Process for refining crude tall oil

Patent metadata

Field	Value
Publication number	US-11987768-B2
Application number	US-202318208412-A
Country	US
Kind code	B2
Filing date	Jun 12, 2023
Priority date	Jun 15, 2022
Publication date	May 21, 2024
Grant date	May 21, 2024

Abstract

The disclosure relates to a method for refining crude tall oil, wherein the method comprises first evaporating tall oil material (10) in a first evaporator (100) whereafter the first fraction (11) is fed to a first distilling column (200) and the second fraction (12) is fed to further evaporation. The condensate(s) recovered from the further evaporation(s) is fed to a second distilling column (300).The present disclosure further concerns the use of different fractions obtained by the method for the production of biofuels or components thereof.

First claim

The invention claimed is:

1. A method for refining crude tall oil, characterized in that the method comprises
(a) evaporating tall oil material ( 10 ) in a first evaporator ( 100 ) at a temperature between 255 and 295° C. and a pressure between 80 and 220 mbar to obtain a first fraction ( 11 ) comprising crude sulphate turpentine, light fatty acids, light neutrals, silicon compounds and water and a second fraction ( 12 ) comprising fatty acids, resin acids, neutral substances and residue components;
(b1) evaporating said second fraction ( 12 ) in a second evaporator ( 110 ) at a temperature between 230 and 270° C. and a pressure between 5 and 20 mbar to obtain a third fraction ( 13 ) comprising fatty acids, resin acids and light neutral substances, and a first concentrate fraction ( 14 ); and evaporating said first concentrate fraction ( 14 ) in a third evaporator ( 120 ) at a temperature between 280 and 320° C. and a pressure between 5 and 20 mbar to produce a fourth fraction ( 16 ) comprising fatty acids, resin acids and light neutral substances, and a residue fraction ( 15 ); or alternatively
(b2) evaporating said second fraction ( 12 ) in a second evaporator ( 110 ) at a temperature between 300 and 340° C. and a pressure between 3 and 10 mbar to obtain a third fraction ( 13 ) comprising fatty acids, resin acids and neutral substances and a residue fraction ( 15 );
whereafter the method further comprises
(c) distilling said first fraction ( 11 ) in a first distilling column ( 200 ) to obtain at least a crude fatty acid fraction ( 20 );
(d) distilling said third ( 13 ) and said fourth fraction ( 16 ) of step (b1) or said third fraction ( 13 ) of step (b2) in a second distilling column ( 300 ) to obtain at least a crude fatty acid fraction ( 30 ); and
(e) recovering a combined crude fatty acid fraction ( 40 ) from said first distilling column ( 200 ) and said second distilling column ( 300 ).

2. The method according to claim 1 , characterized in that the feed to the first fraction ( 11 ), is 6-25 wt % of the tall oil material used as feedstock.

3. The method according to claim 1 , characterized in that the method further comprises recovering a crude sulphate turpentine fraction and a water fraction ( 21 , 22 ) from said first distilling column ( 200 ).

4. The method according to claim 1 , characterized in that the total amount of restricted metals, including Ca, Fe, K, Mg, Na, As, of the combined crude fatty acid fraction is below 20 ppm.

5. The method according to claim 1 , characterized in that the method further comprises obtaining a tall oil rosin fraction ( 32 ) and/or tall oil pitch rosin fraction ( 31 ) from said second distilling column ( 300 ).

6. The method according to claim 5 , characterized in that the method further comprises obtaining rosin soap from said tall oil rosin fraction and/or from said tall oil pitch rosin fraction.

7. The method according to claim 1 , characterized in that the size of the second ( 110 ) and third evaporator ( 120 ) is adjusted.

8. The method according to claim 1 , characterized in that the tall oil material ( 10 ) is crude tall oil or a mixture of different crude tall oils.

9. The method according to claim 1 , characterized in that evaporating tall oil material ( 10 ) in said first evaporator ( 100 ) is done at a temperature between 260 and 290° C. and/or at a pressure selected from between 80 and 220 mbar.

10. The method according to claim 1 , characterized in that evaporating said second fraction ( 12 ) in a second evaporator ( 110 ) in step (b1) is done at a temperature between 235 and 265° C. and a pressure selected from between 5 and 20 mbar.

11. The method according to claim 1 , characterized in that evaporating the concentrate fraction ( 14 ) of the second evaporator ( 110 ) in a third evaporator ( 120 ) in step (b1) is done at a temperature between 285 and 315° C. and a pressure selected from between 3 and 15 mbar.

12. The method according to claim 1 , characterized in that evaporating said second fraction ( 12 ) in a second evaporator ( 110 ) in step (b2) is done at a temperature between 310 and 330° C. and at a pressure selected from between 3 and 10 mbar.

13. The method according to claim 1 , characterized in that distilling the first fraction ( 11 ) in the first distilling column ( 200 ) is done at a temperature between 130° C. and 170° C. and a pressure selected from between 30 to 70 mbar.

14. The method according to claim 1 , characterized in that distilling the third fraction ( 13 ) and optional fourth fraction ( 16 ) of the second evaporator ( 110 ) and optional third evaporator ( 120 ) in the second distilling column ( 300 ) is done at a temperature between 260° C. and 300° C. and a pressure selected from between 3 to 8 mbar.

15. The method according to claim 1 , characterized in that the process further comprises converting said recovered combined crude fatty acid fraction ( 40 ) by hydroprocessing to biofuels or components thereof.

16. The method according to claim 1 , wherein the recovered combined crude fatty acid fraction ( 40 ) is a feed for hydroprocessing.

17. The method according to claim 1 , characterized in that the feed to the first fraction ( 11 ), is 6-20 wt % of the tall oil material used as feedstock.

18. The method according to claim 1 , characterized in that the feed to the first fraction ( 11 ), is 8-15 wt % of the tall oil material used as feedstock.

19. The method according to claim 1 , characterized in that the tall oil material ( 10 ) is crude tall oil or a mixture of different crude tall oils, wherein the tall oil material comprises above 50 ppm impurities.

20. The method according to claim 1 , characterized in that the tall oil material ( 10 ) is crude tall oil or a mixture of different crude tall oils, wherein the tall oil material comprises 50-700 ppm impurities.

21. The method according to claim 1 , characterized in that the tall oil material ( 10 ) is crude tall oil or a mixture of different crude tall oils, wherein the tall oil material comprises 100-500 ppm impurities.

22. The method according to claim 1 , characterized in that the tall oil material ( 10 ) is crude tall oil or a mixture of different crude tall oils, wherein the tall oil material comprises 250-400 ppm impurities.

Assignees

• Upm Kymmene Corp

Inventors

• Kotoneva Jari
• Äijälä Timo

Classifications

• C11B3/12 Primary

  by distillation · CPC title

• C10G3/50

  in the presence of hydrogen, hydrogen donors or hydrogen generating compounds · CPC title

• C10G2400/02

  Gasoline · CPC title

• C10G2400/04

  Diesel oil · CPC title

• C10G2400/08

  Jet fuel · CPC title