Stable dispersant and application thereof in preparing copolymer polyols

Patent metadata

Field	Value
Publication number	US-11945775-B2
Application number	US-201817294102-A
Country	US
Kind code	B2
Filing date	Dec 26, 2018
Priority date	Dec 21, 2018
Publication date	Apr 2, 2024
Grant date	Apr 2, 2024

Abstract

A stable dispersant and an application thereof in preparing copolymer polyols, the preparation method for the stable dispersant including the steps of 1) contacting a polyol with a dianhydride compound for reaction so as to prepare an adduct; 2) performing a ring-opening addition reaction on the adduct obtained in step 1) and an epoxy compound to prepare a stable dispersant; the dianhydride compound does not contain a double bond that may copolymerize with an olefinically unsaturated monomer, while the epoxy compound contains a double bond that may copolymerize with an olefinically unsaturated monomer, the polyol is a polyester polyol and/or a polyether polyol, preferably being a polyether polyol. The stable dispersant obtained by means of the described preparation method has a multi-active site anchoring function, and is applied to the synthesis of copolymer polyols to obtain copolymer polyols having relatively uniform particle size.

First claim

What is claimed is:

1. A preparation method for a stable dispersant, comprising:
1) Contacting a polyol with a dianhydride compound for reaction to prepare an adduct; and
2) performing a ring-opening addition reaction on the adduct obtained in step 1) and an epoxy compound to prepare a stable dispersant;
wherein the dianhydride compound does not contain a double bond that may copolymerize with an olefinically unsaturated monomer while the epoxy compound contains a double bond that may copolymerize with an olefinically unsaturated monomer, and the polyol is a polyester polyol and/or a polyether polyol.

2. The preparation method according to claim 1 , wherein the dianhydride compound is one selected from the group consisting of pyromellitic dianhydride, benzophenonetetracarboxylic dianhydride, biphenyltetracarboxylic dianhydride, tetracarboxydiphthalic ether dianhydride, hexafluorotetracarboxylic dianhydride, triphenylbiether tetracarboxylic dianhydride, 1,2,4,5-cyclohexenetetracarboxylic dianhydride, cyclobutanetetracarboxylic dianhydride, bisphenol A type diether tetracarboxylic dianhydride, naphthalene-1,4,5,8-tetracarboxylic dianhydride, 3,4,9,10-perylenetetracarboxylic dianhydride, 3,3′,4,4′-triphenylbiether tetracarboxylic dianhydride, 1,2,3,4-cyclopentanetetracarboxylic dianhydride, and a combination of more than two selected therefrom.

3. The preparation method according to claim 2 , wherein the epoxy compound is one selected from the group consisting of glycidyl ether, glycidyl acrylate, derivatives thereof, and a combination of more than two selected therefrom.

4. The method according to claim 1 , wherein the molar ratio of the polyol to the dianhydride compound is (0.2-4):1; and wherein the molar ratio of the dianhydride compound to the epoxy compound is (0.1-2): 1.

5. The preparation method according to claim 1 , wherein the molar ratio of the dianhydride compound to the epoxy compound is (0.3-8): 1.

6. The preparation method according to claim 1 , wherein in step 1), for the polyol, the number-average molecular weight is 2500 to 15000, and the average functionality is 2.0 or more.

7. The preparation method according to claim 1 , wherein the temperatures of the reactions in step 1) and step 2) are 60° C. to 150° C.

Assignees

• Wanhua Chemical Group Co Ltd

Inventors

• Li Fuguo
• Liu Yang
• Ju Changxun
• Liu Bin
• Qin Chengqun
• Wu Xunkun
• Li Jing
• Zheng Bing
• Wang Lunpeng

Classifications

• C07C67/26 Primary

  with an oxirane ring · CPC title

• C08G18/0876

  the dispersing or dispersed phase being a polyol · CPC title

• C08G18/14

  Manufacture of cellular products · CPC title

• C08G2101/00

  Manufacture of cellular products · CPC title

• C08G65/3324 Primary

  cyclic · CPC title