Wash liquids for use in additive manufacturing with dual cure resins
US-10343331-B2 · Jul 9, 2019 · US
US11987003B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11987003-B2 |
| Application number | US-202217929357-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 2, 2022 |
| Priority date | Dec 14, 2016 |
| Publication date | May 21, 2024 |
| Grant date | May 21, 2024 |
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A method of making a three-dimensional object, including the steps of: (a) providing a carrier platform; (b) producing the three-dimensional object adhered to the carrier platform; (c) immersing the object in a wash liquid with the object remaining adhered to the carrier platform; (d) agitating the object in the wash liquid and/or the wash liquid with the object immersed therein to at least partially remove residual resin from the object; (e) separating the object from the wash liquid, with the object remaining adhered to the carrier platform; (f) agitating the object at least partially remove residual wash liquid; and (g) repeating steps (c) through (f) at least once to remove additional polymerizable resin, steps (c) through (f) are carried out in the same vessel, the immersing step (c) includes filling the vessel with the wash liquid, and the separating step (e) includes draining the wash liquid from the vessel.
Opening claim text (preview).
We claim: 1. A method of making a three-dimensional object from a polymerizable resin, said method comprising the steps of: (a) providing a carrier platform on which said three-dimensional object can be formed; (b) producing said three-dimensional object adhered to said carrier platform from said polymerizable resin by stereolithography using an additive manufacturing apparatus, said object having residual resin on a surface thereof; (c) immersing said object in a wash liquid with said object remaining adhered to said carrier platform; (d) agitating (i) said object in said wash liquid, (ii) said wash liquid with said object immersed therein, or (iii) both said object in said wash liquid and said wash liquid with said object immersed therein, to at least partially remove said residual resin from the surface of said object; (e) separating said object from said wash liquid, with said object remaining adhered to said carrier platform, said object having residual wash liquid on the surface thereof; (f) agitating said object to at least partially remove said residual wash liquid from the surface thereof; and (g) repeating steps (c) through (f) at least once to remove additional polymerizable resin from the surface thereof, wherein steps (c) through (f) are carried out in the same vessel, said immersing step (c) comprises filling said vessel with said wash liquid, and said separating step (e) comprises draining said wash liquid from said vessel, wherein said filling and said draining are carried out using a common fill and drain line, wherein the method further comprises, after said producing step (b) and before said immersing step (c): removing said carrier platform with said object adhered thereto from said additive manufacturing apparatus and connecting said carrier platform with said object adhered thereto to an object agitator above said vessel; and then lowering said carrier platform with said object adhered thereto into said vessel, and wherein said object agitator is configured to spin said carrier platform with said object adhered thereto about a vertical axis for said agitating step (d) and said agitating step (f). 2. A method of making a three-dimensional object from a polymerizable resin, said method comprising the steps of: (a) providing a carrier platform on which said three-dimensional object can be formed; (b) producing said three-dimensional object adhered to said carrier platform from said polymerizable resin by stereolithography using an additive manufacturing apparatus, said object having residual resin on a surface thereof; and also generating wash cycle parameters and dry cycle parameters for said object, wherein at least one of said wash cycle parameters and at least one of said dry cycle parameters are generated based on (i) at least one characteristic of said object, (ii) a type of said polymerizable resin, (iii) an orientation of said object on said carrier platform, or (iv) a combination thereof; (c) immersing said object in said wash liquid with said object remaining adhered to said carrier platform; (d) agitating, according to said wash cycle parameters, (i) said object in said wash liquid, (ii) said wash liquid with said object immersed therein, or (iii) both said object in said wash liquid and said wash liquid with said object immersed therein, to at least partially remove said residual resin from the surface of said object; (e) separating said object from said wash liquid, with said object remaining adhered to said carrier platform, said object having residual wash liquid on the surface thereof; (f) agitating, according to said dry cycle parameters, said object to at least partially remove said residual wash liquid from the surface thereof; and (g) optionally repeating steps (c) through at least once to remove additional polymerizable resin from the surface thereof, wherein said agitating step (d) and said agitating step (f) both include spinning said carrier platform with said object remaining adhered thereto, wherein the method further comprises, after said producing step (b) and before said immersing step (c): removing said carrier platform with said object adhered thereto from said additive manufacturing apparatus and connecting said carrier platform with said object adhered thereto to an object agitator above a wash vessel; and then lowering said carrier platform with said object adhered thereto into said wash vessel, and wherein said object agitator is configured to spin said carrier platform with said object adhered thereto about a vertical axis for said agitating step (d) and said agitating step (f). 3. The method of claim 2 , wherein said optionally repeating step (g) is present. 4. The method of claim 2 , wherein said steps (c) through (f) are carried out in a total time of not more than 10 minutes. 5. The method of claim 2 , wherein said wash cycle parameters, and said dry cycle parameters, include duration of agitation, maximum speed of agitation, acceleration of agitation, deceleration of agitation, direction of agitation, and/or number of repeatings (g) (when present). 6. The method of claim 2 , wherein steps (c) through (f) are carried out in said wash vessel, said immersing step (c) comprises filling said wash vessel with said wash liquid, and said separating step (e) comprises draining said wash liquid from said wash vessel. 7. The method of claim 2 , wherein a maximum spinning speed of said agitating step (d) is slower than a maximum spinning speed of said agitating step (f). 8. The method of claim 2 , wherein said object and said carrier platform together have both a center of mass and an axis of rotation, and wherein said center of mass is either aligned with or offset from said axis of rotation. 9. The method of claim 2 , wherein said wash liquid comprises an organic solvent. 10. The method of claim 9 , wherein said organic solvent comprises an azeotropic mixture. 11. The method of claim 2 , wherein said carrier platform comprises a unique identifier, and said generating step is carried out with information associated with said unique identifier. 12. The method of claim 2 , further comprising the step of: (h) distilling said wash liquid to remove residual resin therefrom and produce a distilled wash liquid; and then (i) repeating steps (a) through (f), or steps (a) through (g) (when present) with said distilled wash liquid. 13. The method of claim 2 wherein said carrier platform with said object adhered thereto is positioned at a vertical level in said wash vessel that is the same vertical level in said agitating step (d) and said agitating step (f).
Cleaning · CPC title
Cleaning involving contact with liquid · CPC title
with means for agitating the liquid (by agitating the container B08B3/042, B08B3/044, B08B3/045, B08B3/06) · CPC title
by lowering and raising the level of the cleaning liquid · CPC title
by sonic or ultrasonic vibrations · CPC title
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