Process for producing biofuel and biofuel components

Patent metadata

Field	Value
Publication number	US-10240095-B2
Application number	US-201314395163-A
Country	US
Kind code	B2
Filing date	Apr 17, 2013
Priority date	Apr 18, 2012
Publication date	Mar 26, 2019
Grant date	Mar 26, 2019

Abstract

A process for catalytically converting crude tall oil into hydrocarbons suitable as biofuel components. The crude tall oil is treated in a reactor system including a catalytically active guard bed phase and a catalytically active main reaction phase. At least one of the phases includes a catalyst bed with a combination of hydrodeoxygenating (HDO) and hydrodewaxing (HDW) catalysts. The process provides biofuel with acceptable ignition and cold flow properties.

First claim

The invention claimed is:

1. A process for producing biofuel or biofuel components, comprising:
a first step of feeding of biological material comprising tall oil, crude tall oil, tall oil fatty acids, tall oil derivative(s) or mixtures thereof into a reactor system, which comprises a) a catalytically active guard bed phase and b) a catalytically active main reaction phase and wherein the catalytically active guard bed phase comprises at least one catalyst bed comprising catalytically active material for removing of metals, sulphur and phosphorus, and said catalytically active material is selected from the group consisting of Ni, Co, Mo, W, zeolites, Al 2 O 3 , SiO 2 and mixtures thereof; and
the catalytically active main reaction phase comprises at least one catalyst bed comprising a combination of hydrodeoxygenating (HDO) and hydrodewaxing (HDW) catalysts, wherein the proportion of HDW catalyst content, based on total content of HDW and HDO catalysts, grows towards the outlet end of the reactor system, the HDO catalyst is selected from the group consisting of NiMo, CoMo and a mixture of Ni, Mo and Co, and the HDW catalyst is a NiW catalyst, and wherein the catalytic activity of the guard bed catalysts is lower than that of the main phase catalysts;
a second step of treating the feed material catalytically with hydrogen in the reactor system to cause hydrodeoxygenation, isomerization and cracking of feed material components to provide a hydroprocessing product, and
a third step of recovering at least a fraction of the hydroprocessing product as biofuel or biofuel components.

2. The process according to claim 1 , wherein the combination of HDO and HDW catalysts comprises mixture(s) or layers of the catalysts.

3. The process of claim 2 , wherein said mixture(s) is/are provided by physically mixing HDO and HDW catalyst particles or by adding HDO and HDW catalyst metals onto the same support material.

4. The process of claim 1 , which comprises the step of purifying a feed comprising crude tall oil by two or more evaporative purification steps prior to feeding into said reactor system.

5. The process of claim 1 , wherein the HDO catalyst is selected from the group consisting of NiMo, CoMo and a mixture of Ni, Mo and Co on a support selected from Al 2 O 3 , SiO 2 and ZrO 2 , and the HDW catalyst is selected from NiW/Al 2 O 3 and NiW/zeolite/Al 2 O 3 .

6. The process of claim 1 , wherein the HDO catalyst comprises NiMo/Al 2 O 3 and the HDW catalyst comprises NiW/zeolite/Al 2 O 3 .

7. The process of claim 1 , wherein the main reaction phase comprises two or more main catalyst beds with their respective combinations of HDO and HDW catalysts.

8. The process of claim 1 , wherein the main reaction phase comprises two or more main catalyst beds, which operate in series.

9. The process of claim 1 , wherein the reactor system comprises two or more guard catalyst beds, wherein HDW catalyst is combined with HDO catalyst in at least one of the guard catalyst beds.

10. The process of claim 1 , wherein the feed after the guard bed phase passes through the main catalyst beds of the reactor system in series as a continuous flow without outlets for byproducts or other side streams.

11. The process of claim 1 , wherein water is separated from the hydroprocessing product by cooling.

12. The process of claim 1 , wherein hydrogen sulfide and carbon dioxide are separated from the gaseous hydroprocessing products by amine scrubbing.

13. The process of claim 1 , wherein a diesel fraction and a naphtha fraction are recovered and a heavy fraction is recirculated to the inlet end of the guard bed phase or the main reaction phase.

Assignees

• Upm Kymmene Corp

Inventors

• Nousiainen Jaakko
• Rissanen Arto
• Gutierrez Andrea
• Lindberg Teemu
• Laumola Heli
• Knuuttila Pekka

Classifications

• C10L1/04

  essentially based on blends of hydrocarbons · CPC title

• Y02E50/13

  Cross-Sectional Technologies · mapped topic

• C10G45/58

  to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins (C10G32/00 takes precedence; improving or increasing the octane number or aromatic content of naphtha C10G35/00) · CPC title

• C10G45/64

  containing crystalline alumino-silicates, e.g. molecular sieves · CPC title

• C10L1/1616

  fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine · CPC title