Foundry coke products and associated processing methods via cupolas

Patent metadata

Field	Value
Publication number	US-11946108-B2
Application number	US-202218052739-A
Country	US
Kind code	B2
Filing date	Nov 4, 2022
Priority date	Nov 4, 2021
Publication date	Apr 2, 2024
Grant date	Apr 2, 2024

Abstract

Foundry coke products, and associated methods and systems for melting iron in a cupola furnace with the coke products are disclosed herein. A representative method can include receiving a population of coke products and iron in a cupola furnace, and melting the iron in the cupola furnace to form molten iron having a carbon content higher than a carbon content of the received iron. The coke products can comprise (i) an elongate shape including a length:width dimension of at least 1.5:1, (ii) an ash fusion temperature of no more than 2400° F., and/or (iii) a coke reactivity index (CRI) of at least 30%.

First claim

We claim:

1. A method for melting iron in a cupola furnace, the method comprising:
receiving a population of coke products and iron in a cupola furnace, wherein the coke products comprise (i) an elongate shape including a length:width dimension of at least 1.5:1, (ii) an ash fusion temperature of no more than 2450° F., and/or (iii) a coke reactivity index (CRI) of at least 30%; and
melting the iron in the cupola furnace to form molten iron having a carbon content higher than a carbon content of the received iron.

2. The method of claim 1 , wherein the coke products comprise a fixed carbon content, and wherein at least 40 wt % of the fixed carbon content is transferred to the molten iron in the cupola.

3. The method of claim 1 , wherein the coke products comprise a fixed carbon content, the method further comprising oxidizing the coke products in a lower reactivity region of the cupola to produce carbon monoxide, wherein no more than 40 wt % of the fixed carbon content is released via the produced carbon monoxide.

4. The method of claim 1 , wherein the coke products comprise a fixed carbon content of at least 85 wt %, the method further comprising oxidizing the coke products in a lower reactivity region of the cupola to produce carbon monoxide, wherein no more than 50 lbs/hour of the produced carbon monoxide is released from an upper area of the cupola.

5. The method of claim 1 , wherein melting the iron comprises melting the iron at a melting rate of at least 22 tons/hour and such that a metal tap temperature of the molten iron is at least 2680° F.

6. The method of claim 1 , wherein the cupola comprises an upper drying region, and a lower reaction region downstream of the upper drying region, and wherein the coke products comprise a composition configured to inhibit Boudouard reactions of the coke products within the upper drying region and/or promote oxidation reactions of the coke products within the lower reactivity region.

7. The method of claim 1 , wherein the cupola comprises an upper drying region, and a lower reaction region downstream of the upper drying region, and wherein the method further comprises (i) drying the coke products in the upper drying region, (ii) oxidizing the coke products in the lower reactivity region to produce carbon monoxide, and (iii) combusting the coke products in the lower reactivity region to produce carbon dioxide.

8. The method of claim 7 , wherein drying the coke products comprises shrinking a core of individual coke products and forming a diffusion layer comprising ash or iron, wherein the diffusion layer is radially outward of the core and, in operation, inhibits Boudouard reactions within the cupola at the upper drying region.

9. The method of claim 7 , wherein oxidizing the coke products comprises shrinking a core of individual coke products and forming (i) a first diffusion layer comprising ash that is radially outward of the core and (ii) a second diffusion layer comprising iron that is radially outward of the core and/or first diffusion layer, wherein, in operation, the first diffusion layer and/or the second diffusion layer inhibits Boudouard reactions within the cupola at the upper drying region.

10. The method of claim 1 , wherein the ash fusion temperature is no more than 2200° F.

11. The method of claim 1 , wherein the CRI of the coke products is between 35-45%.

12. The method of claim 1 , wherein the length:width ratio of at least some of the individual coke products is at least 2:1.

13. The method of claim 1 , wherein at least some of the individual coke products have a length of at least 8 inches and a width of at least 4 inches.

14. The method of claim 1 , wherein the coke products have an ash content of 6.0-12.0 wt %.

15. The method of claim 1 , wherein the coke products have a fixed carbon content of at least 90.0 wt %.

16. The method of claim 1 , wherein the coke products have a sulfur content of no more than 0.7 wt %.

17. The method of claim 1 , wherein the coke products have a 2-inch drop shatter of at least 90% and/or a 4-inch drop shatter of at least 78%.

18. A method for melting iron in a cupola furnace, the method comprising:
receiving a population of coke products and iron in a cupola furnace, wherein the coke products comprise at least two or more of (i) an elongate shape including a length:width dimension of at least 1.5:1, (ii) an ash fusion temperature of no more than 2450° F., or (iii) a coke reactivity index (CRI) of at least 30%; and
melting the iron in the cupola furnace to form molten iron having a carbon content higher than a carbon content of the received iron.

19. A method for melting iron in a cupola furnace, the method comprising:
receiving a population of coke products and iron in a cupola furnace, wherein the coke products comprise (i) an elongate shape including a length:width dimension of at least 1.5:1, (ii) an ash fusion temperature of no more than 2450° F., and (iii) a coke reactivity index (CRI) of at least 30%; and
melting the iron in the cupola furnace to form molten iron having a carbon content higher than a carbon content of the received iron.

Assignees

• Suncoke Tech & Development Llc

Inventors

• Quanci John Francis
• RICHARDSON John Michael
• Perkins Jonathan Hale

Classifications

• C21B5/007 Primary

  Conditions of the cokes or characterised by the cokes used · CPC title

• C01B32/40 Primary

  Carbon monoxide · CPC title

• C21B11/02

  in low shaft furnaces {or shaft furnaces} · CPC title

• C21C1/08

  Manufacture of cast-iron · CPC title

• C21B13/0066

  Preliminary conditioning of the solid carbonaceous reductant · CPC title