Thermally stable cellulose ester compositions and articles made using these compositions

Patent metadata

Field	Value
Publication number	US-11976138-B2
Application number	US-201716346910-A
Country	US
Kind code	B2
Filing date	Nov 9, 2017
Priority date	Nov 11, 2016
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

The present application discloses cellulose ester compositions that are plasticizer free that can be processed at higher temperatures with reduced degradation. The cellulose ester compositions disclosed are useful for the preparation of articles, for example eyeglass frames, automotive parts, and toys.

First claim

What is claimed is:

1. A composition comprising a cellulose ester; a secondary antioxidant in the range of from 0.1 to 0.8 wt %; an acid scavenger in the range of from 0.2 to 1.0 wt %; and a salt stabilizer in the range of from 0.01 to 0.1 wt %;
wherein the cellulose ester is a cellulose acetate propionate,
wherein the composition is plasticizer free,
wherein the secondary antioxidant is an orpanophosphorous or orpanosulfur compound,
wherein the acid scavenger is an epoxidized fatty acid ester,
wherein the salt stabilizer is a compound wherein the cation component is aluminum, calcium, magnesium, copper, cerium, antimony, nickel, cobalt, manganese, barium, strontium, zinc, zirconium, tin, cadmium, chromium or iron, and the anion component is a (C 6-20 )alicyclic carboxylic acid, a (C 2-20 )alkyl carboxylic acid, or a (C 6-20 )alkenyl carboxylic acid, wherein the (C 6-20 )alicyclic carboxylic acid, the (C 2-20 )alkyl carboxylic acid, or the (C 6-20 )alkenyl carboxylic acid is naphthenic acid, abietic acid, cyclohexane carboxylic acid, cyclohexane propionic acid, 3-methyl-cyclopentyl acetic acid, 4-methylcyclohexane carboxylic acid, 2,2,6-trimethylcyclohexane carboxylic acid, 2,3-dimethylcyclopentyl acetic acid, 2-methylcyclopentyl propionic acid, palmitic acid, stearic acid, oleic acid, or lauric acid,
wherein the weight percentages of the cellulose ester, the secondary antioxidant, the acid scavenger, and the salt stabilizer are based on the total weight of the composition,
wherein the composition has a heat distortion temperature (“HDT”) that is in the range of from 95° C. to 140° C. according to ASTM D648 as measured at 1.82 MPa using a 3.2 mm thick bar subjected to 70° C. for 4 hours,
wherein the change in the absolute weight average molecular weight (“M w ”) of the cellulose ester due to injection molding is less than 30% when the composition is injection molded with a barrel temperature of 260° C. with a residence time of 5 min,
wherein the b* value is less than 15 as measured according to ASTM E1348 using a 3.2 mm plaque made from the composition which has been injection molded with a barrel temperature of 249° C. with a residence time of 5 min.

2. The composition of claim 1 , wherein the secondary antioxidant is 3,9-bis(2,4-di-tert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane.

3. The composition of claim 1 , wherein the composition further comprises an impact modifier in the range of from 0.1 to 15 wt % based on the total weight of the composition.

4. The composition of claim 1 , the ΔE value is less than 25 wherein ΔE is determined by the following equation:
((L*−100) 2 +(a*−0) 2 +(b*−0) 2 ) 1/2

and the L*, a*, b* values are determined according to ASTM E1348 using a 3.2 mm plaque made from the composition which has been injection molded with a barrel temperature of 249° C. with a residence time of 5 min.

5. The composition of claim 1 , wherein the composition has a notched Izod impact strength of greater than 40 J/m as measured according to ASTM D256 using a 3.2 mm thick bar that has been subjected to 50% relative humidity for 48 hours at 23° C.

6. The composition of claim 1 , wherein the composition has a flexural modulus of greater than 1800 MPa as measured according to ASTM D790 using a 3.2 mm thick bar that has been subjected to 50% relative humidity for 48 hours at 23° C.

7. The composition of claim 1 , wherein the cellulose ester has an absolute weight average molecular weight in the range of from 40,000 Da to 200,000 Da measured according to ASTM D5296 using tetrahydrofuran as a solvent and a flow rate of 1 mL/min.

8. The composition of claim 1 , wherein the spiral flow length is from 3.0 cm to 10.0 cm, when the composition is molded with a spiral flow mold with the conditions of a barrel temperature of 238° C., a melt temperature of 246° C., a molding pressure of 13.8 MPa, a mold thickness of 0.8 mm, and a mold width of 12.7 mm.

9. A molded article comprising the composition of claim 1 .

Assignees

• Eastman Chem Co

Inventors

• Pecorini Thomas Joseph
• Donelson Michael Eugene
• Stack Gary Michael
• Sharpe Jr Emerson Eston
• Feng Wenlai
• An Haining

Classifications

• B29C2945/76668

  barrel · CPC title

• B29C2945/76561

  duration · CPC title

• B29C2945/76531

  Temperature · CPC title

• B29C2945/76498

  Pressure · CPC title

• B29C45/78

  of temperature · CPC title