Polyaniline compositions, articles thereof, and methods thereof

Patent metadata

Field	Value
Publication number	US-11987669-B2
Application number	US-202117407850-A
Country	US
Kind code	B2
Filing date	Aug 20, 2021
Priority date	Oct 8, 2020
Publication date	May 21, 2024
Grant date	May 21, 2024

Abstract

The present disclosure provides compositions, articles thereof, and methods of forming compositions. In at least one aspect, a composition includes (1) an epoxy, (2) an amino or amido hardener, (3) a polyaniline, (4) a dopant selected from a triazolyl, a thiazolyl, a quinolinyl, a salicylate, a benzoate, a glycolate, a phosphate, a sulfonate, an oxalate, or combination(s) thereof; and (5) a pigment selected from titanium dioxide, silica, talc, mica, aluminium stearate, or combination(s) thereof. The polyaniline+dopant comprises greater than 6 wt %, by weight of the composition. In at least one aspect, a method includes introducing an acid form of a polyaniline to a hydroxide to form a polyaniline hydroxide. The method includes introducing a dopant to the polyaniline hydroxide to form a doped polyaniline.

First claim

What is claimed is:

1. A composition comprising:
an epoxy,
an amino or amido hardener,
a doped polyaniline,
wherein a dopant of the doped polyaniline is selected from a benzoate, a glycolate, or combination(s) thereof; and
a pigment comprising titanium dioxide, silica, talc, mica, and aluminium stearate, wherein the polyaniline+dopant comprises greater than 6 wt % of the composition, by weight of the composition.

2. The composition of claim 1 , wherein the polyaniline is an emeraldine form of the polyaniline.

3. The composition of claim 1 , wherein the composition has a volatile organic content 300 g/L or less.

4. The composition of claim 1 , wherein the composition has a volume solids of about 70% or greater, based on the total volume of the composition, as determined by weighing out the ingredients, preparing the composition, and evaporating the solvents.

5. The composition of claim 1 , wherein the composition comprises epoxy+amino hardener and/or amido hardener in an amount of about 40 wt % to about 75 wt %, based on the total weight of the composition.

6. The composition of claim 1 , wherein the composition comprises one or more epoxies in an amount of about 30 wt % to about 50 wt %, based on the total weight of the composition.

7. The composition of claim 1 , wherein the composition comprises amino hardener in an amount of about 12 wt % to about 22 wt %, based on the total weight of the composition.

8. The composition of claim 1 , wherein the composition comprises amido hardener in an amount of about 12 wt % to about 22 wt %, based on the total weight of the composition.

9. The composition of claim 1 , wherein the epoxy is a bisphenol-A epoxy or bisphenol-F epoxy.

10. The composition of claim 1 , wherein the composition comprises polyaniline+dopant in an amount of about 10 wt % to about 60 wt %, based on the total weight of the composition.

11. The composition of claim 1 , wherein a molar ratio of dopant to aniline units of a polyaniline is about 0.3:1 to about 1:1.

12. The composition of claim 1 , wherein the dopant is a benzoate derived from benzoic acid, methylbenzoic acids, salt(s) thereof, or combination(s) thereof.

13. The composition of claim 1 , wherein the dopant is a glycolate selected from glycolate or thioglycolate, salt(s) thereof, or combination(s) thereof.

14. The composition of claim 1 , wherein the titanium dioxide is in an amount of about 0.01 wt % to about 10 wt %, based on the total weight of the composition.

15. The composition of claim 1 , wherein the talc is in an amount of about 0.01 wt % to about 10 wt %, based on the total weight of the composition.

16. The composition of claim 1 , wherein the mica is in an amount of about 0.01 wt % to about 10 wt %, based on the total weight of the composition.

17. The composition of claim 1 , wherein the silica is in an amount of about 0.01 wt % to about 10 wt %, based on the total weight of the composition.

18. The composition of claim 1 , wherein the aluminium stearate is in an amount of about 0.01 wt % to about 0.5 wt %, based on the total weight of the composition.

19. A substrate comprising the composition of claim 1 disposed thereon.

20. The substrate of claim 19 , wherein the composition thereon has a thickness of about 5 μm to about 100 μm.

21. The substrate of claim 20 , wherein the composition has a resistance of about 10 4 Ω/□ to about 10 8 Ω/□.

22. The substrate of claim 19 , wherein the substrate is a vehicle component selected from an airfoil, an auxiliary power unit, a nose of an aircraft, a fuel tank, a tail cone, a panel, a coated lap joint between two or more panels, a wing-to-fuselage assembly, a structural aircraft composite, a fuselage body-joint, or a wing rib-to-skin joint.

23. The substrate of claim 19 , wherein the substrate comprises a metal substrate made of aluminum, aluminum alloy, nickel, iron, iron alloy, steel, titanium, titanium alloy, copper, copper alloy, or combination(s) thereof.

24. The substrate of claim 19 , wherein the substrate comprises aluminum, carbon fiber epoxy, fiberglass reinforced polymer, cellulose reinforced phenolic resin, polyimide, glass, poly ether ether ketone, poly ether ketone, polystyrene, polypropylene, polytetrafluoroethylene, or combination(s) thereof.

25. The composition of claim 1 , wherein the pigment is in an amount of about 0.01 wt % to about 40 wt %, based on the total weight of the composition.

26. The composition of claim 1 , wherein the pigment is in an amount of about 0.01 wt % to about 10 wt %.

27. The substrate of claim 19 , wherein the composition disposed thereon has a thickness of about 1 μm to about 10 μm.

28. The substrate of claim 23 , wherein the substrate comprises a metal substrate made of aluminum, aluminum alloy, steel, titanium, titanium alloy, copper, copper alloy, or combination(s) thereof.

29. The substrate of claim 28 , wherein the substrate comprises a metal substrate made of aluminum, aluminum alloy, or steel.

30. A fiber comprising the composition of claim 1 applied thereon, wherein the fiber is selected from graphite, fiberglass, nylon, or combination(s) thereof.

Assignees

• Boeing Co

Inventors

• Ijeri Vijaykumar
• Gaydos Stephen P
• Kinlen Patrick J

Classifications

• C08G73/0266 Primary

  Polyanilines or derivatives thereof · CPC title

• C08G59/245

  aromatic · CPC title

• C08G59/44

  Amides · CPC title

• C08G59/50

  Amines · CPC title

• C08K3/22

  of metals · CPC title