more and a glass transition temperature of the polyurethane resin is 50° C. or higher. The polyurethane resin has excellent heat resistance and satisfactory adhesive property to various substrates, and is usable as an adhesive composition.
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The invention claimed is: 1. A polyurethane resin containing, as copolymerization components, a polycarbonate polyol (A), an organic diisocyanate (B) and a chain extender (C), wherein the polycarbonate polyol (A) contains a structure represented by the following general formula (1) in an amount of 60 mol % or more, wherein a copolymerization content of the organic diisocyanate (B) is 1 part by mass or more and 50 parts by mass or less, relative to 100 parts by mass of the polycarbonate polyol (A), wherein the chain extender (C) is a polyol compound, and wherein a glass transition temperature of the polyurethane resin is 50° C. or higher, wherein in general formula (1), n represents an integer of 1 to 20. 2. The polyurethane resin according to claim 1 , wherein the organic diisocyanate (B) is isophorone diisocyanate, 4,4′-diphenylmethane diisocyanate or hexamethylene diisocyanate. 3. The polyurethane resin according to claim 1 , wherein the chain extender (C) is a glycol compound having 10 or less carbon atoms. 4. An adhesive composition comprising the polyurethane resin according to claim 1 and a crosslinking agent. 5. A binder for screen inks comprising the polyurethane resin according to claim 1 and a crosslinking agent. 6. A binder for decorative molding comprising the polyurethane resin according to claim 1 and a crosslinking agent.
Polyurethanes · CPC title
containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group · CPC title
acyclic · CPC title
Polycarbonates · CPC title
Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen {(C08G18/2805 takes precedence)} · CPC title
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