Predicting solvent power of light oils

Patent metadata

Field	Value
Publication number	US-10844298-B2
Application number	US-201615239019-A
Country	US
Kind code	B2
Filing date	Aug 17, 2016
Priority date	Sep 1, 2015
Publication date	Nov 24, 2020
Grant date	Nov 24, 2020

Abstract

A method for recalculating the solvent power of a light oil, SP (LO recalculated) , is provided. The method comprises:
titrating the light oil against a reference oil, optionally in the presence of a titrant, to determine a volume fraction of the light oil at the onset of asphaltene precipitation, V (onset fraction LO) , a volume fraction of the reference oil at the onset of asphaltene precipitation, V (onset fraction RO) , and, where a titrant is present, a volume fraction of the titrant at the onset of asphaltene precipitation, V (onset fraction T) , and determining the recalculated solvent power of the light oil, SP (LO recalculated) , according to the following formula:

SP ( LO ⁢ ⁢ recalculated ) = ( CSP ( RO ) - SP ( RO ) * V ( onset ⁢ ⁢ fraction ⁢ ⁢ RO ) - x * SP ( T ) * V ( onset ⁢ ⁢ fraction ⁢ ⁢ T ) ) V ( onset ⁢ ⁢ fraction ⁢ ⁢ LO )
wherein: CSP (RO) is the critical solvent power of the reference oil,
SP (RO) is the solvent power of the reference oil, SP (T) is the solvent power of the titrant, and x is 1 where a titrant is present, and otherwise is 0.

The recalculated solvent power may be used in methods for preventing asphaltene precipitation during processing of crude oils in a refinery.

First claim

The invention claimed is:

1. A method of preparing a blend of a light oil and a heavy oil in a refinery, the blend having a reduced degree of precipitation of asphaltene, said method comprising:
titrating the light oil against a reference oil, optionally in the presence of a titrant, to determine a volume fraction of the light oil at the onset of asphaltene precipitation, V (onset fraction LO) , a volume fraction of the reference oil at the onset of asphaltene precipitation, V (onset fraction RO) , and, where a titrant is present, a volume fraction of the titrant at the onset of asphaltene precipitation, V (onset fraction T) ,
determining the recalculated solvent power of the light oil, SP (LO recalculated) , using the following formula:

SP

(

LO
⁢

⁢
recalculated

)

=

(

CSP

(
RO
)

-

SP

(
RO
)

*

V

(

onset
⁢

⁢
fraction
⁢

⁢
RO

)

-

x
*

SP

(
T
)

*

V

(

onset
⁢

⁢
fraction
⁢

⁢
T

)

)

V

(

onset
⁢

⁢
fraction
⁢

⁢
LO

)

wherein:
CSP (RO) is the critical solvent power of the reference oil,
SP (RO) is the solvent power of the reference oil,
SP (T) is the solvent power of the titrant, and
x is 1 where a titrant is present, and otherwise is 0;

calculating, based on the recalculated solvent power of the light oil, a maximum ratio of light oil that may be included in a blend of the light oil and the heavy oil without asphaltene precipitation occurring in the refinery; and
feeding a blend of the light oil and the heavy oil having up to the maximum ratio of light oil to the refinery.

2. The method of claim 1 , wherein the precipitation of asphaltene from the blend may be reduced by at least 80% by weight as compared to the precipitation that would be observed from the same weight of heavy oil.

3. The method of claim 1 , wherein the precipitation of asphaltene is reduced on the surface of heat exchangers in the refinery.

4. The method of claim 1 , wherein titration intervals of less than 15% by weight are used for titrating the light oil against the reference oil.

5. The method of claim 1 , wherein the light oil is titrated against the reference oil in the presence of a titrant and x is 1.

6. The method of claim 1 , wherein the method comprises titrating the light oil against a plurality of reference oils, predicting a solvent power of the light oil for each of the plurality of reference oils and determining an average predicted solvent power of the light oil.

7. The method of claim 6 , wherein the light oil is titrated against at least 5 reference oils.

8. The method of claim 1 , wherein the solvent power of the reference oil, SP (RO) , is estimated from the characterisation K factor of the reference oil.

9. The method of claim 1 , wherein the critical solvent power of the reference oil, CSP (RO) , is determined by titrating the reference oil against a precipitant.

10. The method of claim 1 , wherein the light oil has an asphaltene content of less than 1% by weight.

11. The method of claim 1 , wherein the reference oil has an asphaltene content of greater than 3% by weight.

12. The method of claim 1 , wherein the light oil and the reference oil are crude oils.

13. The method of claim 1 further comprising determining a relationship between the recalculated solvent power and the bulk properties of the plurality of light oils.

14. The method of claim 13 , wherein the method comprises measuring the bulk properties of the plurality of light oils.

15. The method of claim 13 , wherein the plurality of light oils consists of at least 5 light oils.

16. The method of claim 13 , wherein the bulk properties include at least one of: yield, characterization K factor, total acid number (TAN), nitrogen content, API gravity, aromatics content, and density.

17. The method of claim 13 , further comprising using the relationship between the recalcu

Assignees

• Bp Corp North America Inc

Inventors

• Balashanmugam Soban
• Fisher Ronald
• Rueda-Velásquez Rosa
• Halliday Devin

Classifications

• G01N33/2823

  Raw oil, drilling fluid or polyphasic mixtures · CPC title

• G01N31/16

  using titration · CPC title

• C10G75/00 Primary

  Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general (C10G7/10, C10G9/16 take precedence) · CPC title

• C10G2300/206

  Asphaltenes · CPC title

• C10G2300/802

  Diluents · CPC title