Cellulose ester and impact modifier compositions and articles made using these compositions

Patent metadata

Field	Value
Publication number	US-11230635-B2
Application number	US-201716348573-A
Country	US
Kind code	B2
Filing date	Nov 9, 2017
Priority date	Nov 11, 2016
Publication date	Jan 25, 2022
Grant date	Jan 25, 2022

Abstract

A cellulose ester composition is provided comprising at least one cellulose ester and at least one impact modifier and optionally at least one plasticizer. Processes for producing the cellulose ester compositions as well as articles made using these compositions, such as eyeglass frames, automotive parts, and toys are also provided.

First claim

That which is claimed is:

1. A cellulose ester composition comprising 67 to 99 wt % of at least one cellulose ester, 1 to 30 wt % of at least one impact modifier, and 0 to 3 wt % of at least one plasticizer, based on the total weight of the composition, wherein said cellulose ester is chosen from one or more of cellulose propionate (CP), cellulose butyrate (CB), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB), cellulose propionate butyrate (CPB), cellulose tripropionate (CTP), or cellulose tributyrate (CTB); wherein said impact modifier is an acrylic core-shell impact modifier; and wherein said composition has an HDT value greater than 95° C., and a notched Izod impact strength value greater than 80 J/m measured according to ASTM D256 on 3.2 mm thick bars at 23° C., after conditioning the bars at 230° C. and 50% RH for 48 hours.

2. The cellulose ester composition of claim 1 , wherein said composition comprises 1-15 wt % of said impact modifier.

3. The cellulose ester composition of claim 1 , wherein said composition comprises 70-99 wt % of said cellulose ester, 1-30 wt % of said impact modifier, and no plasticizer.

4. The cellulose ester composition of claim 3 , wherein said composition comprises 85-99 wt % of said cellulose ester, 1-15 wt % of said impact modifier, and no plasticizer.

5. The cellulose ester composition according to claim 1 , wherein said cellulose ester is chosen from cellulose acetate propionate (CAP) or cellulose acetate butyrate (CAB), and wherein the composition comprises 0 to less than 2 wt % plasticizer.

6. The cellulose ester composition of claim 5 , wherein said CAP or CAB have an absolute weight average molecular weight of 15000-300000.

7. The cellulose ester composition of claim 5 , wherein said CAP or CAB have an absolute weight average molecular weight of 70000-120000.

8. The cellulose ester composition according to claim 5 , wherein said cellulose ester is CAP and the composition comprises 0 to 1 wt % plasticizer.

9. The cellulose ester composition according to claim 1 , wherein said composition comprises plasticizer selected from the group consisting of a phosphate plasticizer, a benzoate plasticizer, an adipate plasticizer, a phthalate plasticizer, a glycolic acid ester plasticizer, a carbonate plasticizer, a citric acid ester plasticizer and a hydroxyl-functional plasticizer or a solid, non-crystalline resin plasticizer, or a combination thereof.

10. The cellulose ester composition according to claim 1 , wherein the cellulose ester composition includes a stabilizer selected from the group consisting of secondary antioxidants, acid scavengers, or a combination thereof.

11. The cellulose ester composition according to claim 10 , wherein the cellulose ester composition contains a total of less than 5 wt % of any other components other than the cellulose ester, impact modifier and stabilizers, based on the total weight of the composition.

12. The cellulose ester composition according to claim 1 , wherein said impact modifier has a refractive index of 1.46-1.50.

13. The cellulose ester composition according to claim 1 , wherein said impact modifier has particle size of 0.01-2.0 um.

14. The cellulose ester composition according to claim 1 , wherein said composition further comprises at least one additive selected from the group consisting of antioxidants, thermal stabilizers, mold release agents, antistatic agents, whitening agents, colorants, plasticizers, minerals, UV stabilizers, lubricants, nucleating agents, reinforcing fillers, glass fiber, carbon fiber, flame retardants, dyes, pigments, colorants, additional resins and combinations thereof.

15. An article of manufacture comprising the cellulose ester composition according to claim 1 , wherein the composition has a notched Izod impact strength of at least 150 J/m.

16. The article according to claim 15 , wherein the article of manufacture is formed by injection molding.

17. A film or sheet comprising a cellulose ester composition according to claim 1 .

18. A thermoplastic and melt processable cellulose ester composition comprising:
70-99 wt % of a cellulose ester comprising one or more of cellulose acetate propionate (CAP), and cellulose acetate butyrate (CAB);
0—less than 2 wt % of a plasticizer; and
1-15 wt % of an acrylic core-shell impact modifier; wherein said impact modifier has particle size of 0.01-2.0 um, and wherein said composition has an HDT value greater than 95° C., a notched Izod impact strength value greater than 80 J/m measured according to ASTM D256 on 3.2 mm thick bars at 23° C., and a viscosity of 10,000 P or below at 400 rad/s and 240° C.

19. The cellulose ester composition according to claim 18 , wherein the composition comprises 0 to 1 wt % plasticizer.

20. The cellulose ester composition according to claim 18 , wherein the composition includes a stabilizer selected from the group consisting of secondary antioxidants, acid scavengers, or a combination thereof.

Assignees

• Eastman Chem Co

Inventors

• Feng Wenlai
• Pecorini Thomas Joseph
• Donelson Michael Eugene
• An Haining

Classifications

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08J2301/14

  Mixed esters · CPC title

• C08K5/0016

  Plasticisers · CPC title

• C08L1/14 Primary

  Mixed esters, e.g. cellulose acetate-butyrate · CPC title

• C08L1/10 Primary

  Esters of organic acids {, i.e. acylates} · CPC title