Metal-air battery and production method for air electrode

Patent metadata

Field	Value
Publication number	US-11978877-B2
Application number	US-201917312569-A
Country	US
Kind code	B2
Filing date	Dec 11, 2019
Priority date	Dec 25, 2018
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

A battery performance of a metal-air battery is improved while still maintaining a low environmental burden. A metal-air battery includes an air electrode formed from a co-continuous substance having a three-dimensional network structure in which a plurality of nanostructures are integrated by noncovalent bonds; an anode; and an electrolyte disposed between the air electrode and the anode, in which the electrolyte is a gel electrolyte obtained by gelling an aqueous solution containing an ion conductor with a gelling agent, and the gelling agent is constituted of at least one of a plant-derived polysaccharide, a seaweed-derived polysaccharide, a microbial polysaccharide, an animal-derived polysaccharide, and a group of acetic acid bacteria that produce the polysaccharides.

First claim

The invention claimed is:

1. A metal-air battery comprising:
an air electrode formed from a co-continuous substance having a three- dimensional network structure in which a plurality of nanostructures are integrated by noncovalent bonds;
an anode;
an electrolyte disposed between the air electrode and the anode, wherein the electrolyte is a gel electrolyte obtained by gelling an aqueous solution containing an ion conductor with a gelling agent, and the gelling agent is constituted of at least one of a plant-derived polysaccharide, a seaweed-derived polysaccharide, or an animal-derived polysaccharide;
a first housing disposed on a side of the anode;
a second housing disposed on a side of the air electrode, the second housing including an opening configured to allow the air electrode to come into contact with the surrounding air;
a first current collector provided between the first housing and the anode;
a second current collector provided between the second housing and the air electrode;
a first terminal connecting the first current collector to an outside of the first housing; and
a second terminal connecting the second current collector to an outside of the second housing.

2. The metal-air battery according to claim 1 , wherein the ion conductor is constituted of one or more of a chloride, an acetate, a carbonate, a citrate, a phosphate, 4-(2-hydroxyethyl)-1-piperazine ethanesulfonic acid (HEPES), a pyrophosphate, or a metaphosphate.

3. The metal-air battery according to claim 1 , wherein the plurality of nanostructures of the air electrode are a nanosheet constituted of at least one of carbon, iron oxide, manganese oxide, zinc oxide, molybdenum oxide, or molybdenum sulfide, or are nanofibers constituted of at least one of carbon, iron oxide, manganese oxide, zinc oxide, molybdenum oxide, molybdenum sulfide, or cellulose.

4. The metal-air battery according to claim 1 , wherein the anode is constituted of one or more of magnesium, aluminum, calcium, iron, or zinc.

5. The metal-air battery according to claim 1 , wherein the air electrode supports a catalyst constituted of at least one metal of iron, manganese, zinc, copper, or molybdenum, or an oxide of at least one metal of calcium, iron, manganese, zinc, copper, or molybdenum.

6. A method for manufacturing an air electrode of the metal-air battery according to claim 1 , the method comprising:
a freezing step of freezing a sol or gel in which the plurality of nanostructures are dispersed, to obtain a frozen substance; and
a drying step of drying the frozen substance in a vacuum, to obtain the co-continuous substance.

7. A method for manufacturing an air electrode of the metal-air battery according to claim 1 , the method comprising:
a gel production step of allowing bacteria to produce a gel in which nanofibers constituted of iron oxide or manganese oxide are dispersed;
a freezing step of freezing the gel; and
a drying step of drying the gel as a frozen substance.

8. A method for manufacturing an air electrode of the metal- air battery according to claim 1 , the method comprising:
a gel production step of allowing bacteria to produce a gel in which nanofibers constituted of cellulose are dispersed;
a freezing step of freezing the gel;
a drying step of drying the gel as a frozen substance; and
a carbonization step of heating the co-continuous substance which has been obtained by the drying in a gaseous atmosphere in which cellulose does not combust, to carbonize the co-continuous substance.

9. The metal-air battery according to claim 2 , wherein the plurality of nanostructures of the air electrode are a nanosheet constituted of at least one of carbon, iron oxide, manganese oxide, zinc oxide, molybdenum oxide, or molybdenum sulfide, or are nanofibers constituted of at least one of carbon, iron oxide, manganese oxide, zinc oxide, molybdenum oxide, molybdenum sulfide, or cellulose.

10. The metal-air battery according to claim 2 , wherein the anode is constituted of one or more of magnesium, aluminum, calcium, iron, or zinc.

11. The metal-air battery according to claim 3 , wherein the anode is constituted of one or more of magnesium, aluminum, calcium, iron, or zinc.

12. The metal-air battery according to claim 2 , wherein the air electrode supports a catalyst constituted of at least one metal of iron, manganese, zinc, copper, or molybdenum, or an oxide of at least one metal of calcium, iron, manganese, zinc, copper, or molybdenum.

13. The metal-air battery according to claim 3 , wherein the air electrode supports a catalyst constituted of at least one metal of iron, manganese, zinc, copper, or molybdenum, or an oxide of at least one metal of calcium, iron, manganese, zinc, copper, or molybdenum.

14. The metal-air battery according to claim 4 , wherein the air electrode supports a catalyst constituted of at least one metal of iron, manganese, zinc, copper, or molybdenum, or an oxide of at least one metal of calcium, iron, manganese, zinc, copper, or molybdenum.

15. A method for manufacturing an air electrode of the metal- air battery according to claim 2 , the method comprising:
a freezing step of freezing a sol or gel in which the plurality of nanostructures are dispersed, to obtain a frozen substance; and
a drying step of drying the frozen substance in a vacuum, to obtain the co-continuous substance.

16. A method for manufacturing an air electrode of the metal- air battery according to claim 3 , the method comprising:
a freezing step of freezing a sol or gel in which the plurality of nanostructures are dispersed, to obtain a frozen substance; and
a drying step of drying the frozen substance in a vacuum, to obtain the co-continuous substance.

17. A method for manufacturing an air electrode of the metal-air battery according to claim 4 , the method comprising:
a freezing step of freezing a sol or gel in which the plurality of nanostructures are dispersed, to obtain a frozen substance; and
a drying step of drying the frozen substance in a vacuum, to obtain the co-continuous substance.

18. A method for manufacturing an air electrode of the metal-air battery according to claim 5 , the method comprising:
a freezing step of freezing a sol or gel in which the plurality of nanostructures are dispersed, to obtain a frozen substance; and
a drying step of drying the frozen substance in a vacuum, to obtain the co-continuous substance.

19. A method for manufacturing an air electrode of the metal-air battery according to claim 2 , the method comprising:
a gel production step of allowing bacteria to produce a gel in which nanofibers constituted of cellulose are dispersed;
a freezing step of freezing the gel;
a drying step of drying the gel as a frozen substance; and
a carbonization step of heating the co-continuous substance which has been obtained by the drying in a gaseous atmosphere in which cellulose does not combust, to carbonize the co-continuous substance.

20. A method for manufacturing an air electrode of the metal- air battery according to claim 3 , the method comprising:
a gel production step of allowing bacteria to produce a gel in which nanofibers constituted of cellulose are dispersed;
a freezing step of freezing the gel;
a drying step of drying the gel as a frozen substance; and
a carbonization step of heating the co-continuous substance which has been obtained by the drying in a gaseous atmosphere in which cellulose does not combust, to carbonize the co-continuous substance.

Assignees

• Nippon Telegraph & Telephone

Inventors

• Iwata Mikayo
• Nohara Masaya
• Minowa Hironobu
• Sakamoto Shuhei
• Komatsu Takeshi

Classifications

• H01M12/06 Primary

  with one metallic and one gaseous electrode · CPC title

• H01M4/9025

  Oxides specially used in fuel cell operating at high temperature, e.g. SOFC · CPC title

• H01M4/9041

  Metals or alloys (H01M4/92 takes precedence) · CPC title

• H01M4/8882

  Heat treatment, e.g. drying, baking · CPC title

• H01M2300/0085

  Immobilising or gelification of electrolyte · CPC title