Detection method for determining content of chlorine ions in marine sand

Patent metadata

Field	Value
Publication number	US-11940431-B2
Application number	US-202017290784-A
Country	US
Kind code	B2
Filing date	Jul 17, 2020
Priority date	Aug 28, 2019
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

A detection method for determining chloride ions content in sea sand includes the steps of drying sea sand to a constant weight, adding the dried sea sand to boiling deionized water, fully stirring, and standing and filtering the deionized water to obtain washed sea sand and a washed filtrate. The washed sea sand is then ground into a powder and added into deionized water and fully stirred, the deionized water then filtered to obtain a powder filtrate. Half of the washed filtrate and half of the powder filtrate is then mixed and stirred to prepare a mixed filtrate. The chloride ions content in each of the washed filtrate, the powder filtrate, and the mixed filtrate is then measured by using a silver nitrate titration method. The detection results are then analyzed and corrected to obtain the chloride ions content in the sea sand.

First claim

What is claimed is:

1. A detection method for determining chloride ions content in sea sand, characterized by being performed in the steps as follows:
Step 1, preparing a washed filtrate:
drying a sea sand sample to be detected to constant weight, weighing the dried sea sand sample to be detected with a mass of G 0 , then adding the dried sea sand sample to boiling deionized water, fully stirring for 3-6 min, letting stand for 10-15 min, and then filtering to obtain washed sea sand and a washed filtrate, wherein the deionized water is heated during stirring to keep the temperature not lower than 90° C., and a mass ratio of the dried sea sand sample to be detected for mixing and stirring to the deionized water is 1:(1.5-2.5);
Step 2, preparing a powder filtrate:
drying the washed sea sand from Step 1 until the surface of the sea sand is free of water, then grinding the washed sea sand into powder with a fineness of not less than 100 meshes, then adding the powder to deionized water, fully stirring for 5-10 min, and afterward, filtering to obtain a powder filtrate, wherein a mass ratio of the dried washed sea sand to the deionized water is 1:(1.5-2.5);
Step 3, preparing a mixed filtrate:
firstly, placing the washed filtrate prepared in Step 1 and the powder filtrate prepared in Step 2 in a thermostatic chamber, and letting stand for 15-20 min; then dividing the washed filtrate from Step 1 after standing into 2 equal parts separately, dividing the powder filtrate prepared in Step 2 after standing into 2 equal parts separately, and then mixing one part of the washed filtrate and one part of the powder filtrate to obtain a mixed filtrate, wherein the remaining part of the washed filtrate and the remaining part of the powder filtrate are for later separate use respectively;
Step 4, measuring the mass of chloride ions in different filtrates:
taking the mixed filtrate, the remaining part of the washed filtrate and the remaining part of the powder filtrate from Step 3 in same volume, and measuring the mass H 1 of chloride ions in the remaining part of washed filtrate, the mass H 2 of chloride ions in the remaining part of powder filtrate and the mass H 3 of the chloride ions in the mixed filtrate by using a silver nitrate titration method;
Step 5, determining the chloride ions content in the sea sand:
firstly, calculating the value of a, wherein a is the ratio of a sum of the mass H 1 of chloride ions in the remaining part of washed filtrate as measured in Step 4 and the mass H 2 of chloride ions in the remaining part of powder filtrate as measured in Step 4 to the mass H 3 of chloride ions in the mixed filtrate as measured in Step 4, i.e., a=(H 1 +H 2 )/H 3 ;
then, when 0.850≤a≤1.150, directly determining the chloride ions content Q in the sea sand according to the following three conditions; when the value of a is less than 0.850 or the value of a is greater than 1.150, repeating Step 4 and recalculating the value of a until 0.850≤a≤1.150, and then determining the chloride ions content Q in the sea sand according to the following three conditions:
Condition 1: when 0.850≤a<0.975, the total mass H of chloride ions in the sea sand is: H=m(H 1 +H 2 )+H 3 ; and then the chloride ions content Q in the sea sand is:

Q
=

m
⁡
(

H
1

+

H
2

)

+

H
3

G
0

×
100
⁢
%

;

Condition 2: when 0.975≤a≤1.025, the total mass H of chloride ions in the sea sand is: H=H 1 +H 2 +H 3 ; and then the chloride ions content Q in the sea sand is:

Q
=

H
1

+

H
2

+

H
3

G
0

×
100
⁢
%

;

Condition 3: when 1.025<a≤1.150, the total mass H of chloride ions in the sea sand is: H=H 1 +H 2 +nH 3 ; and then the chloride ions content Q in the sea sand is:

Q
=

H
1

+

H
2

+

nH
3

G
0

×
100
⁢
%

;

wherein m and n are coefficients, with m=1+(1−a)=2−a, and n=1+(a−1)=a.

2. The detection method for determining the chloride ions content in the sea sand according to claim 1 , characterized in that, after the mixed filtrate is prepared in Step 3, the remaining part of the washed filtrate and the remaining part of the powder filtrate are placed in the same thermostatic chamber.

3. The detection method for determining the chloride ions content in the sea sand according to claim 1 , characterized in that, when the masses of chloride ions in different filtrates are measured by using the silver nitrate titration method, a potassium chromate aqueous solution with a mass fraction of 5% is used as an indicator, and a ratio of a dropped volume of the potassium chromate aqueous solution in Step 4 to the volume of each of the mixed filtrate, the remaining part of the washed filtrate and the remaining part of the powder filtrate during titration is 1:50.

4. The detection method for determining the chloride ions content in the sea sand according to claim 1 , characterized in that, a drying oven with a temperature of 100-110° C. is used for drying in Step 1 and Step 2; and the temperature of the thermostatic chamber is controlled to be 25-35° C. in Step 3.

5. The detection method for determining the chloride ions content in the sea sand according to claim 1 , characterized in that, a magnetic stirrer is used for stirring in Step 1 and Step 2, wherein

Assignees

• Univ Fuzhou

Inventors

• Yang Zhengxian
• Hong Rongcan
• Lu Lin
• Cai Shuikun
• Changtai Deng
• Lin Xiaohui
• Lin Xiuqing

Classifications

• G01N31/16 Primary

  using titration · CPC title

• G01N1/28 Primary

  Preparing specimens for investigation {including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q}(mounting specimens on microscopic slides G02B21/34; means for supporting the objects or the materials to be analysed in electron microscopes H01J37/20 {; laboratory gas handling apparatus B01L5/00}) · CPC title

• G01N1/34

  Purifying; Cleaning {(processes or apparatus for extracting or separating nucleic acids from biological samples C12N15/1003)} · CPC title

• G01N1/4077

  by other techniques involving separation of suspended solids · CPC title

• G01N1/38

  Diluting, dispersing or mixing samples · CPC title