Layered-double-hydroxide-oriented film and method for producing same
US-2015340680-A1 · Nov 26, 2015 · US
US2019348730A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2019348730-A1 |
| Application number | US-201816347624-A |
| Country | US |
| Kind code | A1 |
| Filing date | Mar 12, 2018 |
| Priority date | Sep 28, 2017 |
| Publication date | Nov 14, 2019 |
| Grant date | — |
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One aspect of the sheet-like air cell of the present invention includes a positive electrode having a catalyst layer, a negative electrode, a separator, and an electrolyte solution that are housed in a sheet-like outer case. The electrolyte solution is an aqueous solution that contains an electrolyte salt and has a pH of 3 or more and less than 12. The electrolyte solution contains a water-soluble high-boiling solvent with a boiling point of 150° C. or more in an amount of 3 to 30% by mass of the total solvent. Another aspect of the sheet-like air cell of the present invention includes a positive electrode having a catalyst layer, a negative electrode, a separator, and an electrolyte that are housed in a sheet-like outer case. The electrolyte is obtained by blending an electrolyte solution and a thickening agent. The electrolyte solution is an aqueous solution that contains an electrolyte salt and has a pH of 3 or more and less than 12.
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1 .- 3 . (canceled) 4 . A sheet-type air cell comprising: a positive electrode having a catalyst layer, a negative electrode, a separator, and an electrolyte that are contained in a sheet-type outer case, wherein the electrolyte is obtained by blending an electrolyte solution and a thickening agent, and the electrolyte solution is an aqueous solution that contains an electrolyte salt and has a pH of 3 or more and less than 12. 5 . The sheet-type air cell according to claim 4 , wherein the thickening agent has a functional group in a molecule, the functional group including a carboxyl group or its salt. 6 .- 7 . (canceled) 8 . The sheet-type air cell according to claim 4 , wherein the thickening agent is polysaccharide or polyalkylene glycol having a molecular weight of 1000 or more. 9 . The sheet-type air cell according to claim 8 , wherein the thickening agent is a cellulose derivative. 10 . The sheet-type air cell according to claim 9 , wherein the cellulose derivative is carboxymethyl cellulose with a degree of etherification of 0.9 or more. 11 . The sheet-type air cell according to claim 4 , wherein the electrolyte further contains a water-soluble high-boiling solvent that has a boiling point of 150° C. or more. 12 . The sheet-type air cell according to claim 4 , having a thickness of 1 mm or less. 13 . (canceled) 14 . A patch being wearable and comprising the sheet-type air cell according to claim 4 as a power supply. 15 . The sheet-type air cell according to claim 4 , wherein the negative electrode is formed of a metal sheet with a thickness of 10 to 500 μm. 16 . The sheet-type air cell according to claim 15 , wherein the metal sheet is zinc foil or zinc alloy foil. 17 . The sheet-type air cell according to claim 16 , wherein the metal sheet is zinc alloy foil containing bismuth. 18 . The sheet-type air cell according to claim 15 , wherein the metal sheet has a portion serving as an active material and a lead portion. 19 . The sheet-type air cell according to claim 4 , wherein a concentration of the electrolyte salt in the electrolyte solution is 5 to 50% by mass. 20 . The sheet-type air cell according to claim 4 , wherein the electrolyte solution contains a salt of a strong acid and a weak base as the electrolyte salt. 21 . The sheet-type air cell according to claim 4 , wherein the electrolyte solution contains an ammonium salt as the electrolyte salt. 22 . The sheet-type air cell according to claim 11 , wherein the electrolyte contains polyhydric alcohol or polyalkylene glycol having a molecular weight of 600 or less as the water-soluble high-boiling solvent. 23 . The sheet-type air cell according to claim 11 , wherein the water-soluble high-boiling solvent has a surface tension of 30 mN/m or more and a relative dielectric constant of 30 or more. 24 . The sheet-type air cell according to claim 4 , wherein the aqueous solution has a pH of less than 7.
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