Multi-cavity semi-open resonant photoacoustic cell and multi-gas simultaneous measurement system
US-11300499-B2 · Apr 12, 2022 · US
US11940375B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11940375-B2 |
| Application number | US-202117535978-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 26, 2021 |
| Priority date | Dec 8, 2020 |
| Publication date | Mar 26, 2024 |
| Grant date | Mar 26, 2024 |
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The present disclosure relates to the technical field of fiber-optic gas sensing and laser photoacoustic spectroscopy, and reliability of a gas detection system is improved by actively selecting a working frequency of low noise interference combined with an optical fiber photoacoustic sensing probe capable of isolating high-frequency noise. A gas enters a photoacoustic microcavity through gaps on a sound-sensitive diaphragm after diffusing into a miniature air chamber through a plurality of micropores. Photoacoustic excitation light is incident into the photoacoustic microcavity through a fiber-optic collimator and then excited to generate a photoacoustic pressure wave to cause the sound-sensitive diaphragm to vibrate periodically. An end face of a single-mode optical fiber and the sound-sensitive diaphragm constitutes a fiber-optic Fabry-Perot interferometer. The interferometer measures a deflection of the diaphragm and inverts a concentration of the to-be-measured gas.
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The invention claimed is: 1. A fiber-optic photoacoustic sensing probe capable of resisting interference from ambient noise, comprising a fiber-optic collimator ( 9 ), a single-mode optical fiber ( 10 ), a photoacoustic microcavity ( 11 ), a miniature air chamber ( 12 ), a diffusion micropore ( 13 ), a sound-sensitive diaphragm ( 14 ), and a sound-insulated housing ( 15 ), wherein the miniature air chamber ( 12 ) is provided inside the sound-insulated housing ( 15 ), the miniature air chamber ( 12 ) is cylindrical, and a plurality of diffusion micropores ( 13 ) communicating with the outside are provided along a diameter direction of the miniature air chamber ( 12 ); the sound-sensitive diaphragm ( 14 ) is installed inside the miniature air chamber ( 12 ), and comprises a plurality of gaps ( 141 ) that constitute a cross-shaped beam structure at a central position of the sound-sensitive diaphragm ( 14 ); the photoacoustic microcavity ( 11 ) is deployed inside the sound-insulated housing ( 15 ) along a direction perpendicular to the miniature air chamber ( 12 ), one end of the photoacoustic microcavity ( 11 ) is connected to the outside, and the other end of the photoacoustic microcavity ( 11 ) is connected to the miniature air chamber ( 12 ); the fiber-optic collimator ( 9 ) is sealed and installed on the end, connected to the outside, of the photoacoustic microcavity ( 11 ); the single-mode optical fiber ( 10 ) is connected to the miniature air chamber ( 12 ) along a horizontal center line of the sound-insulated housing ( 15 ); and a center of the sound-sensitive diaphragm ( 14 ) and an end face of the single-mode optical fiber ( 10 ) constitute a fiber-optic Fabry-Perot interferometer. 2. The fiber-optic photoacoustic sensing probe capable of resisting interference from ambient noise according to claim 1 , wherein a working process is as follows: a gas enters the photoacoustic microcavity ( 11 ) through the gaps ( 141 ) on the sound-sensitive diaphragm ( 14 ) after diffusing into the miniature air chamber ( 12 ) through the plurality of diffusion micropores ( 13 ); photoacoustic excitation light is incident into the photoacoustic microcavity ( 11 ) through the fiber-optic collimator ( 9 ), and then excited to generate a photoacoustic pressure wave to cause the sound-sensitive diaphragm ( 14 ) to vibrate periodically; and a deflection of the diaphragm is measured by using the fiber-optic Fabry-Perot interferometer, and a concentration of the to-be-measured gas is inverted. 3. A sensing system using the fiber-optic photoacoustic sensing probe capable of resisting interference from ambient noise according to claim 2 , comprising: a signal collection and processing circuit ( 1 ), a laser light source drive circuit ( 2 ), a photoacoustic excitation light source ( 3 ), a double-core optical fiber ( 4 ), a fiber-optic photoacoustic sensing probe ( 5 ), a detection light source ( 6 ), a fiber-optic circulator ( 7 ), and a photodetector ( 8 ), wherein an input terminal of the photodetector ( 8 ) is connected to port 3# of the fiber-optic circulator ( 7 ), and an output terminal of the photodetector ( 8 ), the signal collection and processing circuit ( 1 ), the laser light source drive circuit ( 2 ), and the photoacoustic excitation light source ( 3 ) are connected in series and then connected to the fiber-optic photoacoustic sensing probe ( 5 ) by using one optical fiber of the double-core optical fiber ( 4 ); the detection light source ( 6 ) is connected to port 1# of the fiber-optic circulator ( 7 ), and port 2# of the fiber-optic circulator ( 7 ) is connected to the fiber-optic photoacoustic sensing probe ( 5 ) by using the other optical fiber of the double-core optical fiber ( 4 ); and the signal collection and processing circuit ( 1 ) adopts a digital lock-in amplifier based on a field programmable gate array (FPGA). 4. The sensing system according to claim 3 , wherein a working process comprises the following steps: step 1: turning off the photoacoustic excitation light source ( 3 ), wherein the detection light is reflected on a surface of the fiber-optic Fabry-Perot interferometer after entering the fiber-optic photoacoustic sensing probe ( 5 ), to output an interference signal; step 2: performing demodulation and spectrum analysis on the output interference signal to obtain influence of ambient noise, and then determining a low-interference frequency as a working frequency; step 3: driving the photoacoustic excitation light source ( 3 ) after determining a modulation frequency, wherein the excitation light is incident into the fiber-optic photoacoustic sensing probe ( 5 ) to cause a photoacoustic effect and generate a photoacoustic signal; step 4: restoring the photoacoustic signal by using an interference-intensity demodulation method, and performing spectrum analysis on the signal; and step 5: calculating a concentration of a to-be-measured gas based on an amplitude of the photoacoustic signal. 5. The sensing system according to claim 4 , wherein a method for determining the low-interference frequency as the working frequency in step 2 is as follows: the detection light emitted by the detection light source ( 6 ) is incident into the fiber-optic photoacoustic sensing probe ( 5 ) after passing through the fiber-optic circulator ( 7 ), and returned Fabry-Perot interference signal light is received by the photodetector ( 8 ) after passing through the fiber-optic circulator ( 7 ); the signal collection and processing circuit ( 1 ) collects a photoelectric signal converted by the photodetector ( 8 ), restores an acoustic wave signal by using the interference-intensity demodulation method, and performs spectrum analysis on the detected ambient noise through fast Fourier transform; and the low-interference frequency in the ambient noise is selected, within a high frequency range and based on a frequency response of the fiber-optic photoacoustic sensing probe ( 5 ) to an external acoustic wave and a spectrum analysis result, as the working frequency of photoacoustic measurement. 6. The sensing system according to claim 4 , wherein the modulation frequency in step 3 is set to half of the working frequency. 7. The sensing system according to claim 4 , wherein the restoring the photoacoustic signal by using an interference-intensity demodulation method specifically comprises: setting a central wavelength of the detection light source ( 6 ) to lock a working point at a position with a maximum absolute value of a slope of an interference curve of the fiber-optic Fabry-Perot interferometer used for photoacoustic detection in the fiber-optic photoacoustic sensing probe ( 5 ), so that acoustic wave detection has the highest sensitivity and a largest linear response range. 8. The sensing system according to claim 3 , wherein the photoacoustic excitation light source ( 3 ) is a near-infrared wavelength-tunable narrow-linewidth laser light source that can be coupled to the single-mode optical fiber. 9. The sensing system according to claim 3 , wherein the double-core optical fiber ( 4 ) is composed of two G652 single-mode optical fibers. 10. The sensing system according to claim 3 , wherein the detection light source ( 6 ) is a wavelength-tunable narrow-linewidth laser light source. 11. A sensing system using the fiber-optic photoacoustic sensing probe capable of resisting interference from ambient noise according to claim 1 , comprising: a signal collection and processing circuit ( 1 ), a laser light source drive circuit ( 2 ), a photoacoustic excitation light source ( 3 ), a double-core optical fiber ( 4 ), a fiber-optic photoacoustic sensing probe ( 5 ), a detection light source ( 6 ), a fiber-optic circulator ( 7 ), and a photode
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